6-methylbenzo[h]quinoline | 31485-96-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 6-methylbenzo[h]quinoline
• 英文别名: 6-methylbenzoquinoline；6-methyl-benzo[h]quinoline；6-Methyl-benzo[h]chinolin；6-Methyl-benzochinolin；6-Methylbenzochinolin
• CAS: 31485-96-8
• 化学式: C₁₄H₁₁N
• mdl: MFCD18448693
• 分子量: 193.248
• InChiKey: ODFBIVRQPJHBPH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  15
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.071
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 海关编码：
  2933990090

反应信息

• 作为反应物：
  描述：

  6-methylbenzo[h]quinoline 、 iridium(III) chloride 、 水 、 三苯基膦 以 乙二醇乙醚 为溶剂， 反应 30.0h， 以86%的产率得到
  参考文献：
  名称：

  苯并喹啉三苯基膦环铱氢加合物及其制备方法 和用途

  摘要：

  本发明公开了一类苯并喹啉三苯基膦环铱氢加合物，该类化合物具有如下通式：，其中R为H、-CH3、-OCH3、-C6H5或-CHO，R位于苯并喹啉的3、5、6或8的位置；该类化合物的制备步骤为：取苯并喹啉衍生物、三氯化铱和三苯基膦加入到溶剂中，在气体保护下加热回流，反应结束后过滤即得。制得的苯并喹啉三苯基膦环铱氢加合物是高活性的催化剂，催化芳基炔和芳基苄醇反应，得到芳基酮化合物。以苯并喹啉衍生物三苯基膦环铱氢加合物为金属催化剂，催化剂用量小，用便宜的弱碱，就能高效催化芳基炔和芳基苄醇反应。该方法具有反应条件温和，反应底物范围广，经济高效等优点，具有重要的应用价值。

  公开号：

  CN103242372B
• 作为产物：
  描述：

  1-萘胺 在 硫酸 、 砷酸、原砷酸 作用下， 生成 6-methylbenzo[h]quinoline
  参考文献：
  名称：

  Buu-Hoi; Guettier, Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1946, vol. 222, p. 665

  摘要：

  DOI：

文献信息

• CONDENSED CYCLIC COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME
  申请人：Samsung Display Co., Ltd.

  公开号：US20180097186A1

  公开（公告）日：2018-04-05

  A condensed cyclic compound and an organic light-emitting device including the same are provided. The organic light-emitting device includes a first electrode, a second electrode, and an organic layer disposed between the first electrode and the second electrode. The organic layer includes the condensed cyclic compound represented by Formula 1: in Formula 1, A 11 is a C 1 -C 60 heterocyclic group, A 12 is a C 5 -C 60 carbocyclic group or a C 1 -C 60 heterocyclic group, X 11 is O or S, X 12 is C, X 13 is selected from N, C, and C(R 13 ), X 14 is selected from N, C, and C(R 14 ), and X 13 and X 14 are linked via a single bond or a double bond.

  提供一种浓缩的环状化合物和包括该化合物的有机发光器件。有机发光器件包括第一电极、第二电极和位于第一电极和第二电极之间的有机层。有机层包括由式1表示的浓缩的环状化合物：在式1中，A11是C1-C60杂环基团，A12是C5-C60碳环基团或C1-C60杂环基团，X11是O或S，X12是C，X13选自N、C和C(R13)，X14选自N、C和C(R14)，X13和X14通过单键或双键连接。
• Process for the preparation of furopyrroles
  申请人：Riggs Lewis Richard

  公开号：US20070100135A1

  公开（公告）日：2007-05-03

  The present invention relates to a process for the preparation of furopyrroles of general formula (I), comprising (a) heating a compound of the formula (II) under microwave irradiation optionally in the presence of an inert solvent, wherein A 1 and A 2 are C 1 -C 18 alkyl, C 2 -C 18 alkenyl, C 2 -C 18 alkynyl, C 5 -C 8 cycloalkyl, C 5- C 8 cycloalkenyl, aryl or heteroaryl, A 3 is hydrogen, C 1 -C 18 alkyl, cyanomethyl, Ar 3 , —CR 30 R 31 —(CH 2 ) m —Ar 3 or Y—R 32 , wherein R 30 and R 31 independently of each other stand for hydrogen or C 1 -C 4 alkyl, or phenyl which can be substitute up to three times with C 1 -C 4 alkyl, Ar 3 stands for aryl, C 5 -C 8 cloalkyl, C 5 -C 8 cycloalkenyl or heteroaryl, which can be substituted one to three times with C 1 -C 9 alkyl, C 1 -C 8 alkoxy, halogen or phenyl, which can be substituted with C 1 -C 8 alkyI or C 1 -C 8 alkoxy one to three times, and m stands for 0, 1, 2, 3 or 4, R is C 1‘-C 18 alkyl, in particular C 1 -C 4 alkyl, aryl, in particular phenyl, or aralkyl, in particular benzyl, which can be substituted one to three times with C 1 -C 8 alkyl, C 1 -C 8 alkoxy, or halogen, Y is —C(O)—, —C(O)O—, —C(O)NH—, —SO 2 NH— or —SO 2 — and R 32 is C 1 -C 18 alkyl, Ar 3 , or aralkyl. The furopyrroles of the general formula (I) can be can be obtained in high yield and high purity by the process of the present invention.

  本发明涉及一种制备一般式（I）的呋喃吡咯的过程，包括（a）在微波辐射下加热公式（II）的化合物，可选地在惰性溶剂的存在下，其中A1和A2为C1-C18烷基，C2-C18烯基，C2-C18炔基，C5-C8环烷基，C5-C8环烯基，芳基或杂环基，A3为氢，C1-C18烷基，氰甲基，Ar3，—CR30R31—（CH2）m—Ar3或Y—R32，其中R30和R31相互独立地代表氢或C1-C4烷基，或苯基，可以用C1-C4烷基取代最多三次，Ar3代表芳基，C5-C8环烷基，C5-C8环烯基或杂环基，可以用C1-C9烷基，C1-C8烷氧基，卤素或苯基取代一到三次，可以用C1-C8烷基或C1-C8烷氧基取代一到三次，m为0，1，2，3或4，R为C1'-C18烷基，特别是C1-C4烷基，芳基，特别是苯基，或芳基烷基，特别是苄基，可以用C1-C8烷基，C1-C8烷氧基或卤素取代一到三次，Y为—C（O）—，—C（O）O—，—C（O）NH—，—SO2NH—或—SO2—，R32为C1-C18烷基，Ar3或芳基烷基。通过本发明的方法可以高产高纯度得到一般式（I）的呋喃吡咯。
• Luminescent Cyclometallated Iridium(III) Complexes Having Acetylide Ligands
  申请人：Thompson Mark E.

  公开号：US20120007061A1

  公开（公告）日：2012-01-12

  The present invention relates to phosphorescent (triplet-emitting) organometallic materials. The phosphorescent materials of the present invention comprise Ir(III)cyclometallated alkynyl complexes for use as triplet light-emitting materials. The Ir(III)cyclometallated alkynyl complexes comprise at least one cyclometallating ligand and at least one alkynyl ligand bonded to the iridium. Also provided is an organic light emitting device comprising an anode, a cathode and an emissive layer between the anode and the cathode, wherein the emissive layer comprises a Ir(III)cyclometallated alkynyl complex as a triplet emitting material.

  本发明涉及磷光（三重态发射）有机金属材料。本发明的磷光材料包括Ir（III）环金属炔基络合物，用作三重态发射材料。Ir（III）环金属炔基络合物包括至少一个环金属配体和至少一个与铱键合的炔基配体。还提供了一种有机发光器件，包括阳极、阴极和位于阳极和阴极之间的发射层，其中发射层包括Ir（III）环金属炔基络合物作为三重态发射材料。
• Luminescent Cyclometallated Iridium (III) Complexes Having Acetylide Ligands
  申请人：The University of Southern California

  公开号：US20150076470A1

  公开（公告）日：2015-03-19

  The present invention relates to phosphorescent (triplet-emitting) organometallic materials. The phosphorescent materials of the present invention comprise Ir(III)cyclometallated alkynyl complexes for use as triplet light-emitting materials. The Ir(III)cyclometallated alkynyl complexes comprise at least one cyclometallating ligand and at least one alkynyl ligand bonded to the iridium. Also provided is an organic light emitting device comprising an anode, a cathode and an emissive layer between the anode and the cathode, wherein the emissive layer comprises a Ir(III)cyclometallated alkynyl complex as a triplet emitting material.

  本发明涉及磷光（三重态发射）有机金属材料。本发明的磷光材料包括用作三重态发射材料的Ir（III）环金属化炔基配合物。Ir（III）环金属化炔基配合物包括至少一个环金属配体和至少一个与铱键合的炔基配体。还提供了一种有机发光器件，包括阳极、阴极和位于阳极和阴极之间的发射层，其中发射层包括Ir（III）环金属化炔基配合物作为三重态发射材料。
• <i>N</i>-Heterocyclization of Naphthylamines with 1,2- and 1,3-Diols Catalyzed by an Iridium Chloride/BINAP System
  作者：Hiroomi Aramoto、Yasushi Obora、Yasutaka Ishii

  DOI：10.1021/jo801966u

  日期：2009.1.16

  Benzoquinoline derivatives were successfully synthesized by iridium-catalyzed N-heterocyclization of naphthylamines with diols. For instance, the reaction of 1-naphthylamine with 1,3-propanediol catalyzed by IrCl3 combined with BINAP as a ligand produced 7,8-benzoquinoline in quantitative yield. The N-heterocyclization reaction was found to be markedly influenced by the ligands employed. Benzoindoles were also synthesized by the same strategy from napthylamines with 1,2-diols. A reaction mechanism for the N-heterocyclization of naphthylamines with 1,3-diols by IrCl3 was proposed.