1',2,3,3',4,4',6-hepta-O-benzyl-6'-O-methacryloyl-sucrose | 800369-26-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1',2,3,3',4,4',6-hepta-O-benzyl-6'-O-methacryloyl-sucrose
• 英文别名: [(2R,3R,4S,5S)-3,4-bis(phenylmethoxy)-5-(phenylmethoxymethyl)-5-[(2R,3R,4S,5R,6R)-3,4,5-tris(phenylmethoxy)-6-(phenylmethoxymethyl)oxan-2-yl]oxyoxolan-2-yl]methyl 2-methylprop-2-enoate
• CAS: 800369-26-0
• 化学式: C₆₅H₆₈O₁₂
• 分子量: 1041.25
• InChiKey: GZMRVYLMDNPQAJ-BGEPPVSMSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.2
• 重原子数：
  77
• 可旋转键数：
  29
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  119
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为产物：
  描述：

  1',2,3,3',4,4',6-hepta-O-benzyl-6'-O-tert-butyldiphenylsilyl-sucrose 在 4-二甲氨基吡啶 、 四丁基氟化铵 、 三乙胺 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 生成 1',2,3,3',4,4',6-hepta-O-benzyl-6'-O-methacryloyl-sucrose
  参考文献：
  名称：

  Regioselective Copolymerization of Acryl Sucrose Monomers

  摘要：

  1',2,3,3',4,4',6-Hepta-O-benzyl-sucrose has been prepared and selectively 6'-O-esterified with small alpha,beta-unsaturated acid derivatives. New chiral copolymers containing sucrose have been synthesized by radical polymerization, and some of their physical properties have been determined.

  DOI：

  10.1021/jo048957y

文献信息

• Potentially Biodegradable Polymers Based on α- or β-Pinene and Sugar Derivatives or Styrene, Obtained under Normal Conditions and on Microwave Irradiation
  作者：Maria Teresa Barros、Krasimira T. Petrova、Ana Maria Ramos

  DOI：10.1002/ejoc.200600890

  日期：2007.3

  The homopolymerisation of α- and β-pinene and their copolymerisation with styrene and hepta-O-benzyl-6′-O-methacryloyl-sucrose (BMS) have been examined in the presence of AIBN as free-radical initiator, either in toluene or without solvent at 80 °C at normal pressure and also in a synthetic microwave oven. A study of the effect of the reaction conditions, the monomer structure and the initial ratio

  α-和β-蒎烯的均聚以及它们与苯乙烯和七-O-苄基-6'-O-甲基丙烯酰基-蔗糖（BMS）的共聚已经在AIBN作为自由基引发剂的存在下，在甲苯或在 80 °C 和常压下以及合成微波炉中无溶剂。已经对反应条件、单体结构和共聚单体的初始比例对最终共聚物性质的影响进行了研究，每一种都含有两种天然产物。发现了一种在微波辐射温和条件下在短反应时间内合成聚（β-蒎烯）、聚（α-蒎烯-共聚苯乙烯）和聚（β-蒎烯-共聚苯乙烯）的新方法。（© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)
• Regioselective Copolymerization of Acryl Sucrose Monomers
  作者：Maria Teresa Barros、Krasimira T. Petrova、Ana Maria Ramos

  DOI：10.1021/jo048957y

  日期：2004.10.1

  1',2,3,3',4,4',6-Hepta-O-benzyl-sucrose has been prepared and selectively 6'-O-esterified with small alpha,beta-unsaturated acid derivatives. New chiral copolymers containing sucrose have been synthesized by radical polymerization, and some of their physical properties have been determined.