Ag(8-hydroxyquinoline) | 15521-50-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: Ag(8-hydroxyquinoline)
• 英文别名: (Quinolin-8-olato-N1,O8)silver；silver;quinolin-8-olate
• CAS: 15521-50-3
• 化学式: Ag*C₉H₆NO
• 分子量: 252.021
• InChiKey: KOEBPWXXFIJQPG-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.31
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  36
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  Ag(8-hydroxyquinoline) 、 三丁基膦 以 乙醚 为溶剂， 以96%的产率得到(tri-n-butylphosphine)2Ag(8-hydroxyquinoline)
  参考文献：
  名称：

  Phosphane- and phosphite-silver(I) phenolates: Synthesis, characterization and their use as CVD precursors

  摘要：

  The silver(I) salts [AgOR] (3a, R = C9H6N; 3b, R = C6H4-2-CHO, 3c, R = C6H4-2-Cl; 3d, R = C6H4-2-C N; 3e, R = C6H4-2-NO2) are accessible by the stoichiometric reaction of [AgNO3] (1) with HOR (2a, R = C9H6N; 2b, R = C6H4-2-CHO; 2c, R = C6H4-2-Cl; 2d, R = C6H4-2-C N; 2e, R = C6H4-2-NO2) in presence of NEt3. Treatment of 3a-3e with (PBu3)-Bu-n (4), P(OMe)(3) (5a) or P(OCH2CF3)(3) (5b) in the ratios of 1:1 and 1:2, respectively, produced complexes [LmAgOR] (L = (PBu3)-Bu-n, m = 1: 6a, R = C9H6N; 6b, R = C6H4-2-CHO; 6c, R = C6H4-2-Cl; 6d, R= C6H4-2-C N; 6e, R= C6H4-2-NO2. m = 2: 7a, R= C9H4; 7b, R= C6H4-2-CHO; 7c, R= C6H4-2-Cl; 7d, R = C6H4-2-C N; 7e, R = C6H4-2-NO2. L = P(OMe)(3), m = 1: 8a, R = C6H4-2-CHO; 8b, R = C6H4-2-NO2. m = 2: 9, R = C6H4-2-NO2. L = P(OCH2CF3)(3), m = 1: 10, R = C6H4-2-NO2). Based on TGA, temperature-programmed and in situ molecular beam mass spectrometry metal-organic 7e was applied as CVD precursor in the deposition of silver onto glass substrates. The resulting silver films were characterized by XRD. The SEM image of a film grown from 7e at 350 degrees C showed a homogeneous surface with grain sizes of 40 nm. The molecular structures of 8b and 10 in the solid state were determined. They are isostructural and are cubane-like structured. Low-temperature P-31{H-1} NMR studies showed that the title complexes are dynamic in solution and exchange at room temperature their ligands. (C) 2010 Published by Elsevier B.V.

  DOI：

  10.1016/j.ica.2010.05.049
• 作为产物：
  描述：

  8-羟基喹啉 、 silver dithizonate 以 氯仿 、 水 为溶剂， 生成 Ag(8-hydroxyquinoline)
  参考文献：
  名称：

  在有机相-III中的金属螯合物交换双硫di酸酯和肟酸酯的萃取和交换常数。

  摘要：

  分光光度法研究了银，Tl（I），Cu（II），Zn，Cd，Hg（II），Pb，Co（II），Ni，Pd，In，Ga和Bi的双硫iz酸酯和含氧酸酯之间的反应。根据确定的交换常数，已计算出金属二硫氰酸盐或金属含氧酸盐的萃取常数。通过这种方法，可以计算出许多金属螯合物的萃取常数，这些常数很难通过研究水相和氯仿相之间的分布来确定。

  DOI：

  10.1016/0039-9140(69)80024-x

文献信息

• Solvent extraction study in the silver(I)-8-hydroxyquinoline system
  作者：J. Hála

  DOI：10.1016/0022-1902(65)80170-1

  日期：1965.12

  The extraction of Ag(I) with 8-hydroxyquinoline into chloroform was studied in the low range of 8-hydroxyquinoline concentrations. The existence of AgOx and AgOx2− in the aqueous phase was proved and their stability constants were determined. It was shown that Ag(I) is extracted as AgOx·HOx. The equilibrium extraction constants were determined. The structure of these complexes is discussed as well

  研究了在低浓度的8-羟基喹啉中用8-羟基喹啉将Ag（I）萃取到氯仿中的方法。AgOx和AgOx存在2 -在水相中被证明并测定它们的稳定性常数。结果表明，Ag（I）被提取为AgOx·HOx。确定平衡提取常数。讨论了这些络合物的结构以及水相中AgOx·HOx的存在。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ag: MVol.B6, 1.5.1.14, page 107 - 118
  作者：

  DOI：——

  日期：——
• Phosphane- and phosphite-silver(I) phenolates: Synthesis, characterization and their use as CVD precursors
  作者：Alexander Jakob、Heike Schmidt、Bernhard Walfort、Tobias Rüffer、Thomas Haase、Katharina Kohse-Höinghaus、Heinrich Lang

  DOI：10.1016/j.ica.2010.05.049

  日期：2011.1

  The silver(I) salts [AgOR] (3a, R = C9H6N; 3b, R = C6H4-2-CHO, 3c, R = C6H4-2-Cl; 3d, R = C6H4-2-C N; 3e, R = C6H4-2-NO2) are accessible by the stoichiometric reaction of [AgNO3] (1) with HOR (2a, R = C9H6N; 2b, R = C6H4-2-CHO; 2c, R = C6H4-2-Cl; 2d, R = C6H4-2-C N; 2e, R = C6H4-2-NO2) in presence of NEt3. Treatment of 3a-3e with (PBu3)-Bu-n (4), P(OMe)(3) (5a) or P(OCH2CF3)(3) (5b) in the ratios of 1:1 and 1:2, respectively, produced complexes [LmAgOR] (L = (PBu3)-Bu-n, m = 1: 6a, R = C9H6N; 6b, R = C6H4-2-CHO; 6c, R = C6H4-2-Cl; 6d, R= C6H4-2-C N; 6e, R= C6H4-2-NO2. m = 2: 7a, R= C9H4; 7b, R= C6H4-2-CHO; 7c, R= C6H4-2-Cl; 7d, R = C6H4-2-C N; 7e, R = C6H4-2-NO2. L = P(OMe)(3), m = 1: 8a, R = C6H4-2-CHO; 8b, R = C6H4-2-NO2. m = 2: 9, R = C6H4-2-NO2. L = P(OCH2CF3)(3), m = 1: 10, R = C6H4-2-NO2). Based on TGA, temperature-programmed and in situ molecular beam mass spectrometry metal-organic 7e was applied as CVD precursor in the deposition of silver onto glass substrates. The resulting silver films were characterized by XRD. The SEM image of a film grown from 7e at 350 degrees C showed a homogeneous surface with grain sizes of 40 nm. The molecular structures of 8b and 10 in the solid state were determined. They are isostructural and are cubane-like structured. Low-temperature P-31H-1} NMR studies showed that the title complexes are dynamic in solution and exchange at room temperature their ligands. (C) 2010 Published by Elsevier B.V.
• Metal chelate exchange in the organic phase—III Extraction and exchange constants of dithizonates and oxinates
  作者：J starý

  DOI：10.1016/0039-9140(69)80024-x

  日期：1969.3

  Reactions between dithizonates and oxinates of Ag, Tl(I), Cu(II), Zn, Cd, Hg(II), Pb, Co(II), Ni, Pd, In, Ga and Bi in chloroform have been studied spectrophotometrically. From the exchange constants determined, the extraction constants of metal dithizonates or metal oxinates have been calculated. By this method extraction constants of many metal chelates can be calculated which are difficult to determine

  分光光度法研究了银，Tl（I），Cu（II），Zn，Cd，Hg（II），Pb，Co（II），Ni，Pd，In，Ga和Bi的双硫iz酸酯和含氧酸酯之间的反应。根据确定的交换常数，已计算出金属二硫氰酸盐或金属含氧酸盐的萃取常数。通过这种方法，可以计算出许多金属螯合物的萃取常数，这些常数很难通过研究水相和氯仿相之间的分布来确定。