tert-Butyl(dichloro)gallane | 135257-35-1

• 分子结构分类: 有机化合物 - 有机金属化合物 - 金属烷基卤化物
• 英文名称: tert-Butyl(dichloro)gallane
• CAS: 135257-35-1
• 化学式: C₄H₉Cl₂Ga
• 分子量: 197.744
• InChiKey: FBOMQYYHAMDELZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  2.75
• 重原子数：
  7
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,2-dipotassium-1,2-di-t-butylphosphanediide * 0.5 THF 、 tert-Butyl(dichloro)gallane 以 四氢呋喃 为溶剂， 以44%的产率得到
  参考文献：
  名称：

  Cowley, Alan H.; Jones, Richard A.; Mardones, Miguel A., Angewandte Chemie, 1991, vol. 103, # 9, p. 1163 - 1164

  摘要：

  DOI：

文献信息

• Novel dimeric ring systems containing gallium
  作者：Alan H. Cowley、David S. Brown、Andreas Decken、Smuruthi Kamepalli

  DOI：10.1039/cc9960002425

  日期：——

  A gallole (gallacyclopentadiene) is found to dimerise in a different fashion than boroles; the corresponding diazabutadiene complex is also dimeric.

  发现没食子酰二聚体（gallacyclopentadiene）以与硼杂环戊二烯不同的方式进行二聚化；相应的二氮杂丁二烯络合物也是二聚体。
• Dimeric gallium and indium dialkylphosphido complexes with unusual Group 13-15 stoichiometries
  作者：David A. Atwood、Vicki O. Atwood、Alan H. Cowley、Hala R. Gobran、Richard A. Jones、Tina M. Smeal、Carl J. Carrano

  DOI：10.1021/om00033a024

  日期：1993.9

  Three group 13 dialkylphosphido complexes have been prepared with group 13-15 stoichiometries of 1:2, [t-Bu(i-Pr2P)Ga(A-P-i-Pr2)]2 (1) and [i-Pr(i-Pr2P)In(mu-P-i-Pr2)]2 (2), and 2:3, [t-Bu(i-Pr2P)Ga(mu-P-i-Pr2)2Ga(Cl)t-Bu] (3). These complexes were prepared in moderate yields via the reaction of the appropriate lithium dialkylphosphide and alkyl group 13 halide in the desired stoichiometric ratio. Each compound has been characterized by elemental analysis, H-1 and P-31 NMR, and mass spectroscopy. The structures of 2 and 3 were established by X-ray crystallography. Crystal data for 2: space group P2(1)/c, a = 11.283(1) angstrom, b = 11.429(5) angstrom, c = 15.836(3) angstrom, beta = 104.19(1)-degrees, V = 1980(6) angstrom3, Z = 4, R = 0.0401. Crystal data for 3: space group P2(1)/c, a = 18.453(4) angstrom, b = 9.516(2) angstrom, c = 20.745(4) angstrom, beta = 106.88(3)-degrees, V = 3486(2) angstrom3, z = 8, R = 0.0551. Both compounds feature structures with four-membered M2P2 rings.