9-[3]pyridyl-acridine | 120090-60-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 9-[3]pyridyl-acridine
• 英文别名: 9-[3]Pyridyl-acridin；9-Pyridin-3-ylacridine
• CAS: 120090-60-0
• 化学式: C₁₈H₁₂N₂
• 分子量: 256.307
• InChiKey: OEHBIJLLEOFRNN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  20
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  烟酸 、 二苯胺 在 zinc(II) chloride 作用下， 生成 9-[3]pyridyl-acridine
  参考文献：
  名称：

  Cook et al., Journal of the Chemical Society, 1943, p. 413,416

  摘要：

  DOI：

文献信息

• SUBSTITUTED ACRIDINE DERIVATIVES AND THEIR USE
  申请人：Hitachi Chemical Co., Ltd.

  公开号：EP0305545A1

  公开（公告）日：1989-03-08

  Substituted acridine derivatives represented by general formula (I) (wherein R,, R2, R3, R4, R5, R6, R7, and Ra each independently represents a hydrogen atom, an alkyl group, a substituted alkyl group, an aryl group, a substituted aryl group, a halogen atom or an alkoxy group, and Z1 represents a six-membered heterocyclic aromatic group containing one or two nitrogen atoms in the ring and optionally having a 1 ~ 8C alkyl substituent or a quinolyl group) and a photopolymerizable composition containing 0.01 to 10 parts by weight of said derivative, 100 parts by weight of a photopolymerizable compound having a boiling point of 100°C or above under ordinary pressure and having at least one ethylenically unsaturated group, and 0 to 400 parts by weight of a thermoplastic organic polymer are disclosed.

  通式(I)代表的取代吖啶衍生物 (其中 R、、R2、R3、R4、R5、R6、R7 和 Ra 各自独立地代表氢原子、烷基、取代的烷基、芳基、取代的芳基、卤素原子或烷氧基，Z1 代表在环中含有一个或两个氮原子的六元杂环芳基，并可选择地具有 1 ~ 8C 烷基取代基或醌基)和一种可光聚合的组合物，该组合物含有 0.本发明公开了一种可光聚合的组合物，该组合物含有0.01至10份重量的所述衍生物、100份重量的在常压下沸点为100°C或以上并具有至少一个乙烯不饱和基团的可光聚合化合物，以及0至400份重量的热塑性有机聚合物。
• Polymerization process characterized by a two layer coating against scale formation deposited using a steam carrier
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：EP0934955A1

  公开（公告）日：1999-08-11

  An improved process for producing a polymer by polymerizing a monomer having an ethylenic double bond in a polymerization vessel having a polymer scale preventive coating film on its inner wall surfaces, etc. is provided. The coating film is formed by coating a first coating liquid containing a compound selected from the group consisting of an aromatic compound having 5 or more conjugated π bonds and a heterocyclic compound having 5 or more conjugated π bonds, and then coating a second coating liquid on the first layer. The first and second coating liquids are applied by means of steam as a carrier. The second layer has a surface having a contact angle to water of less than 60° after its surface has been brought into contact with a solution of mixture of water and a vinyl chloride monomer in a weight ratio of 1:1, at 50°C for 1 hour. This process can shorten the time for forming the coating film to improve productivity, can improve the effect of preventing adhesion of polymer scale, can make colored particles less mix into polymer products obtained by this process, can lessen fish eyes and initial discoloring of formed products and can improve the quality of polymeric products and their formed or molded products.

  本发明提供了一种通过在聚合容器中聚合具有乙烯双键的单体来生产聚合物的改进工艺，该聚合容器的内壁表面等处具有聚合物防垢涂膜。该涂膜是通过涂覆第一涂覆液形成的，第一涂覆液含有选自具有 5 个或更多共轭 π 键的芳香族化合物和具有 5 个或更多共轭 π 键的杂环化合物的一组化合物，然后在第一层上涂覆第二涂覆液。第一种和第二种涂覆液通过蒸汽作为载体进行涂覆。第二层表面与水和氯乙烯单体重量比为 1:1 的混合物溶液在 50°C 下接触 1 小时后，其表面与水的接触角小于 60°。这种工艺可以缩短涂膜的形成时间，从而提高生产率；可以提高防止聚合物鳞片附着的效果；可以使有色颗粒较少地混入通过这种工艺获得的聚合物产品中；可以减少成型产品的鱼眼和初期褪色现象；可以提高聚合物产品及其成型或模塑产品的质量。
• Process for producing a polymer by polymerization of a monomer having an ethylenic double bond
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：EP1063242A1

  公开（公告）日：2000-12-27

  A process for producing a polymer by polymerizing in a polymerization vessel a monomer having an ethylenic double bond is provided. In this process, the polymerization vessel has a polymer scale preventive coating film on its inner wall surfaces and other surfaces with which the monomer comes into contact during polymerization. The coating film is formed by coating a first coating liquid containing a compound selected from the group consisting of an aromatic compound having 5 or more conjugated π bonds and a heterocyclic compound having 5 or more conjugated π bonds and a second coating liquid containing at least one hydrophilic compound selected from the group consisting of a water-soluble polymeric compound, an inorganic colloid, an inorganic salt and an acid; the first coating liquid and the second coating liquid being simultaneously coated by means of steam as a carrier. This process can shorten the time for forming coating films of scale preventive agents to improve productivity, can improve the effect of preventing scales, can make colored particles less mix into polymer products obtained by this process, can lessen fish eyes and initial discoloring of formed products and can improve the quality of polymeric products and their formed or molded products.

  提供了一种通过在聚合容器中聚合具有乙烯双键的单体来生产聚合物的工艺。在该工艺中，聚合容器的内壁表面和聚合过程中单体接触的其他表面上有一层聚合物防垢涂膜。涂膜是通过涂覆第一涂覆液和第二涂覆液形成的，第一涂覆液含有一种选自具有 5 个或更多共轭 π 键的芳香族化合物和具有 5 个或更多共轭 π 键的杂环化合物的化合物，第二涂覆液含有至少一种选自水溶性高分子化合物、无机胶体、无机盐和酸的亲水性化合物；第一涂覆液和第二涂覆液通过蒸汽作为载体同时涂覆。这种工艺可以缩短防垢剂形成涂膜的时间以提高生产率，可以提高防垢效果，可以使有色颗粒较少地混入通过该工艺获得的聚合物产品中，可以减少成型产品的鱼眼和初始变色，可以提高聚合物产品及其成型或模塑产品的质量。
• Polymerisation process in a reactor with double coating against scale formation
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：EP1043338A1

  公开（公告）日：2000-10-11

  An improved process for producing a polymer by polymerizing a monomer having an ethylenic double bond in a polymerization vessel having a polymer scale preventive coating film on its inner wall surfaces, etc. is provided. The coating film is formed by coating a first coating liquid containing a compound selected from the group consisting of an aromatic compound having 5 or more conjugated π bonds and a heterocyclic compound having 5 or more conjugated π bonds, and then coating a second coating liquid a dye and/or pigment on the first layer. The first and second coating liquids are applied by means of steam as a carrier. The second layer has a surface having a contact angle to water of less than 60° after its surface has been kept in contact with a solution of mixture of water and a vinyl chloride monomer in a weight ratio of 1:1 at 50° C for 1 hour. This process can shorten the time for forming the coating film to improve productivity, can improve the effect of preventing adhesion of polymer scale, can make colored particles less mix into polymer products obtained by this process, can lessen fish eyes and initial discoloring of formed products and can improve the quality of polymeric products and their formed or molded products.

  本发明提供了一种通过在聚合容器中聚合具有乙烯双键的单体来生产聚合物的改进工艺，该聚合容器的内壁表面等处具有聚合物防垢涂膜。涂膜的形成方法是在第一层涂上含有选自具有 5 个或更多共轭 π 键的芳香族化合物和具有 5 个或更多共轭 π 键的杂环化合物的化合物的第一涂膜液，然后在第一层上涂上染料和/或颜料的第二涂膜液。第一种和第二种涂布液是以蒸汽为载体涂布的。第二层表面与水和氯乙烯单体重量比为 1:1 的混合物溶液在 50 摄氏度下接触 1 小时后，其表面与水的接触角小于 60°。这种工艺可以缩短涂膜的形成时间以提高生产率，可以提高防止聚合物鳞片附着的效果，可以使有色颗粒较少地混入通过这种工艺获得的聚合物产品中，可以减少成型产品的鱼眼和初期褪色，可以提高聚合物产品及其成型或模塑产品的质量。
• Process for production of vinyl chloride polymer
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP0172427B1

  公开（公告）日：1989-07-05