α-tert-butylperoxyethyl acetate | 24257-46-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: α-tert-butylperoxyethyl acetate
• 英文别名: α-acetyloxyethyl tert-butyl peroxide；1-Acetoxy-ethyl-tert.-butyl-peroxid；alpha-Acetyloxyethyl t-butyl peroxide；1-tert-butylperoxyethyl acetate
• CAS: 24257-46-3
• 化学式: C₈H₁₆O₄
• 分子量: 176.213
• InChiKey: GIRSMGVMIKCHFB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  12
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  α-tert-butylperoxyethyl acetate 在 二乙胺 作用下， 以 氯苯 为溶剂， 以100%的产率得到溶剂黄146
  参考文献：
  名称：

  Turovskii, A. A.; Kucher, R. V.; Kushch, O. V, Journal of Organic Chemistry USSR (English Translation), 1986, vol. 22, p. 654 - 657

  摘要：

  DOI：
• 作为产物：
  描述：

  2-(1-氯乙基过氧)-2-甲基丙烷 、 溶剂黄146 在 三乙胺 作用下， 以 氯仿 为溶剂， 反应 0.08h， 以92%的产率得到α-tert-butylperoxyethyl acetate
  参考文献：
  名称：

  Synthesis of α-hydroxyalkyl peroxide esters and ethers as initiators of radical processes

  摘要：

  alpha-Hydroxyalkyl peroxide esters and ethers containing, along with the peroxy bond, also acyloxy and alkoxy groups, are effective initiators of radical processes. The initiation efficiency is due to the capability of these molecules to generate simultaneously oxygen- and carbon-centered radicals capable of hydrogen abstraction from the substrate and of addition to > C=CaOE (c) bonds. The selectivity of the synthesis of alpha-hydroxyalkyl peroxide esters and ethers is mainly determined by the steps of the synthesis and isolation of the intermediate alpha-chloroalkyl peroxides, because of their high reactivity. Experimental conditions allowing control of the synthesis of alpha-hydroxyalkyl peroxide esters and ethers were found.

  DOI：

  10.1134/s1070427214120167
• 作为试剂：
  描述：

  二乙胺 在 α-tert-butylperoxyethyl acetate 作用下， 以 氯苯 为溶剂， 生成 3-aza-2-pentene 、 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Turovskii, A. A.; Kucher, R. V.; Kushch, O. V, Journal of Organic Chemistry USSR (English Translation), 1986, vol. 22, p. 654 - 657

  摘要：

  DOI：

文献信息

• Cement Admixture composition
  申请人：W.R. Grace & Co.-Conn.

  公开号：EP0556061A1

  公开（公告）日：1993-08-18

  Cement admixture compositions formed from alkenyl ether/maleic anhydride copolymers having specific molecular structures have been found to impart a high degree of slump loss over a sustained period of time while not causing any significant set retardation of the treated cement based composition.

  研究发现，由具有特定分子结构的烯基醚/马来酸酐共聚物形成的水泥外加剂组合物可在持续一段时间内产生较高程度的坍落度损失，同时不会对经处理的水泥基组合物造成任何明显的凝固延迟。
• Turovskii, A. A.; Navrotskii, V. A.; Turovskii, N. A., Journal of general chemistry of the USSR, 1985, vol. 55, # 1, p. 152 - 155
  作者：Turovskii, A. A.、Navrotskii, V. A.、Turovskii, N. A.、Aleinikova, T. P.、Kushch, O. V.

  DOI：——

  日期：——
• ALEJNIKOVA, T. P.;NAVROTSKIJ, V. A.;KARGINA, L. V., XIMIYA I TEXNOL. EHLEMENTOORGAN. POLUPRODUKTOV I POLIMEROV, VOLGOGRAD, 19+
  作者：ALEJNIKOVA, T. P.、NAVROTSKIJ, V. A.、KARGINA, L. V.

  DOI：——

  日期：——
• Synthesis of α-hydroxyalkyl peroxide esters and ethers as initiators of radical processes
  作者：T. P. Aleinikova、V. A. Navrotskii

  DOI：10.1134/s1070427214120167

  日期：2014.12

  alpha-Hydroxyalkyl peroxide esters and ethers containing, along with the peroxy bond, also acyloxy and alkoxy groups, are effective initiators of radical processes. The initiation efficiency is due to the capability of these molecules to generate simultaneously oxygen- and carbon-centered radicals capable of hydrogen abstraction from the substrate and of addition to > C=CaOE (c) bonds. The selectivity of the synthesis of alpha-hydroxyalkyl peroxide esters and ethers is mainly determined by the steps of the synthesis and isolation of the intermediate alpha-chloroalkyl peroxides, because of their high reactivity. Experimental conditions allowing control of the synthesis of alpha-hydroxyalkyl peroxide esters and ethers were found.
• Turovskii, A. A.; Kucher, R. V.; Kushch, O. V, Journal of Organic Chemistry USSR (English Translation), 1986, vol. 22, p. 654 - 657
  作者：Turovskii, A. A.、Kucher, R. V.、Kushch, O. V、Turovskii, N. A.

  DOI：——

  日期：——