2,2-dimethyl-3-vinyloxy-propan-1-ol | 86261-61-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2,2-dimethyl-3-vinyloxy-propan-1-ol
• 英文别名: 3-Ethenoxy-2,2-dimethylpropan-1-ol
• CAS: 86261-61-2
• 化学式: C₇H₁₄O₂
• 分子量: 130.187
• InChiKey: NUJUOKYDQOVNBK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  9
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,2-dimethyl-3-vinyloxy-propan-1-ol 、 甲基丙烯酸甲酯 在 甲醇 、 sodium methylate 作用下， 生成 methacrylic acid-(2,2-dimethyl-3-vinyloxy-propyl ester)
  参考文献：
  名称：

  Esters of vinyloxyalkoxy compounds and unsaturated carboxylic acids and polymers thereof

  摘要：

  公开号：

  US02692256A1
• 作为产物：
  描述：

  2,2-二甲基-1,3-丙二醇 、 乙炔 在 氢氧化钾 作用下， 生成 2,2-dimethyl-3-vinyloxy-propan-1-ol
  参考文献：
  名称：

  Esters of vinyloxyalkoxy compounds and unsaturated carboxylic acids and polymers thereof

  摘要：

  公开号：

  US02692256A1

文献信息

• CURABLE COMPOSITION, CURED ARTICLE OBTAINED THEREFROM AND PROCESS FOR PREPARATION OF THE SAME
  申请人：Miyamoto Masahiro

  公开号：US20110269894A1

  公开（公告）日：2011-11-03

  Fine polymer particles are dispersed as primary particles in a vinyl monomer to provide a high quality composition in which the dispersed state and stability of the particles are regulated to a high degree and to provide a curable composition being excellent in handleability and using fine polymer particles as a toughness-imparting agent. For the above, the curable composition of the present invention comprises 100 parts by weight of a vinyl monomer (A) and 0.1 to 100 parts by weight of fine polymer particles (B) having a volume average particle size of 0.05 to 1 m, in which the fine polymer particles (B) are dispersed in the form of primary particles in the vinyl monomer (A).

  细聚合物粒子被分散为主要粒子在乙烯单体中，以提供高品质的组合物，其中粒子的分散状态和稳定性得到高度调节，并使用细聚合物粒子作为增加韧性的剂，提供可固化的组合物，其操作性能优异。为此，本发明的可固化组合物包括100重量份的乙烯单体（A）和0.1至100重量份的细聚合物粒子（B），其体积平均粒径为0.05至1μm，其中细聚合物粒子（B）以主要粒子的形式分散在乙烯单体（A）中。
• EPOXY COMPOUND, CURABLE COMPOSITION, CURED PRODUCT, METHOD OF PRODUCING EPOXY COMPOUND, AND REACTIVE DILUENT
  申请人：JXTG NIPPON OIL & ENERGY CORPORATION

  公开号：US20190071409A1

  公开（公告）日：2019-03-07

  The present invention discloses a monoepoxy compound represented by the following Formula (1), a curable composition containing the same, a cured product therefrom, a method of producing the monoepoxy compound, and a reactive diluent containing the monoepoxy compound. The monoepoxy compound represented by the Formula (1) is useful in that it is capable of reducing the viscosity of a curable composition containing the monoepoxy compound, while preventing a reduction in the heat resistance of the curable composition as well as a reduction in the weight of the curable composition upon curing. (In the Formula (1), R 1 to R 6 are each independently selected from the group consisting of a hydrogen atom, an alkyl group, and an alkoxy group.)

  本发明揭示了一种由以下式（1）表示的单环氧化合物，包含该化合物的可固化组合物，由此固化产物，制备单环氧化合物的方法以及含有单环氧化合物的反应性稀释剂。式（1）表示的单环氧化合物有用之处在于，它能够减少含有单环氧化合物的可固化组合物的粘度，同时防止可固化组合物的耐热性和固化后的重量降低。（在式（1）中，R1至R6各自独立地选自氢原子、烷基和烷氧基组成的群）
• EPOXY COMPOUND, CURABLE COMPOSITION CONTAINING THE SAME, AND CURED PRODUCT OBTAINED BY CURING CURABLE COMPOSITION
  申请人：JXTG NIPPON OIL & ENERGY CORPORATION

  公开号：US20190161494A1

  公开（公告）日：2019-05-30

  The present invention discloses a composition comprising at least one or more stereoisomers of a compound represented by the following Formula (1), wherein, in a gas chromatogram obtained by analyzing the composition by gas chromatography, the ratio of the area of the maximum peak with respect to the total area of peaks derived from the stereoisomers is 60% or more; and wherein the maximum peak is present within the range of retention time of from 27.6 to 28.0 minutes. The present invention also discloses: a curable composition comprising the above described composition, and one selected from the group consisting of a thermal cationic polymerization initiator, an acid anhydride-based curing agent and a curing accelerator, and a photo-cationic polymerization initiator; as well as a cured product therefrom. The above described curable composition is useful in that it allows for the production of a cured product having a high heat resistance. (In the Formula (1), R 1 to R 18 are each independently selected from the group consisting of a hydrogen atom, an alkyl group and an alkoxy group.)

  本发明公开了一种组合物，包括由以下式（1）表示的化合物的至少一种立体异构体，其中，在通过气相色谱分析组合物获得的气相色谱图中，立体异构体所得峰的总面积比之下最大峰的面积比为60％或更高；而且最大峰存在于保留时间范围为27.6至28.0分钟之间。本发明还公开了：包括上述组合物和选自热固性阳离子聚合引发剂、酸酐基固化剂和固化促进剂以及光引发的阳离子聚合引发剂的固化组合物；以及由此固化产生的固化产品。上述固化组合物的用处在于它允许生产具有高耐热性的固化产品。（在式（1）中，R1到R18各自独立地选自氢原子、烷基和烷氧基的群体。）
• Production of aqueous based fluoro-polymer compositions
  申请人：ZENECA LIMITED

  公开号：EP0320156A2

  公开（公告）日：1989-06-14

  Production of an aqueous-based composition comprising a fluoropolymer and a vinyl copolymer by (1) preparing a non-aqueous solution of a fluoropolymer comprising repeat units derived from at least one fluorolefine and repeat units bearing chain-pendant disperser groups imparting water-emulsifiability or water-solubility to the fluoropolymer; (2) converting the non-aqueous solution formed in step (1) into an aqueous-based emulsion or solution of said fluoropolymer; and (3) polymerising at least one vinyl monomer to form a vinyl polymer in the presence of said aqueous-based emulsion or solution from step (2).

  (1) 制备含氟聚合物的非水性溶液，该含氟聚合物包含由至少一种氟烯衍生的重复单元和带有链悬垂分散基团的重复单元，链悬垂分散基团赋予含氟聚合物水乳化性或水溶性；(2) 将步骤(1)中形成的非水性溶液转化为所述含氟聚合物的水性乳液或溶液；以及 (3) 在步骤(2)中所述水性乳液或溶液的存在下，聚合至少一种乙烯基单体以形成乙烯基聚合物。
• CATIONICALLY CURABLE COMPOSITION AND CURED PRODUCT THEREOF
  申请人：Asahi Kasei Chemicals Corporation

  公开号：EP1849808A1

  公开（公告）日：2007-10-31

  An object of the present invention is to provide a cationic curable composition which has low viscosity, can be rapidly photo-cured even in the air, has good adhesion to a substrate such as glass or resin, and is excellent in glass cleaner resistance and water resistance; an ink jet ink, a gravure ink and a hard coating material which comprise the composition; and cured products thereof. A cationic curable composition comprising: (A) 1 to 100 parts by weight of a phenol derivative having 3 or more aromatic rings per molecule, wherein the aromatic ring has a structure in which some or all of hydrogen atoms of phenolic hydroxyl groups of the aromatic ring are substituted by polymerizable functional groups; (B) 1 to 500 parts by weight of a cationic polymerizable compound; and (C) 0.05 to 20 parts by weight of a photo- and/or thermo-cationic initiator is provided.

  本发明的目的是提供一种阳离子可固化组合物，该组合物粘度低，即使在空气中也能快速光固化，对玻璃或树脂等基材有良好的附着力，并具有优异的耐玻璃清洁剂性和耐水性；提供一种包含该组合物的喷墨油墨、凹版油墨和硬涂层材料；以及其固化产品。一种阳离子可固化组合物包括：(A) 1 至 100 份（按重量计）苯酚衍生物，每个分子具有 3 个或更多的芳香环，其中芳香环具有一种结构，在这种结构中，芳香环的酚羟基的部分或全部氢原子被可聚合官能团取代；(B) 1 至 500 份（按重量计）阳离子可聚合化合物；以及 (C) 0.05 至 20 份（按重量计）光阳离子和/或热阳离子引发剂。