[(E)-4-decoxybut-2-enoxy]cyclohexane | 1228276-17-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [(E)-4-decoxybut-2-enoxy]cyclohexane
• CAS: 1228276-17-2
• 化学式: C₂₀H₃₈O₂
• 分子量: 310.521
• InChiKey: KEWHWOVKZMDNKK-BUHFOSPRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  22
• 可旋转键数：
  14
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1-丙-2-烯氧基癸烷 、 allyl cyclohexyl ether 在 C₃₁H₃₄Cl₂N₃O₃Ru 作用下， 以 二氯甲烷 为溶剂， 反应 3.0h， 生成 、 [(E)-4-decoxybut-2-enoxy]cyclohexane
  参考文献：
  名称：

  New nitrochromenylmethylidene-containing ruthenium metathesis catalyst

  摘要：

  New Hoveyda-Grubbs type catalyst containing nitrochromenyl ligand is reported herein. The catalyst was tested in model RCM, CM and enyne reactions. Its activity was compared with that of commercially available complexes and with literature data for Grela catalyst. New catalyst appeared to be fast initiating, but less stable than other catalysts. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2011.12.024

文献信息

• New efficient ruthenium metathesis catalyst containing chromenyl ligand
  作者：Agnieszka Hryniewicka、Jacek W. Morzycki、Stanisław Witkowski

  DOI：10.1016/j.jorganchem.2010.02.025

  日期：2010.5

  A synthesis of new Hoveyda-Grubbs-type catalyst with chromenyl ligand was described herein. The new catalyst was tested in model RCM and CM reactions. The catalyst proved to be quite efficient. It showed activity comparable or superior to that of commercially available Grubbs second-generation complexes. (C) 2010 Elsevier B.V. All rights reserved.
• New nitrochromenylmethylidene-containing ruthenium metathesis catalyst
  作者：Agnieszka Hryniewicka、Anna Kozłowska、Stanisław Witkowski

  DOI：10.1016/j.jorganchem.2011.12.024

  日期：2012.3

  New Hoveyda-Grubbs type catalyst containing nitrochromenyl ligand is reported herein. The catalyst was tested in model RCM, CM and enyne reactions. Its activity was compared with that of commercially available complexes and with literature data for Grela catalyst. New catalyst appeared to be fast initiating, but less stable than other catalysts. (C) 2012 Elsevier B.V. All rights reserved.