8-(3,3-Diethoxypropylsulfanyl)octan-1-ol | 1427195-73-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 8-(3,3-Diethoxypropylsulfanyl)octan-1-ol
• 英文别名: 8-(3,3-diethoxypropylsulfanyl)octan-1-ol
• CAS: 1427195-73-0
• 化学式: C₁₅H₃₂O₃S
• 分子量: 292.483
• InChiKey: ZQQQAIKNYIHGRF-UHFFFAOYSA-N

物化性质

• 沸点：
  394.4±42.0 °C(Predicted)
• 密度：
  0.972±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  19
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  64
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  8-(3,3-Diethoxypropylsulfanyl)octan-1-ol 在 水 、 对甲苯磺酸 作用下， 以 四氢呋喃 为溶剂， 反应 2.0h， 以80%的产率得到3-((8-hydroxyoctyl)thio)propanal
  参考文献：
  名称：

  Synthesis of (3E)-Dodecen-12-olide, a Potential Pheromone Component of the Emerald Ash Borer

  摘要：

  Emerald ash borer (EAB), Agrilus planipennis Fairmaire, is an invasive insect that has killed millions of ash trees in the USA and Canada. A concise synthesis of a potential EAB pheromone component, (3E)-dodecen-12-olide, using highly stereoselective JuliaKocienski olefination as the key step, is reported. Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications (R) to view the free supplemental file.

  DOI：

  10.1080/00397911.2011.634083
• 作为产物：
  描述：

  8-溴-1-辛醇 在 sodium iodide 、 sodium hydroxide 作用下， 以 甲醇 、 乙腈 为溶剂， 反应 48.5h， 生成 8-(3,3-Diethoxypropylsulfanyl)octan-1-ol
  参考文献：
  名称：

  Synthesis of (3E)-Dodecen-12-olide, a Potential Pheromone Component of the Emerald Ash Borer

  摘要：

  Emerald ash borer (EAB), Agrilus planipennis Fairmaire, is an invasive insect that has killed millions of ash trees in the USA and Canada. A concise synthesis of a potential EAB pheromone component, (3E)-dodecen-12-olide, using highly stereoselective JuliaKocienski olefination as the key step, is reported. Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications (R) to view the free supplemental file.

  DOI：

  10.1080/00397911.2011.634083

文献信息

• Synthesis of (3<i>E</i>)-Dodecen-12-olide, a Potential Pheromone Component of the Emerald Ash Borer
  作者：D. I. MaGee、P. D. Mayo、P. J. Silk、B. Beattie

  DOI：10.1080/00397911.2011.634083

  日期：2013.5.15

  Emerald ash borer (EAB), Agrilus planipennis Fairmaire, is an invasive insect that has killed millions of ash trees in the USA and Canada. A concise synthesis of a potential EAB pheromone component, (3E)-dodecen-12-olide, using highly stereoselective JuliaKocienski olefination as the key step, is reported. Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications (R) to view the free supplemental file.