2-(4-Hydroxybenzoyl)-pyrrole | 92012-21-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-(4-Hydroxybenzoyl)-pyrrole
• 英文别名: (4-hydroxyphenyl)-(1H-pyrrol-2-yl)methanone
• CAS: 92012-21-0
• 化学式: C₁₁H₉NO₂
• 分子量: 187.198
• InChiKey: NRWUQWRLIMQGND-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  53.1
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4-苯甲氧基苯(甲)酰氯 在 platinum(IV) oxide 氢气 、 三乙胺 、 三氯氧磷 作用下， 以 甲醇 、 乙醇 、 1,2-二氯乙烷 、 甲苯 为溶剂， 25.0~80.0 ℃ 、101.33 kPa 条件下， 反应 116.0h， 生成 2-(4-Hydroxybenzoyl)-pyrrole
  参考文献：
  名称：

  Catalytic hydrogenation of pyrroles at atmospheric pressure

  摘要：

  DOI：

  10.1021/jo00196a020

文献信息

• Emissive polymeric materials for optoelectronic devices
  申请人：General Electric Company

  公开号：US07973126B2

  公开（公告）日：2011-07-05

  Polymers including at least one structural unit derived from a compound of formula I or including at least one pendant group of formula II may be used in optoelectronic devices wherein R1, R3, R4 and R6 are independently hydrogen, alkyl, alkoxy, oxaalkyl, alkylaryl, aryl, arylalkyl, heteroaryl, substituted alkyl; substituted alkoxy, substituted oxaalkyl, substituted alkylaryl, substituted aryl, substituted arylalkyl, or substituted heteroaryl; R1a is hydrogen or alkyl; R2 is alkylene, substituted alkylene, oxaalkylene, CO, or CO2; R2a is alkylene; R5 is independently at each occurrence hydrogen, alkyl, alkylaryl, aryl, arylalkyl, alkoxy, carboxy, substituted alkyl; substituted alkylaryl, substituted aryl, substituted arylalkyl, or substituted alkoxy, X is halo, triflate, —B(OR1a)2, or  located at the 2, 5- or 2, 7-positions; and L is derived from phenylpyridine, tolylpyridine, benzothienylpyridine, phenylisoquinoline, dibenzoquinozaline, fluorenylpyridine, ketopyrrole, 2-(1-naphthyl)benzoxazole)), 2-phenylbenzoxazole, 2-phenylbenzothiazole, coumarin, thienylpyridine, phenylpyridine, benzothienylpyridine, 3-methoxy-2-phenylpyridine, thienylpyridine, phenylimine, vinylpyridine, pyridylnaphthalene, pyridylpyrrole, pyridylimidazole, phenylindole, derivatives thereof or combinations thereof.

  含有至少一个来自化合物I的结构单元或含有至少一个来自化合物II的挂链基团的聚合物，可用于光电子器件中，其中R1、R3、R4和R6独立地为氢、烷基、烷氧基、氧代烷基、烷基芳基、芳基、芳基烷基、杂芳基、取代烷基、取代烷氧基、取代氧代烷基、取代烷基芳基、取代芳基、取代芳基烷基或取代杂芳基；R1a为氢或烷基；R2为烷基烯烃、取代烷基烯烃、氧代烷基烯烃、CO或CO2；R2a为烷基烯烃；R5在每次出现时独立地为氢、烷基、烷基芳基、芳基、芳基烷基、烷氧基、羧基、取代烷基、取代烷基芳基、取代芳基、取代芳基烷基或取代烷氧基；X为卤素、三氟甲烷基磺酸盐、-B（OR1a）2或位于2,5-或2,7-位置；L来源于苯基吡啶、甲苯基吡啶、苯并噻吩基吡啶、苯基异喹啉、二苯并喹啉、芴基吡啶、酮基吡咯、2-(1-萘基)苯并噁唑、2-苯基苯并噁唑、香豆素、噻吩基吡啶、苯基吡啶、苯并噻吩基吡啶、3-甲氧基-2-苯基吡啶、噻吩基吡啶、苯基亚胺、乙烯基吡啶、吡啶基萘、吡啶基吡咯、吡啶基咪唑、苯基吲哚、其衍生物或其组合物。
• POLYMER FOR OPTOELECTRONIC DEVICE
  申请人：Ye Qing

  公开号：US20110108807A1

  公开（公告）日：2011-05-12

  A polymer useful in an optoelectronic device comprises structural unit of formula I: wherein R 1 is, independently at each occurrence, a C 1 -C 20 aliphatic radical, a C 3 -C 20 aromatic radical, or a C 3 -C 20 cycloaliphatic radical; a is, independently at each occurrence, an integer ranging from 0-4; Ar 1 is aryl or heteroaryl; Ar 2 is fluorene; R 2 is alkylene, substituted alkylene, oxaalkylene, CO, or CO 2 ; R 3 , R 4 and R 5 are independently hydrogen, alkyl, alkoxy, alkylaryl, aryl, arylalkyl, heteroaryl, substituted alkyl; substituted alkoxy, substituted alkylaryl, substituted aryl, substituted arylalkyl, or substituted heteroaryl; and L is derived from phenylpyridine, tolylpyridine, benzothienylpyridine, phenylisoquinoline, dibenzoquinozaline, fluorenylpyridine, ketopyrrole, 2-(1-naphthyl)benzoxazole)), 2-phenylbenzoxazole, 2 phenylbenzothiazole, coumarin, thienylpyridine, phenylpyridine, benzothienylpyridine, 3 methoxy-2-phenylpyridine, thienylpyridine, phenylimine, vinylpyridine, pyridylnaphthalene, pyridylpyrrole, pyridylimidazole, phenylindole, derivatives thereof or combinations thereof.

  一种在光电器件中有用的高分子，包括结构单元I的公式，其中R1在每次出现时独立地是C1-C20脂肪基，C3-C20芳香基或C3-C20环脂肪基；a在每次出现时独立地是0-4的整数；Ar1是芳基或杂芳基；Ar2是芴基；R2是烷基，取代烷基，氧代烷基，CO或CO2；R3、R4和R5独立地是氢，烷基，烷氧基，烷基芳基，芳基，芳基烷基，杂芳基，取代烷基，取代烷氧基，取代烷基芳基，取代芳基，取代芳基烷基，或取代杂芳基；L源自苯基吡啶，甲苯基吡啶，苯并噻吩基吡啶，苯基异喹啉，二苯并喹唑啉，芴基吡啶，酮基吡咯，2-(1-萘基)苯并噁唑，2-苯基苯并噁唑，2-苯基苯并噻唑，香豆素，噻吩基吡啶，苯基吡啶，苯并噻吩基吡啶，3-甲氧基-2-苯基吡啶，噻吩基吡啶，苯基亚胺，乙烯基吡啶，吡啶基萘，吡啶基吡咯，吡啶基咪唑，苯基吲哚，其衍生物或其组合。
• Polymer for optoelectronic device
  申请人：Ye Qing

  公开号：US08512879B2

  公开（公告）日：2013-08-20

  A polymer useful in an optoelectronic device comprises structural unit of formula I: wherein R1 is, independently at each occurrence, a C1-C20 aliphatic radical, a C3-C20 aromatic radical, or a C3-C20 cycloaliphatic radical; a is, independently at each occurrence, an integer ranging from 0-4; Ar1 is aryl or heteroaryl; Ar2 is fluorene; R2 is alkylene, substituted alkylene, oxaalkylene, CO, or CO2; R3, R4 and R5 are independently hydrogen, alkyl, alkoxy, alkylaryl, aryl, arylalkyl, heteroaryl, substituted alkyl; substituted alkoxy, substituted alkylaryl, substituted aryl, substituted arylalkyl, or substituted heteroaryl; and L is derived from phenylpyridine, tolylpyridine, benzothienylpyridine, phenylisoquinoline, dibenzoquinozaline, fluorenylpyridine, ketopyrrole, 2-(1-naphthyl)benzoxazole)), 2-phenylbenzoxazole, 2 phenylbenzothiazole, coumarin, thienylpyridine, phenylpyridine, benzothienylpyridine, 3 methoxy-2-phenylpyridine, thienylpyridine, phenylimine, vinylpyridine, pyridylnaphthalene, pyridylpyrrole, pyridylimidazole, phenylindole, derivatives thereof or combinations thereof.

  一种用于光电器件的聚合物，包含结构单元I的公式，其中R1在每次出现时都是C1-C20脂肪基，C3-C20芳香基或C3-C20环脂肪基，a在每次出现时都是0-4的整数，Ar1是芳基或杂环芳基，Ar2是芴基，R2是烷基，取代烷基，氧代烷基，CO或CO2，R3，R4和R5分别是氢，烷基，烷氧基，烷基芳基，芳基，芳基烷基，杂环芳基，取代烷基，取代烷氧基，取代烷基芳基，取代芳基，取代芳基烷基，取代杂环芳基，L是来自苯基吡啶，甲苯基吡啶，苯并噻吩基吡啶，苯基异喹啉，二苯并喹唑啉，芴基吡啶，酮吡咯，2-（1-萘基）苯并噁唑，2-苯基苯并噁唑，香豆素，噻吩基吡啶，苯基吡啶，苯并噻吩基吡啶，3-甲氧基-2-苯基吡啶，噻吩基吡啶，苯亚胺，乙烯基吡啶，吡啶萘，吡啶吡咯，吡啶咪唑，苯基吲哚，其衍生物或其组合物。
• EMISSIVE POLYMERIC MATERIALS FOR OPTOELECTRONIC DEVICES
  申请人：Shiang Joseph John

  公开号：US20090156783A1

  公开（公告）日：2009-06-18

  Polymers including at least one structural unit derived from a compound of formula I or including at least one pendant group of formula II may be used in optoelectronic devices wherein R 1 , R 3 , R 4 and R 6 are independently hydrogen, alkyl, alkoxy, oxaalkyl, alkylaryl, aryl, arylalkyl, heteroaryl, substituted alkyl; substituted alkoxy, substituted oxaalkyl, substituted alkylaryl, substituted aryl, substituted arylalkyl, or substituted heteroaryl; R 1a is hydrogen or alkyl; R 2 is alkylene, substituted alkylene, oxaalkylene, CO, or CO 2 ; R 2a is alkylene; R 5 is independently at each occurrence hydrogen, alkyl, alkylaryl, aryl, arylalkyl, alkoxy, carboxy, substituted alkyl; substituted alkylaryl, substituted aryl, substituted arylalkyl, or substituted alkoxy, X is halo, triflate, —B(OR 1a ) 2 , or located at the 2, 5- or 2, 7-positions; and L is derived from phenylpyridine, tolylpyridine, benzothienylpyridine, phenylisoquinoline, dibenzoquinozaline, fluorenylpyridine, ketopyrrole, 2-(1-naphthyl)benzoxazole)), 2-phenylbenzoxazole, 2-phenylbenzothiazole, coumarin, thienylpyridine, phenylpyridine, benzothienylpyridine, 3-methoxy-2-phenylpyridine, thienylpyridine, phenylimine, vinylpyridine, pyridylnaphthalene, pyridylpyrrole, pyridylimidazole, phenylindole, derivatives thereof or combinations thereof.

  含有至少一个来自化合物I的结构单元或含有至少一个公式II的挂链基团的聚合物可以用于光电子器件中，其中R1、R3、R4和R6独立地为氢、烷基、烷氧基、氧代烷基、烷基芳基、芳基、芳基烷基、杂芳基、取代烷基、取代烷氧基、取代氧代烷基、取代烷基芳基、取代芳基、取代芳基烷基或取代杂芳基；R1a为氢或烷基；R2为烷基、取代烷基、氧代烷基、CO或CO2；R2a为烷基；R5独立地为每个出现的氢、烷基、烷基芳基、芳基、芳基烷基、烷氧基、羧基、取代烷基、取代烷基芳基、取代芳基、取代芳基烷基或取代烷氧基；X为卤素、三氟甲烷磺酸盐、-B(OR1a)2或位于2,5-或2,7-位置；L来源于苯基吡啶、甲苯基吡啶、苯并噻吩基吡啶、苯基异喹啉、二苯并喹唑啉、芴基吡啶、酮基吡咯、2-(1-萘基)苯并噁唑、2-苯基苯并噁唑、香豆素、噻吩基吡啶、苯基吡啶、苯并噻吩基吡啶、3-甲氧基-2-苯基吡啶、噻吩基吡啶、苯亚胺、乙烯基吡啶、吡啶基萘、吡啶基吡咯、吡啶基咪唑、苯基吲哚、其衍生物或其组合物。
• JPH08100166A
  申请人：——

  公开号：JPH08100166A

  公开（公告）日：1996-04-16