Trimethyl 4-nonanone | 1170160-95-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Trimethyl 4-nonanone
• 英文别名: 2,2-dimethyldecan-5-one
• CAS: 1170160-95-8
• 化学式: C₁₂H₂₄O
• 分子量: 184.322
• InChiKey: LXXGRJVKKUPXQR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  13
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3,3-二甲基-1-丁烯 、 正己醛 在 2-氨基-3-甲基吡啶 、 Rhodium, chlorobis(triphenylphosphine)- 、 4-三氟甲基苯甲酸 、 环己胺 作用下， 以 甲苯 为溶剂， 反应 12.0h， 以83%的产率得到Trimethyl 4-nonanone
  参考文献：
  名称：

  The effects of amine and acid catalysts on efficient chelation-assisted hydroacylation of alkene with aliphatic aldehyde

  摘要：

  Efficient intermolecular hydroacylation of 1-alkene with aliphatic aldehyde was achieved using a catalyst mixture of cyclohexylamine, p-trifluoromethylbenzoic acid, Wilkinson's complex and 2-amino-3-picoline. The formation of unwanted aldol side-product was avoided through the conjugate addition of cyclohexylamine to the aldol intermediate that was initially generated, followed by the retro-Mannich-type fragmentation of the resulting beta-aminoaldimine.

  DOI：

  10.1016/j.tetlet.2009.02.091

文献信息

• GRAPHENIC DISPERSIONS AND SLURRIES AND COATINGS THEREOF
  申请人：Graphenix Development, Inc.

  公开号：US20150337104A1

  公开（公告）日：2015-11-26

  The present invention is particularly directed to graphenic dispersion and slurry compositions and the production and uses thereof, where these compositions exhibit one or more of the hallmark strength, thermal or electrical properties of “pure” graphene while at the same time being optimized in terms of solubility or other properties necessary for compatibility with one or more end processes. In specific embodiments, a composition of matter includes a graphenic mixture and at least one species of polymerized product of benzyl alcohol, and a method of making such composition of matter comprises sonicating the graphenic mixture in heated benzyl alcohol. In a further specific embodiment, a composition of matter is formed by sonicating a graphenic mixture in heated benzyl alcohol, wherein the resulting composition exhibits a binder functionality in the absence of exogenous binder.
• US8106114B2
  申请人：——

  公开号：US8106114B2

  公开（公告）日：2012-01-31
• US9828484B2
  申请人：——

  公开号：US9828484B2

  公开（公告）日：2017-11-28
• [EN] DRAG REDUCING AGENT AND METHOD OF USE<br/>[FR] AGENT DE RÉDUCTION DE LA TRAÎNÉE ET PROCÉDÉ D'UTILISATION ASSOCIÉ
  申请人：EATON GERALD BRUCE

  公开号：WO2011053359A1

  公开（公告）日：2011-05-05

  The present invention relates to a drag reducing agent, composition, compound, product, process and method of use for use in petroleum pipelines and the like. A preferred embodiment of the present invention provides a cryogenically-ground polyalphaolefin polymer at 15-25 wt.% of the commercial product formulation. The bulking agents comprise ethylene bis-stearamide alone or in combination with other polyethylene and/or polypropylene polymers at 2.0-5.0 wt.% of the commercial product formulation. In addition, diisobutyl ketone 20-60 wt.% of the commercial product formulation and propylene carbonate 2.8-8.4 wt.% of the commercial product formulation are used.
• [EN] GRAPHENIC DISPERSIONS AND SLURRIES AND COATINGS THEREOF<br/>[FR] DISPERSIONS ET SUSPENSIONS CONCENTRÉES GRAPHÉNIQUES ET REVÊTEMENTS DE CELLES-CI
  申请人：GRAPHENIX DEV INC

  公开号：WO2014004649A1

  公开（公告）日：2014-01-03

  The present invention is particularly directed to graphenic dispersion and slurry compositions and the production and uses thereof, where these compositions exhibit one or more of the hallmark strength, thermal or electrical properties of "pure" graphene while at the same time being optimized in terms of solubility or other properties necessary for compatibility with one or more end processes. In specific embodiments, a composition of matter includes a graphenic mixture and at least one species of polymerized product of benzyl alcohol, and a method of making such composition of matter comprises sonicating the graphenic mixture in heated benzyl alcohol. In a further specific embodiment, a composition of matter is formed by sonicating a graphenic mixture in heated benzyl alcohol, wherein the resulting composition exhibits a binder functionality in the absence of exogenous binder.