m-Hydroxy-phenylcinnamat | 103826-22-8

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 肉桂酸及其衍生物
• 英文名称: m-Hydroxy-phenylcinnamat
• 英文别名: trans-cinnamic acid-(3-hydroxy-phenyl ester)；trans-Zimtsaeure-(3-hydroxy-phenylester)；3-Hydroxyphenyl 3-phenylacrylate；(3-hydroxyphenyl) (E)-3-phenylprop-2-enoate
• CAS: 103826-22-8
• 化学式: C₁₅H₁₂O₃
• 分子量: 240.258
• InChiKey: FBJBXBJXYQABMO-MDZDMXLPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  m-Hydroxy-phenylcinnamat 在 sodium dodecyl-sulfate 作用下， 以 水 为溶剂， 反应 6.0h， 生成 (E)-2',4'-dihydroxychalcone
  参考文献：
  名称：

  胶束环境下肉桂酸苯酯的光重排

  摘要：

  肉桂酸苯基酯在水性SDS介质中的光解作用可有效且高产率地合成相应的2'-羟基查耳酮。

  DOI：

  10.1016/s0040-4039(00)89310-7
• 作为产物：
  描述：

  肉桂酸 、 间苯二酚 在 三氯化锑 作用下， 生成 m-Hydroxy-phenylcinnamat
  参考文献：
  名称：

  Miyano; Matsui, Bulletin of the Chemical Society of Japan, 1958, vol. 31, p. 398,401

  摘要：

  DOI：

文献信息

• Comparison of reputed duplicate populations in the Russian and US Potato Genebanks using RAPD Markers
  作者：J. B. Bamberg、S. D. Kiru、A. H. del Rio

  DOI：10.1007/bf02884345

  日期：2001.9

  The Association of Potato Intergenebank Collaborators (APIC) produced a global inventory of wild potato genetic resources that is available on the Internet (www.potgenebank.org/ipd). This database shows that, in many cases, several genebanks have samples of the progeny from a single original germplasm collection. The assumption has been that these samples are genetically equivalent, so all the characterization and evaluation data gathered on a seedlot from one genebank can be applied to all the other "duplicate" seedlots in other genebanks. This assumption was tested by comparing 25 pairs of reputed duplicates in the VIR (St. Petersburg, Russia) and US (Sturgeon Bay, USA) potato genebanks using RAPDs. In 23 of 25 populations, reputed duplicates among genebanks had significantly less similarity than replicate samples taken from a single population. The average genetic similarity of reputed duplicates was 93%, and the lowest was 81%. Thus, users of germplasm should be aware that reputed duplicate populations from these genebanks may not be genetically identical.
• Barbry; Champagne, Journal of Chemical Research - Part S, 2001, # 2, p. 78 - 79
  作者：Barbry、Champagne

  DOI：——

  日期：——
• Miyano; Matsui, Bulletin of the Chemical Society of Japan, 1958, vol. 31, p. 398,401
  作者：Miyano、Matsui

  DOI：——

  日期：——
• Photorearrangement of phenyl cinnamates under micellar environment
  作者：A.K. Singh、T.S. Raghuraman

  DOI：10.1016/s0040-4039(00)89310-7

  日期：1985.1

  Photolysis of phenyl cinnamates in aqueous SDS medium results in an efficient and high yield synthesis of the corresponding 2′-hydroxychalcones.

  肉桂酸苯基酯在水性SDS介质中的光解作用可有效且高产率地合成相应的2'-羟基查耳酮。