4-acetylphenyl phenylcarbamate | 37070-86-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4-acetylphenyl phenylcarbamate
• 英文别名: 4-Acetylphenyl-N-phenylcarbamat；(4-acetylphenyl) N-phenylcarbamate
• CAS: 37070-86-3
• 化学式: C₁₅H₁₃NO₃
• 分子量: 255.273
• InChiKey: UWCOLNSWZMFWOH-UHFFFAOYSA-N

物化性质

• 沸点：
  396.6±34.0 °C(Predicted)
• 密度：
  1.239±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  55.4
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  碘苯 、 一氧化碳 、 对羟基苯乙酮 在 sodium azide 作用下， 以 1,4-二氧六环 为溶剂， 60.0 ℃ 、101.33 kPa 条件下， 反应 12.0h， 以77%的产率得到4-acetylphenyl phenylcarbamate
  参考文献：
  名称：

  Fe3O4 @ SiO2 / Schiff碱/ Pd络合物作为高效多相且可回收的纳米催化剂，用于一锅多米诺骨牌合成氨基甲酸酯和不对称尿素。

  摘要：

  通过一锅法使用容易获得且经济的起始原料（芳基卤化物，一氧化碳，叠氮化钠，胺和醇），已经开发了直接催化氨基甲酸酯和脲合成钯催化的多米诺骨牌方法。这种高效且无光气的工艺提供了一种廉价且诱人的途径，可以以良好的收率获得优良的合成产物。

  DOI：

  10.1002/ejoc.201901140

文献信息

• Cellulose Compound Film, Optical Compensation Sheet, Polarizing Plate, and Liquid Crystal Display Device
  申请人：Nozoe Yutaka

  公开号：US20070259134A1

  公开（公告）日：2007-11-08

  A cellulose compound film containing a cellulose compound having two or more substituents whose polarizability anisotropies Δα calculated by mathematical formula (1) are different from each other, wherein substitution degrees of the following substituents A and B in the cellulose compound satisfy relationship as defined by mathematical formula (A1), in which the substituent A has the lowest Δα and the substituent B has the highest Δα: Δ ⁢ ⁢ α = α ⁢ ⁢ x - α ⁢ ⁢ y + α ⁢ ⁢ z 2 Mathematical ⁢ ⁢ formula ⁢ ⁢ ( 1 ) wherein, in characteristic values obtained after diagonalization of polarizability tensor, αx is the largest component, αy is the second largest component, and αz is the smallest component; DS B 2+ DS B 3− DS B 6≧−0.1   Mathematical formula (A1) wherein DS B 2, DS B 3, and DS B 6 represent a substitution degree of the substituent B at the 2-, 3-, or 6-position of a β-glucose ring constituting unit of cellulose, respectively; and an optical compensation film, a polarizing plate, and a liquid crystal display device, using the cellulose compound film.

  一种纤维素化合物薄膜，其含有具有两个或更多取代基的纤维素化合物，其极化率各向异性Δα通过数学公式（1）计算得出，其中以下取代基A和B的取代度满足数学公式（A1）所定义的关系，其中取代基A具有最低的Δα，而取代基B具有最高的Δα：Δα = αx-αy + αz2数学公式（1）其中，在极化率张量对角化后获得的特征值中，αx是最大分量，αy是第二大分量，αz是最小分量;DSB2 + DSB3-DSB6≥-0.1数学公式（A1）其中DSB2、DSB3和DSB6分别表示取代基B在纤维素构成单位β-葡萄糖环的2-、3-或6-位置的取代度;以及使用该纤维素化合物薄膜的光学补偿膜、偏光板和液晶显示装置。
• Cellulose Acylate Film, Method of Producing the Same, Cellulose Derivative Film, Optically Compensatory Film Using the Same, Optically-Compensatory Film Incorporating Polarizing Plate, Polarizing Plate and Liquid Crystal Display Device
  申请人：Haruta Hiromoto

  公开号：US20090290100A1

  公开（公告）日：2009-11-26

  A method of producing a cellulose derivative film, the method comprising: forming a film with a solvent cast method from a dope including a cellulose derivative satisfying following conditions (a) and (b): (a) at least one among three hydroxyl groups included in a glucose unit of cellulose is substituted by a substituent of which a polarizability anisotropy Δα represented as following Expression (1) is 2.5×10 −24 cm 3 or higher: Expression (1): Δα=αx−(αy+αz)/2, wherein αx, αy and αz is as defined in the specification; and (b) when a substitution degree by a substituent of which Δα is 2.5×10 −24 cm 3 or higher is P A , and a substitution degree by a substituent of which Δα is lower than 2.5×10 −24 cm 3 is P B , the P A and P B satisfy following Expressions (3) and (4): Expression (3): 2P A +P B >3.0; and Expression (4): P A >0.2.

  一种生产纤维素衍生物薄膜的方法，该方法包括：使用包括满足以下条件（a）和（b）的纤维素衍生物的溶胶，通过溶剂浇铸法形成薄膜：（a）纤维素的葡萄糖单元中的三个羟基中的至少一个被取代为极化率各向异性Δα（以下表达式（1）表示）为2.5×10-24cm3或更高的取代基：表达式（1）：Δα=αx-（αy+αz）/ 2，其中αx，αy和αz如规范中定义的；并且（b）当Δα为2.5×10-24cm3或更高的取代基的取代度为PA时，Δα低于2.5×10-24cm3的取代基的取代度为PB，PA和PB满足以下表达式（3）和（4）：表达式（3）：2PA + PB> 3.0；表达式（4）：PA> 0.2。
• Transparent thermoplastic film and a method of producing the same
  申请人：Hashimoto Kiyokazu

  公开号：US20070275183A1

  公开（公告）日：2007-11-29

  A method of producing a transparent thermoplastic film comprising transversely stretching a film by 1% to 200%, wherein a ratio (Lc/Wc) of a clutch length (Lc) of a chuck to a clutch depth (Wc) of the chuck in the transverse stretching zone is in the range of 3 to 50.
• Method of producing transparent thermoplastic film and transparent thermoplastic film
  申请人：Hashimoto Kiyokazu

  公开号：US20070286998A1

  公开（公告）日：2007-12-13

  A method of producing a transparent thermoplastic film comprising transversely stretching a film by 1 to 200%, in which the ratio (L 2 /L 1 ) of a length (L 2 ) of a transverse stretching zone to a length (L 1 ) of a preheating zone is within the range of 0.5 to 30.
• Resin film, production method thereof, polarizing plate and liquid crystal display device
  申请人：Fukagawa Nobutaka

  公开号：US20070290168A1

  公开（公告）日：2007-12-20

  A resin film has a photoelastic coefficient of from 0 to 30×10 −8 cm 2 /N; and Re satisfying the following formulae (1) to (4): 20 nm< Re (548)<300 nm :   Formula (1) 0.5< Re (446)/ Re (548)<1 :   Formula (2) 1.0< Re (629)/ Re (548)<2.0 :   Formula (3) 0.1%≦[ Re (548) at 25° C., 10% RH− Re (548) at 25° C., 80% RH}/ Re (548) at 25° C., 60% RH]≦20%, :   Formula (4) wherein Re(λ) represents an in-plane retardation at a wavelength of λ.