2-Methyl-6-hepten-1,2-diol | 103618-47-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 2-Methyl-6-hepten-1,2-diol
• 英文别名: 2-methylhept-6-ene-1,2-diol
• CAS: 103618-47-9
• 化学式: C₈H₁₆O₂
• 分子量: 144.214
• InChiKey: ISKPMQXXVPVALE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  10
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-Methyl-6-hepten-1,2-diol 在 palladium dichloride copper dichloride 作用下， 以 乙二醇二甲醚 为溶剂， 以50%的产率得到(1S,5R)-1,5-二甲基-6,8-二氧杂双环[3.2.1]辛烷
  参考文献：
  名称：

  到 (±)-FRONTALIN 的便捷合成路线

  摘要：

  (±)-Frontalin 从乙酰乙酸乙酯开始，包括使用氯化钯作为催化剂的分子内环化，以几个步骤顺序合成。

  DOI：

  10.1246/cl.1985.1849
• 作为产物：
  描述：

  庚-6-烯-2-酮 在 硫酸 、 三甲基碘化亚砜 、 sodium hydride 作用下， 以 四氢呋喃 、 二甲基亚砜 为溶剂， 反应 1.0h， 生成 2-Methyl-6-hepten-1,2-diol
  参考文献：
  名称：

  到 (±)-FRONTALIN 的便捷合成路线

  摘要：

  (±)-Frontalin 从乙酰乙酸乙酯开始，包括使用氯化钯作为催化剂的分子内环化，以几个步骤顺序合成。

  DOI：

  10.1246/cl.1985.1849

文献信息

• Multifunctional curing agents and their use in improving strength of composites containing carbon fibers embedded in polymeric matrix
  申请人：UT-Battelle, LLC

  公开号：US10240011B2

  公开（公告）日：2019-03-26

  A functionalized carbon fiber having covalently bound on its surface a sizing agent containing epoxy groups, at least some of which are engaged in covalent bonds with crosslinking molecules, wherein each of said crosslinking molecules possesses at least two epoxy-reactive groups and at least one free functional group reactive with functional groups of a polymer matrix in which the carbon fiber is to be incorporated, wherein at least a portion of said cros slinking molecules are engaged, via at least two of their epoxy-reactive groups, in crosslinking bonds between at least two epoxy groups of the sizing agent. Composites comprised of these functionalized carbon fibers embedded in a polymeric matrix are also described. Methods for producing the functionalized carbon fibers and composites thereof are also described.

  一种功能化碳纤维，其表面共价结合了一种含有环氧基团的上浆剂，其中至少有一部分与交联分子以共价键结合，其中每个交联分子都具有至少两个环氧反应基团和至少一个与碳纤维所结合的聚合物基体的官能团反应的自由官能团、其中，至少有一部分所述交联分子通过至少两个环氧反应基团参与上浆剂的至少两个环氧基团之间的交联键。此外，还介绍了由嵌入聚合物基体中的这些功能化碳纤维组成的复合材料。此外，还介绍了生产功能化碳纤维及其复合材料的方法。
• MULTIFUNCTIONAL CURING AGENTS AND THEIR USE IN IMPROVING STRENGTH OF COMPOSITES CONTAINING CARBON FIBERS EMBEDDED IN A POLYMERIC MATRIX
  申请人：UT-BATTELLE, LLC

  公开号：US20160102180A1

  公开（公告）日：2016-04-14

  A functionalized carbon fiber having covalently bound on its surface a sizing agent containing epoxy groups, at least some of which are engaged in covalent bonds with crosslinking molecules, wherein each of said crosslinking molecules possesses at least two epoxy-reactive groups and at least one free functional group reactive with functional groups of a polymer matrix in which the carbon fiber is to be incorporated, wherein at least a portion of said crosslinking molecules are engaged, via at least two of their epoxy-reactive groups, in crosslinking bonds between at least two epoxy groups of the sizing agent. Composites comprised of these functionalized carbon fibers embedded in a polymeric matrix are also described. Methods for producing the functionalized carbon fibers and composites thereof are also described.
• MULTIFUNCTIONAL CURING AGENTS AND THEIR USE IN IMPROVING STRENGTH OF COMPOSITES CONTAINING CARBON FIBERS EMBEDDED IN POLYMERIC MATRIX
  申请人：UT-Battelle, LLC

  公开号：US20170166712A1

  公开（公告）日：2017-06-15

  A functionalized carbon fiber having covalently bound on its surface a sizing agent containing epoxy groups, at least some of which are engaged in covalent bonds with crosslinking molecules, wherein each of said crosslinking molecules possesses at least two epoxy-reactive groups and at least one free functional group reactive with functional groups of a polymer matrix in which the carbon fiber is to be incorporated, wherein at least a portion of said cros slinking molecules are engaged, via at least two of their epoxy-reactive groups, in crosslinking bonds between at least two epoxy groups of the sizing agent. Composites comprised of these functionalized carbon fibers embedded in a polymeric matrix are also described. Methods for producing the functionalized carbon fibers and composites thereof are also described.
• US9617398B2
  申请人：——

  公开号：US9617398B2

  公开（公告）日：2017-04-11
• CONVENIENT SYNTHETIC ROUTE TO (±)-FRONTALIN
  作者：Boonsong Kongkathip、Rongsan Sookkho、Ngampong Kongkathip

  DOI：10.1246/cl.1985.1849

  日期：1985.12.5

  (±)-Frontalin was synthesized in a few steps sequence starting from ethyl acetoacetate involving intramolecular cyclization using palladium chloride as catalyst.

  (±)-Frontalin 从乙酰乙酸乙酯开始，包括使用氯化钯作为催化剂的分子内环化，以几个步骤顺序合成。

表征谱图