3,6,9,12,15-Pentaoxapentacosane-1,17-diol | 75506-91-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3,6,9,12,15-Pentaoxapentacosane-1,17-diol
• 英文别名: 1-[2-[2-[2-[2-(2-hydroxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]decan-2-ol
• CAS: 75506-91-1
• 化学式: C₂₀H₄₂O₇
• 分子量: 394.549
• InChiKey: ZHUBCRUXYPBUKE-UHFFFAOYSA-N

物化性质

• 沸点：
  190 °C(Press: 0.005 Torr)
• 密度：
  1.022±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  27
• 可旋转键数：
  23
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  86.6
• 氢给体数：
  2
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  3,6,9,12,15-Pentaoxapentacosane-1,17-diol 、 2-[2-[2-[2-[2-(2-hydroxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]decan-1-ol 、 对甲苯磺酰氯 、 sodium hydroxide 、 lithium 、 氢氧化钾 、 1,4-二氧六环 以56%的产率得到
  参考文献：
  名称：

  IKEDA ISAO; YAMAMURA SHINGO; NAKATSUJI YOHJI; OKAHARA MITSUO, J. ORG. CHEM., 1980, 45, NO 26, 5355-5358

  摘要：

  DOI：
• 作为产物：
  描述：

  1,2-二甲基丁炔酯 、 羟丙基淀粉磷酸酯 生成 3,6,9,12,15-Pentaoxapentacosane-1,17-diol
  参考文献：
  名称：

  IKEDA ISAO; YAMAMURA SHINGO; NAKATSUJI YOHJI; OKAHARA MITSUO, J. ORG. CHEM., 1980, 45, NO 26, 5355-5358

  摘要：

  DOI：

文献信息

• Micellar Solutions of Octyl-18-crown-6
  作者：M. Campagna、L. Dei、C. M. C. Gambi、P. Lo Nostro、S. Zini、P. Baglioni

  DOI：10.1021/jp971852x

  日期：1997.12.1

  The solution properties of the novel surfactant octyl-18-crown-6 (C-8 Phi(6)) have been investigated with phase diagram, light-scattering, and surface tension measurements. This tenside is made up of an octyl hydrophobic chain attached to a 18-crown-6 ether and cyclic polar head-group that is highly selective for complexing Ki ions. The results show that C-8 Phi(6) produces micellar structures in water and in KCl aqueous solutions, with a radius of about 30 Angstrom. Addition of potassium ions in a molar ratio of 0.4 (KCl/C-8 Phi(6)) increases the hydrophilicity of the surfactant, as shown by the increment of the phase separation temperature, and produces a slight shift in the critical micellar concentration value, as it results from surface tension measurements. The intermicellar interaction parameter alpha, obtained from QELS experiments, has been discussed. Pure C-8 Phi(6) micelles experience attractive intermicellar interactions overimposed to the hard-sphere interactions, while the K+ complexation of the surfactant polar head-groups leads to a decrease of the average attractive component of the interaction. These results show that intermicellar interactions are selectively controlled and modulated by simply adding a proper salt that can be complexed by the polar head-groups of the surfactant.