1-isopropyl-3-methyl-1H-imidazol-3-ium chloride | 139143-10-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 1-isopropyl-3-methyl-1H-imidazol-3-ium chloride
• 英文别名: 3-(1-methylethyl)-1-methylimidazolium chloride；1-Methyl-3-propan-2-ylimidazol-1-ium;chloride；1-methyl-3-propan-2-ylimidazol-1-ium;chloride
• CAS: 139143-10-5
• 化学式: C₇H₁₃N₂*Cl
• 分子量: 160.647
• InChiKey: RWJZHFSZXGTPPB-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -2.1
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  8.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-isopropyl-3-methyl-1H-imidazol-3-ium chloride 在 氟硼酸钠 作用下， 以 水 为溶剂， 反应 0.25h， 以19%的产率得到3-(1-甲基乙基)-1-甲基咪唑四氟硼酸盐
  参考文献：
  名称：

  Influence of different branched alkyl side chains on the properties of imidazolium-based ionic liquids

  摘要：

  在微波辐射下采用两种不同的合成方法合成了几种新的分支离子液体。将不同的已知离子液体（包括线性和分支型）加入到这一组新的离子液体中，以研究分支对热物理性质的影响，从而揭示第一结构与性质之间的关系。利用热重分析法研究了分解行为，差示扫描量热法用于研究分支对热行为的影响，例如熔点、玻璃转变温度、冰点和冷结晶温度。此外，还分析了所选离子液体的水吸收情况。

  DOI：

  10.1039/b807119e
• 作为产物：
  描述：

  N-甲基咪唑 、 2-氯丙烷 以28%的产率得到1-isopropyl-3-methyl-1H-imidazol-3-ium chloride
  参考文献：
  名称：

  Influence of different branched alkyl side chains on the properties of imidazolium-based ionic liquids

  摘要：

  在微波辐射下采用两种不同的合成方法合成了几种新的分支离子液体。将不同的已知离子液体（包括线性和分支型）加入到这一组新的离子液体中，以研究分支对热物理性质的影响，从而揭示第一结构与性质之间的关系。利用热重分析法研究了分解行为，差示扫描量热法用于研究分支对热行为的影响，例如熔点、玻璃转变温度、冰点和冷结晶温度。此外，还分析了所选离子液体的水吸收情况。

  DOI：

  10.1039/b807119e

文献信息

• Selenium-<i>N</i>-heterocyclic carbene (Se-NHC) complexes with higher aromaticity inhibit microbes: synthesis, structure, and biological potential
  作者：Amna Kamal、Muhammad Adnan Iqbal、Haq Nawaz Bhatti、Abdul Ghaffar

  DOI：10.1080/00958972.2022.2101921

  日期：2022.7.18

  Abstract The synthesis of five selenium complexes bearing imidazole-based N-heterocyclic carbene ligands (Se-NHC) are reported. The adducts were characterized by elemental and spectroscopic analysis (FTIR, 1H and 13C NMR). Single-crystal XRD confirmed the structures of two Se-NHC adducts, VIII and XI. Zone of inhibition (ZOI) values of Se-NHC complexes were evaluated towards two bacterial (Bacillus

  摘要 报道了五种带有咪唑基N-杂环卡宾配体 (Se-NHC) 的硒配合物的合成。通过元素和光谱分析（FTIR、1 H 和13 C NMR）对加合物进行表征。单晶 XRD 证实了两种 Se-NHC 加合物VIII和XI的结构。Se-NHC 复合物的抑制区 (ZOI) 值针对两种细菌（苏云金芽孢杆菌和大肠杆菌）和一种真菌菌株（白色念珠菌）进行了评估。最活跃的测试化合物是XI ，对大肠杆菌的抑制值为 24.1 ± 0.1 mm，并且比四环素（参比药物）显示出更高的活性。同样，XI对白色念珠菌表现出良好的抑制潜力(26.5 ± 0.2 mm)。溶血试验证明受试​​化合物（Ⅷ - Ⅻ）对健康人体血液无毒；然而，溶栓表明VIII - XII可用作潜在的溶栓剂。得出的结论是，在咪唑的末端氮原子上具有更多芳环的 Se-NHC 卡宾加合物比其他测试的化合物更有效。Se-NHC 化合物对细菌菌株比真菌菌株更有效。
• PROCESSES FOR PRODUCING SILK DOPE
  申请人：Commonwealth Scientific and Industrial Research Organisation

  公开号：EP2475677A1

  公开（公告）日：2012-07-18
• PRODUCT PREPARATION AND RECOVERY FROM THERMOLYSIS OF LIGNOCELLULOSICS IN IONIC LIQUIDS
  申请人：Argyropoulos Dimitris

  公开号：US20080185112A1

  公开（公告）日：2008-08-07

  The present invention provides methods for the thermolysis of lignocellulosic materials, such as wood, cellulose, lignin, and lignocellulose. In specific embodiments, the methods comprise combining the lignocellulosic material with an ionic liquid and subjecting the mixture of the lignocellulosic material and the ionic media to pyrolytic conditions to form a recoverable product, such as a commodity chemical.
• POLYMER DERIVATIVES AND COMPOSITES FROM THE DISSOLUTION OF LIGNOCELLULOSICS IN IONIC LIQUIDS
  申请人：Argyropoulos Dimitris

  公开号：US20080188636A1

  公开（公告）日：2008-08-07

  The present invention provides wood derivatives and composite materials prepared by first solvating a lignocellulosic material using an ionic liquid. The solvated lignocellulosic material can be derivatized to incorporate functional groups, particularly groups that facilitate later combination with polymer materials, including non-polymer polymers. The polymeric materials can be combined with the derivatized lignocellulosic material in solution, or the derivatized lignocellulosic material can be isolated and later combined with the polymeric material in a melt. The invention encompasses a variety of wood derivatives, composites, and nanocomposites useful for preparing multiple types of products, including membranes, fibers, and formed parts.
• USE OF LIGNOCELLULOSICS SOLVATED IN IONIC LIQUIDS FOR PRODUCTION OF BIOFUELS
  申请人：Argyropoulos Dimitris

  公开号：US20080190013A1

  公开（公告）日：2008-08-14

  The present invention provides a method for converting lignocellulosic material into biofuel. In particular embodiments, the method comprises pre-treating lignocellulosic material by dissolving the material in ionic liquids. The pretreated lignocellulosic material can be isolated, such as by precipitation with a regenerating solvent (e.g., water), and be used directly in the formation of biofuel, including undergoing hydrolysis to form sugar and fermentation to form fuel, such as bioethanol. The ionic liquid can be recycled for further use, such as by evaporation of the water introduced during precipitation, and the recycling provides a route to a hemicellulose rich fraction and an ionic liquid of consistent quality and wood dissolution characteristics. The recovered hemicelluloses are of significant utilization potential toward commodity and specialty applications.