2-methyl-1,4,5-triphenyl-1H-imidazole | 24499-04-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 2-methyl-1,4,5-triphenyl-1H-imidazole
• 英文别名: 2-methyl-1,4,5-triphenyl-1H-imidazole；2-Methyl-1,4,5-triphenyl-1H-imidazol；2-Methyl-1,4,5-triphenyl-imidazol；1H-Imidazole, 2-methyl-1,4,5-triphenyl-；2-methyl-1,4,5-triphenylimidazole
• CAS: 24499-04-5
• 化学式: C₂₂H₁₈N₂
• 分子量: 310.398
• InChiKey: GLMATDQQVFXTDC-UHFFFAOYSA-N

物化性质

• 熔点：
  194 °C(Solv: methanol (67-56-1))
• 沸点：
  489.3±48.0 °C(Predicted)
• 密度：
  1.08±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  24
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  17.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2-methyl-3,4,5-triphenyl-oxazolium; perchlorate 在 乙酸铵 、 乙酸酐 、 溶剂黄146 作用下， 生成 2-methyl-1,4,5-triphenyl-1H-imidazole
  参考文献：
  名称：

  Gompper, Chemische Berichte, 1957, vol. 90, p. 374,381

  摘要：

  DOI：

文献信息

• Compound for organic photoelectric device and organic photoelectric device including the same
  申请人：Jung Ho-Kuk

  公开号：US20100200054A1

  公开（公告）日：2010-08-12

  A compound for an organic photoelectric device, represented by the following Chemical Formula 1:

  一种用于有机光电器件的化合物，化学式如下：Chemical Formula 1
• [EN] NOVEL ORGANIC ELECTROLUMINESCENT COMPOUNDS AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME<br/>[FR] NOUVEAUX COMPOSÉS ÉLECTROLUMINESCENTS ORGANIQUES ET DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE UTILISANT CEUX-CI
  申请人：ROHM & HAAS ELECT MAT

  公开号：WO2011132865A1

  公开（公告）日：2011-10-27

  Disclosed are organic electroluminescent compounds and organic electroluminescent devices employing said compounds. The organic electroluminescent compounds of the invention are substituted dihydro-pyrrolo[3,2-b:4,5-b']diindole, dihydro-furo[3,2-b:4,5-b']diindole and dihydro-thieno[3,2-b:4,5-b']diindole compounds defined by chemical formula (1), The compounds, when used in as a host material of an OLED device, exhibit good luminous efficiency and lifespan.

  本发明公开了有机电致发光化合物和应用所述化合物的有机电致发光器件。本发明的有机电致发光化合物是通过化学式（1）定义的取代二氢吡咯并[3,2-b:4,5-b']二吲哚、二氢呋并[3,2-b:4,5-b']二吲哚和二氢噻吩并[3,2-b:4,5-b']二吲哚化合物。当这些化合物作为OLED器件的主体材料时，表现出良好的发光效率和寿命。
• Clay supported titanium catalyst for the solvent free synthesis of tetrasubstituted imidazoles and benzimidazoles
  作者：V. Kannan、K. Sreekumar

  DOI：10.1016/j.molcata.2013.04.004

  日期：2013.9

  A series of clay supported metal containing catalysts were prepared and their catalytic performance was evaluated in the synthesis of tetrasubstitued imidazoles under solvent free condition. It was found that K10 supported titanium catalyst showed higher activity compared to other catalysts. The catalysts were characterized by FTIR, XRD, TG/DTA, BET surface area and SEM. The general applicability of the method was demonstrated for the synthesis of tetra- substituted imidazoles from aldehydes and amines containing various electron donating and electron withdrawing substituents. The diversity of the catalyst was studied by synthesis of benzimidazoles and quinoxalines. The mechanism of formation of the products is explained in detail. The catalyst was found to be active for three cycles. (C) 2013 Elsevier B.V. All rights reserved.
• THE ACTION OF AMMONIA ON BENZIL
  作者：DAVID DAVIDSON、MARVIN WEISS、MURRAY JELLING

  DOI：10.1021/jo01227a004

  日期：1937.9
• Everest; McCombie, Journal of the Chemical Society, 1911, vol. 99, p. 1750
  作者：Everest、McCombie

  DOI：——

  日期：——