2-iso-propyl-4,5-di-(1,1-dimethylpropyl)imidazole | 1352427-57-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 2-iso-propyl-4,5-di-(1,1-dimethylpropyl)imidazole
• 英文别名: 4,5-bis(2-methylbutan-2-yl)-2-propan-2-yl-1H-imidazole
• CAS: 1352427-57-6
• 化学式: C₁₆H₃₀N₂
• 分子量: 250.428
• InChiKey: RQXLVVFAUXLLBE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  18
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.81
• 拓扑面积：
  28.7
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2-氯代-2-甲基丁烷 在 copper(I) bromide 、 lithium bromide ammonium acetate 、 magnesium 、 溶剂黄146 作用下， 以 四氢呋喃 为溶剂， 反应 48.0h， 生成 2-iso-propyl-4,5-di-(1,1-dimethylpropyl)imidazole
  参考文献：
  名称：

  [EN] COMPLEXES OF IMIDAZOLE LIGANDS
  [FR] COMPLEXES DE LIGANDS IMIDAZOLES

  摘要：

  金属咪唑酸盐配合物的描述中，描述了咪唑配体上带有大体积基团的功能化咪唑和它们的阴离子对应物，即咪唑酸盐。考虑到由一个或多个这种多烷基化咪唑阴离子配位到一种或多种金属的化合物，所述金属选自碱金属、过渡金属、镧系金属、锕系金属、主族金属，包括硫属元素。或者，可以将多种不同的咪唑阴离子以及其他不同的阴离子配位到金属上以形成新的配合物。还考虑到合成新化合物并将其用于形成含金属薄膜的用途。

  公开号：

  WO2011156699A1

文献信息

• Volatile Imidazoles and Group 2 Imidazole Based Metal Precursors
  申请人：Norman John Anthony Thomas

  公开号：US20120035351A1

  公开（公告）日：2012-02-09

  Sterically hindered imidazole ligands are described, along with their synthesis, which are capable of coordinating to Group 2 metals, such as: calcium, magnesium, strontium, in an eta-5 coordination mode which permits the formation of monomeric or dimeric volatile complexes. A compound comprising one or more polysubstituted imidazolate anions coordinated to a metal selected from the group consisting of barium, strontium, magnesium, radium or calcium or mixtures thereof. Alternatively, one anion can be substituted with and a second non-imidazolate anion. Synthesis of the novel compounds and their use to form BST films is also contemplated

  具有立体位阻的咪唑配体被描述，以及它们的合成，这些配体能够与2族金属（如：钙、镁、锶）配位形成η-5配位模式，从而形成单聚或二聚挥发性络合物。 一种化合物包括一个或多个多取代咪唑酸根离子与从钡、锶、镁、镭、钙或其混合物中选择的金属配位。或者，一个阴离子可以被取代为第二个非咪唑酸根离子。 还考虑了这些新化合物的合成以及它们用于形成BST薄膜的用途。
• Complexes Of Imidazole Ligands
  申请人：Norman John Anthony Thomas

  公开号：US20120121806A1

  公开（公告）日：2012-05-17

  Metal imidazolate complexes are described where imidazoles ligands functionalized with bulky groups and their anionic counterpart, i.e., imidazolates are described. Compounds comprising one or more such polyalkylated imidazolate anions coordinated to a metal or more than one metal, selected from the group consisting of alkali metals, transition metals, lanthanide metals, actinide metals, main group metals, including the chalcogenides, are contemplated. Alternatively, multiple different imidazole anions, in addition to other different anions, can be coordinated to metals to make new complexes. The synthesis of novel compounds and their use to form thin metal containing films is also contemplated.

  本文描述了具有大体积基团的咪唑配体及其阴离子对应物即咪唑酸盐的金属咪唑酸盐络合物。本文考虑了由一种或多种这种多烷基化咪唑酸盐阴离子与一种或多种金属（包括碱金属、过渡金属、稀土金属、锕系金属、主族金属和硫属化物）配位而成的化合物。此外，还可以将多种不同的咪唑酸盐阴离子与其他不同的阴离子配位到金属上，以制备新的络合物。本文还考虑了合成新化合物并将其用于形成含金属薄膜的用途。
• Volatile imidazoles and group 2 imidazole based metal precursors
  申请人：Air Products and Chemicals, Inc.

  公开号：EP2371821A1

  公开（公告）日：2011-10-05

  Sterically hindered imidazole ligands are described, along with their synthesis, which are capable of coordinating to Group 2 metals, such as: calcium, magnesium, strontium, in an eta-5 coordination mode which permits the formation of monomeric or dimeric volatile complexes. A compound comprising one or more polysubstituted imidazolate anions coordinated to a metal selected from the group consisting of barium, strontium, magnesium, radium or calcium or mixtures thereof. Alternatively, one anion can be substituted with and a second non-imidazolate anion. Synthesis of the novel compounds and their use to form BST films is also contemplated

  描述了可与第 2 组金属（如钙、镁、锶）以 eta-5 配位模式配位的立体受阻咪唑配体及其合成方法，这种配体可形成单体或二聚体挥发性络合物。 由一个或多个与选自钡、锶、镁、镭或钙或其混合物的金属配位的多取代咪唑啉阴离子组成的化合物。或者，一个阴离子可以被第二个非咪唑酸阴离子取代。 还可考虑合成新型化合物并将其用于形成 BST 薄膜
• Group 2 Imidazolate Formulations for Direct Liquid Injection
  申请人：Air Products and Chemicals, Inc.

  公开号：EP2644284A1

  公开（公告）日：2013-10-02

  A composition comprising group 2 imidazolate compounds which are coordinated to suitable neutral donor ligand molecules to provide group 2 metal complexes that are highly soluble in hydrocarbon solvents. In one embodiment, the composition is used for the direct liquid injection delivery of the group 2 precursor to the chamber of an ALD or CVD chamber for the deposition of group 2 containing thin films such as, for example, STO and BST films.

  一种由 2 族咪唑酸盐化合物组成的组合物，该化合物与合适的中性供体配体分子配位，以提供高度溶于烃类溶剂的 2 族金属络合物。在一个实施方案中，该组合物用于将 2 族前驱体直接液注输送到 ALD 或 CVD 室的腔室中，以沉积含有 2 族的薄膜，例如 STO 和 BST 薄膜。
• COMPLEXES OF IMIDAZOLE LIGANDS
  申请人：Air Products and Chemicals, Inc.

  公开号：EP2580223A1

  公开（公告）日：2013-04-17