(2S)-2-[(2S)-2-methylbutoxy]propan-1-ol | 146309-61-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (2S)-2-[(2S)-2-methylbutoxy]propan-1-ol
• CAS: 146309-61-7
• 化学式: C₈H₁₈O₂
• 分子量: 146.23
• InChiKey: GZQOBIOQBOEEDS-YUMQZZPRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  10
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (2S)-2-[(2S)-2-methylbutoxy]propan-1-ol 在 吡啶 、 氢氧化钾 作用下， 以 乙醇 、 水 为溶剂， 反应 240.0h， 生成 4-[2-(2-甲基-丁氧基)-丙氧基]-苯甲醛
  参考文献：
  名称：

  New Chiral Thiols and Related Side Chain Liquid Crystalline Polymers

  摘要：

  New series of chiral thiols with three aromatic rings and the N = N group in the molecular core have been synthesized and grafted on polybutadiene diols backbone. The resulting polymers possess the OH end groups for possible preparation of the liquid crystal ordered networks. Basic properties of the thiols and resulting polybutadiene diols have been studied by polarizing microscopy and differential scanning calorimetry. The resulting diol-based polymers show the liquid crystalline behaviour in a broad temperature range. The effect of the side chain structure and density of grafting on the properties of polybutadiene diols has been studied and discussed.

  DOI：

  10.1080/15421400701205628
• 作为产物：
  描述：

  (S)-1-iodo-2-methyl-butane 在 lithium aluminium tetrahydride 、 silver(l) oxide 作用下， 以 乙醚 为溶剂， 反应 56.0h， 生成 (2S)-2-[(2S)-2-methylbutoxy]propan-1-ol
  参考文献：
  名称：

  New Chiral Thiols and Related Side Chain Liquid Crystalline Polymers

  摘要：

  New series of chiral thiols with three aromatic rings and the N = N group in the molecular core have been synthesized and grafted on polybutadiene diols backbone. The resulting polymers possess the OH end groups for possible preparation of the liquid crystal ordered networks. Basic properties of the thiols and resulting polybutadiene diols have been studied by polarizing microscopy and differential scanning calorimetry. The resulting diol-based polymers show the liquid crystalline behaviour in a broad temperature range. The effect of the side chain structure and density of grafting on the properties of polybutadiene diols has been studied and discussed.

  DOI：

  10.1080/15421400701205628

文献信息

• US5366656A
  申请人：——

  公开号：US5366656A

  公开（公告）日：1994-11-22
• US5462695A
  申请人：——

  公开号：US5462695A

  公开（公告）日：1995-10-31
• New Chiral Thiols and Related Side Chain Liquid Crystalline Polymers
  作者：Alexej Bubnov、Miroslav Kašpar、Zdena Sedláková、Michal Ilavský

  DOI：10.1080/15421400701205628

  日期：2007.3.26

  New series of chiral thiols with three aromatic rings and the N = N group in the molecular core have been synthesized and grafted on polybutadiene diols backbone. The resulting polymers possess the OH end groups for possible preparation of the liquid crystal ordered networks. Basic properties of the thiols and resulting polybutadiene diols have been studied by polarizing microscopy and differential scanning calorimetry. The resulting diol-based polymers show the liquid crystalline behaviour in a broad temperature range. The effect of the side chain structure and density of grafting on the properties of polybutadiene diols has been studied and discussed.