O¹,O²;O³,O⁴;O⁵,O⁶-tricyclohexyLiDene-D-mannitol | 70167-57-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: O¹,O²;O³,O⁴;O⁵,O⁶-tricyclohexyLiDene-D-mannitol
• 英文别名: O¹,O²;O³,O⁴;O⁵,O⁶-Tricyclohexyliden-D-mannit；1,3:2,5:4,6-Tri-O-cyclohexylidene-D-mannitol；(2R,3R)-2,3-bis[(3R)-1,4-dioxaspiro[4.5]decan-3-yl]-1,4-dioxaspiro[4.5]decane
• CAS: 70167-57-6
• 化学式: C₂₄H₃₈O₆
• 分子量: 422.562
• InChiKey: WGMZNGZBEGHRHH-XRXFAXGQSA-N

物化性质

• 熔点：
  82-84 °C
• 沸点：
  499.14°C (rough estimate)
• 密度：
  1.0660 (rough estimate)
• 稳定性/保质期：
  遵照规定使用和储存，则不会发生分解。

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  30
• 可旋转键数：
  2
• 环数：
  6.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  55.4
• 氢给体数：
  0
• 氢受体数：
  6

安全信息

• 安全说明：
  S24/25
• 储存条件：
  应存于阴凉干燥处。

SDS

Name:	1 3:2 5:4 6-Tri-O-cyclohexylidene-D-mannitol 98% Material Safety Data Sheet
Synonym:	None Known
CAS:	70167-57-6

Section 1 - Chemical Product MSDS Name:1 3:2 5:4 6-Tri-O-cyclohexylidene-D-mannitol 98% Material Safety Data Sheet
Synonym:None Known

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Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
70167-57-6	1,3:2,5:4,6-Tri-O-cyclohexylidene-D-ma	98%	unlisted

Hazard Symbols: None Listed.
Risk Phrases: None Listed.

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Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

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Section 4 - FIRST AID MEASURES
Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove contaminated clothing and shoes. Get medical aid if irritation develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

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Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

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Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

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Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid contact with skin and eyes. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

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Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 70167-57-6: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

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Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 82 - 84 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density:
Molecular Formula:
Molecular Weight: 422.56

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Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.

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Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 70167-57-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1,3:2,5:4,6-Tri-O-cyclohexylidene-D-mannitol - Not listed by ACGIH, IARC, or NTP.

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Section 12 - ECOLOGICAL INFORMATION

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Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

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Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

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Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 70167-57-6: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 70167-57-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 70167-57-6 is not listed on the TSCA inventory.
It is for research and development use only.

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SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为反应物：
  描述：

  O¹,O²;O³,O⁴;O⁵,O⁶-tricyclohexyLiDene-D-mannitol 在 1,4-二氧六环 、 盐酸 、 乙醇 作用下， 生成 O3,O4-cyclohexylidene-D-mannitol
  参考文献：
  名称：

  Bourne et al., Journal of the Chemical Society, 1950, p. 786,788

  摘要：

  DOI：
• 作为产物：
  描述：

  甘露醇 、 环己酮 在 盐酸 作用下， 生成 O¹,O²;O³,O⁴;O⁵,O⁶-tricyclohexyLiDene-D-mannitol
  参考文献：
  名称：

  Bourne et al., Journal of the Chemical Society, 1950, p. 786,788

  摘要：

  DOI：

文献信息

• Kasimirowa, Zhurnal Obshchei Khimii, 1954, vol. 24, p. 626; engl. Ausg. S. 637
  作者：Kasimirowa

  DOI：——

  日期：——
• Process for production of sugar ketals
  申请人：Takeda Chemical Industries, Ltd.

  公开号：EP0139486B1

  公开（公告）日：1988-07-13
• US4659809A
  申请人：——

  公开号：US4659809A

  公开（公告）日：1987-04-21
• Bourne et al., Journal of the Chemical Society, 1950, p. 786,788
  作者：Bourne et al.

  DOI：——

  日期：——