5-Methylundec-5-ene | 31613-73-7

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: 5-Methylundec-5-ene
• CAS: 31613-73-7
• 化学式: C₁₂H₂₄
• 分子量: 168.323
• InChiKey: KCCDVPWBXMNJFG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  12
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  2-丁基辛醇 在 Filtrol 20X acidic clay 作用下， 135.0~160.0 ℃ 、32.0 kPa 条件下， 反应 2.33h， 生成 5-methyl-4-undecene 、 2-丁基-1-辛烯 、 5-Methylundec-5-ene
  参考文献：
  名称：

  DIARYL AMINE ANTIOXIDANTS PREPARED FROM BRANCHED OLEFINS

  摘要：

  二芳基胺通过与支链烯烃反应选择性地烷基化，这些烯烃能够形成三级碳离子，并且可以从易得的支链醇方便地制备。二芳基胺产品是有效的抗氧化剂，通常包含大量的二烷基化二芳基胺和少量的三烷基化和四烷基化二芳基胺。

  公开号：

  US20170015618A1

文献信息

• Scope and Mechanism of Homogeneous Tantalum/Iridium Tandem Catalytic Alkane/Alkene Upgrading using Sacrificial Hydrogen Acceptors
  作者：David C. Leitch、Jay A. Labinger、John E. Bercaw

  DOI：10.1021/om500231t

  日期：2014.7.14

  increases only modestly with temperature. In contrast, the rate of 1-hexene/n-heptane transfer hydrogenation catalyzed by t-Bu[PCP]IrH4 is inverse order in 1-hexene and increases substantially with temperature. Styrene has been investigated as an alternate sacrificial hydrogen acceptor. Styrene dimerization catalyzed by Cp*TaCl2(alkene) is considerably slower than 1-hexene dimerization. The conversion of styrene/heptane

  报道了基于早期/晚期过渡金属对的用于烷烃和烯烃偶联的双均相催化剂体系的深入研究。该系统由用于烯烃二聚化的Cp * TaCl 2（烯烃）和用于烷烃/烯烃转移加氢的夹钳氢化铱组成。由于两种催化剂之间没有动力学相关的相互作用，因此串联机理可以使用两个独立的催化循环进行完整描述。烯烃二聚机理的特征在于Cp * TaCl 2（1-己烯）+ 1-己烯和Cp * TaCl 2（金属环戊烷）之间的熵预平衡差（ΔH °= −22（2）kcal / mol;Δ小号°= -16（2）eu）; 因此，烯烃二聚的总速率在1-己烯中呈正序（表现出饱和动力学），并且仅随温度适度增加。相反，由t -Bu [PCP] IrH 4催化的1-己烯/正庚烷转移氢化速率在1-己烯中是反序的，并且随着温度的升高而增加。已经研究了苯乙烯作为替代的牺牲氢受体。Cp * TaCl 2催化苯乙烯二聚（烯烃）比1-己烯二聚反应要慢得多。通过Ta
• Upgrading Light Hydrocarbons via Tandem Catalysis: A Dual Homogeneous Ta/Ir System for Alkane/Alkene Coupling
  作者：David C. Leitch、Yan Choi Lam、Jay A. Labinger、John E. Bercaw

  DOI：10.1021/ja405191a

  日期：2013.7.17

  Light alkanes and alkenes are abundant but are underutilized as energy carriers because of their high volatility and low energy density. A tandem catalytic approach for the coupling of alkanes and alkenes has been developed in order to upgrade these light hydrocarbons into heavier fuel molecules. This process involves alkane dehydrogenation by a pincer-ligated iridium complex and alkene dimerization by a Cp*TaCl2(alkene) catalyst. These two homogeneous catalysts operate with up to 60/30 cooperative turnovers (Ir/Ta) in the dimerization of 1-hexene/n-heptane, giving C-13/C-14 products in 40% yield. This dual system can also effect the catalytic dimerization of n-heptane (neohexene as the H-2 acceptor) with cooperative turnover numbers of 22/3 (Ir/Ta).
• DIARYL AMINE ANTIOXIDANTS PREPARED FROM BRANCHED OLEFINS
  申请人：Chemtura Corporation

  公开号：US20170015618A1

  公开（公告）日：2017-01-19

  Diaryl amines are selectively alkylated by reaction with branched olefins, which olefins are capable of forming tertiary carbonium ions and can be conveniently prepared from readily available branched alcohols. The diaryl amine products are effective antioxidants and often comprise a high amount of di-alkylated diaryl amines and a low amount of tri- and tetra-alkylated diaryl amines.

  二芳基胺通过与支链烯烃反应选择性地烷基化，这些烯烃能够形成三级碳离子，并且可以从易得的支链醇方便地制备。二芳基胺产品是有效的抗氧化剂，通常包含大量的二烷基化二芳基胺和少量的三烷基化和四烷基化二芳基胺。