4-ethylsulfanyl-quinoline | 4105-40-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 4-ethylsulfanyl-quinoline
• 英文别名: Quinoline, 4-(ethylthio)-；4-ethylsulfanylquinoline
• CAS: 4105-40-2
• 化学式: C₁₁H₁₁NS
• 分子量: 189.281
• InChiKey: TWFYQXCIOOHQID-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  38.2
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2933499090

反应信息

• 作为反应物：
  描述：

  4-ethylsulfanyl-quinoline 在 N-氯代丁二酰亚胺 作用下， 以 四氯化碳 为溶剂， 反应 1.0h， 以80%的产率得到4-(1-Chloro-ethylsulfanyl)-quinoline
  参考文献：
  名称：

  Sulfurization of Azines; Part IX. (1-Chloroalkylthio)-azines

  摘要：

  DOI：

  10.1055/s-1986-31795
• 作为产物：
  描述：

  4-羟基喹啉 在 吡啶 、 氢氧化钾 、 tetraphosphorus decasulfide 作用下， 以 甲苯 为溶剂， 反应 27.5h， 生成 4-ethylsulfanyl-quinoline
  参考文献：
  名称：

  Bsiri; Johnson; Kayirere, Annales Pharmaceutiques Francaises, 1996, vol. 54, # 1, p. 27 - 33

  摘要：

  DOI：

文献信息

• Water-insoluble colorant dispersion
  申请人：Fujifilm Corporation

  公开号：EP2236566A1

  公开（公告）日：2010-10-06

  A water-insoluble colorant dispersion, having: fine particles of a water-insoluble colorant, each of the fine particles containing at least two kinds of colorant; and a polymer compound having at least one repeating unit selected from the group consisting of repeating units represented by the following Formula (1) and (2); wherein, R6 to R8 each independently represent a hydrogen atom or a substituent; X- is an anion group balancing with the cation electric charge on the nitrogen atom; R1 represents a hydrogen atom or a substituent; J represents a specific divalent linking, an alkyl group, an aryl group, or an aralkyl group; W represents a single bond or a divalent linking group; R9 represents a hydrogen atom or a substituent; Q2 represents a group of atoms which is necessary for forming an unsaturated ring together with a carbon atom and a nitrogen atom.

  一种水不溶性着色剂分散体，具有 水不溶性着色剂的细颗粒，每个细颗粒至少含有两种着色剂；以及 聚合物化合物，其至少一个重复单元选自下式（1）和（2）所代表的重复单元组； 其中，R6 至 R8 各自独立地代表氢原子或取代基；X- 是与氮原子上的阳离子电荷平衡的阴离子基团；R1 代表氢原子或取代基；J 代表特定的二价连接、烷基、芳基或芳烷基；W 代表单键或二价连接基团；R9 代表氢原子或取代基；Q2 代表与碳原子和氮原子一起形成不饱和环所必需的原子团。
• Synthesis and antibacterial activity of new 4-alkoxy, 4-aminoalkyl and 4-alkylthioquinoline derivatives
  作者：Marie-Gratia Kayirere、Abdallah Mahamoud、Jacqueline Chevalier、Jean-Claude Soyfer、Andrée Crémieux、Jacques Barbe

  DOI：10.1016/s0223-5234(99)80076-2

  日期：1998.1

  4-Alkoxy-8-methyl-7-nitroquinolines, 4-alkylamino-8-methyl-7-nitroquinolines, 4-alkoxy-2,8-dimethylquinolines, 4-alkylthioquinolines were prepared from 8-methyl-7-nitro-4-quinolone, 8-methyl-7-nitro-4-chloro-quinoline, 2,8-dimethyl-4-quinolone and 4-hydroxyquinoline used as starting material. Compounds were characterized from H-1 and C-13 NMR spectra. These drugs were tested against selected gram-, gram+ and mycobacteria strains. A promising activity was observed against Mycobacterium smegmatis. (C) Elsevier, Paris.
• Complex base-induced generation of 3,4-dehydroquinoline: a new access to quinoline derivatives
  作者：Stéphanie Blanchard、Gérald Guillaumet、Paul Caubère

  DOI：10.1016/s0040-4039(01)01339-9

  日期：2001.10

  3,4-Dehydroquinoline was easily generated from 3-bromoquinoline and a complex base NaNH2-tBuONa. Nucleophilic condensation of amines and thiolates were performed in good yields. (C) 2001 Elsevier Science Ltd. All rights reserved.
• MASLANKIEWICZ A.; SKRZYPEK L., SYNTHESIS,(1986) N 10, 835-839
  作者：MASLANKIEWICZ A.、 SKRZYPEK L.

  DOI：——

  日期：——
• WATER-INSOLUBLE COLORANT DISPERSION
  申请人：SAITO Ryo

  公开号：US20100247878A1

  公开（公告）日：2010-09-30

  A water-insoluble colorant dispersion, having: fine particles of a water-insoluble colorant, each of the fine particles containing at least two kinds of colorant; and a polymer compound having at least one repeating unit selected from the group consisting of repeating units represented by the following Formula (1) and (2); wherein, R 6 to R 8 each independently represent a hydrogen atom or a substituent; X − is an anion group balancing with the cation electric charge on the nitrogen atom; R 1 represents a hydrogen atom or a substituent; J represents a specific divalent linking, an alkyl group, an aryl group, or an aralkyl group; W represents a single bond or a divalent linking group; R 9 represents a hydrogen atom or a substituent; Q 2 represents a group of atoms which is necessary for forming an unsaturated ring together with a carbon atom and a nitrogen atom.