5-甲基-5-[(2-甲基-2-丙基)过氧]-1-己烯-3-炔 | 14906-32-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 5-甲基-5-[(2-甲基-2-丙基)过氧]-1-己烯-3-炔
• 英文名称: 2-tert-butylperoxy-2-methyl-5-hexene-3-ine
• 英文别名: t-butyl dimethylvinylethynylperoxide；tert. Butyl-<1.1-dimethyl-penten-(4)-in-(2)-yl>-peroxyd；tert-butyl 1,1-dimethyl-pent-4-en-2-ynyl peroxide；t-Butyldimethylvinylethynylperoxide；5-tert-butylperoxy-5-methylhex-1-en-3-yne
• CAS: 14906-32-2
• 化学式: C₁₁H₁₈O₂
• 分子量: 182.263
• InChiKey: NRZBWVAKKOCBFV-UHFFFAOYSA-N

物化性质

• 沸点：
  28 °C(Press: 0.5 Torr)
• 密度：
  0.867 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  二甲基(乙烯基乙炔基)甲醇 在 硫酸 、 双氧水 作用下， 生成 5-甲基-5-[(2-甲基-2-丙基)过氧]-1-己烯-3-炔
  参考文献：
  名称：

  Yurzhenko,T.I. et al., Journal of Organic Chemistry USSR (English Translation), 1966, vol. 2, p. 1154 - 1157

  摘要：

  DOI：

文献信息

• EMULSIFYING INITIATOR, CORE-SHELL COPOLYMER, AND THERMOPLASTIC RESIN COMPOSITION COMPRISING SAME
  申请人：LG Chem, Ltd.

  公开号：EP3502148A1

  公开（公告）日：2019-06-26

  Provided are an emulsifying initiator, and more specifically, an emulsifying initiator including a surfactant part, an initiator part and a vinyl monomer-derived repeating unit, the surfactant part including an organic acid-based monomer-derived repeating unit, and the initiator part including a peroxide-based monomer-derived repeating unit, wherein the content of the organic acid-based monomer-derived repeating unit is more than 2.5% by weight and less than 40% by weight, the content of the peroxide-based monomer-derived repeating unit is more than 2.5% by weight and less than 40% by weight, and the content of the vinyl monomer-derived repeating unit is more than 20% by weight and less than 95% by weight, based on the total content of the emulsifying initiator, and wherein the emulsifying initiator has a weight average molecular weight less than 250,000 g/mol; a core-shell copolymer; and a thermoplastic resin composition including the same.

  提供了一种乳化引发剂，更具体地说，是一种包括表面活性剂部分、引发剂部分和乙烯基单体衍生重复单元的乳化引发剂，表面活性剂部分包括有机酸基单体衍生重复单元，引发剂部分包括过氧化物基单体衍生重复单元，其中有机酸基单体衍生重复单元的含量大于 2.以乳化引发剂的总含量为基准，其中有机酸基单体衍生重复单元的含量大于 2.5%（重量比）且小于 40%（重量比），过氧化物基单体衍生重复单元的含量大于 2.5%（重量比）且小于 40%（重量比），乙烯基单体衍生重复单元的含量大于 20%（重量比）且小于 95%（重量比），其中乳化引发剂的重量平均分子量小于 250,000 g/mol；芯壳共聚物；以及包括上述内容的热塑性树脂组合物。
• Emulsifying initiator, core-shell copolymer, and thermoplastic resin composition comprising same
  申请人：LG Chem, Ltd.

  公开号：US10889660B2

  公开（公告）日：2021-01-12

  A core-shell copolymer includes a core including an emulsifying initiator-derived layer derived from an emulsifying initiator, and a core forming monomer-derived repeating unit, bound to the emulsifying initiator-derived layer; and a shell including a shell forming monomer-derived repeating unit, wherein the emulsifying initiator comprising a surfactant part, an initiator part, and a vinyl monomer-derived repeating unit, the surfactant part including an organic acid-based monomer-derived repeating unit, and the initiator part including a peroxide-based monomer-derived repeating unit, wherein the emulsifying initiator has a weight average molecular weight less than 250,000 g/mol.

  一种核壳共聚物包括一个核，该核包括由乳化引发剂衍生的乳化引发剂衍生层，以及与乳化引发剂衍生层结合的核形成单体衍生重复单元； 和包括壳形成单体衍生重复单元的壳，其中乳化引发剂包括表面活性剂部分、引发剂部分和乙烯基单体衍生重复单元，表面活性剂部分包括有机酸基单体衍生重复单元，引发剂部分包括过氧化物基单体衍生重复单元，其中乳化引发剂的重量平均分子量小于 250,000 g/mol。
• Yurzhenko,T.I. et al., Journal of Organic Chemistry USSR (English Translation), 1969, vol. 5, p. 1355 - 1358
  作者：Yurzhenko,T.I. et al.

  DOI：——

  日期：——
• METHOD OF PREPARING CERIUM DIOXIDE NANOPARTICLES
  申请人：Cerion Technology, Inc.

  公开号：EP2064153A2

  公开（公告）日：2009-06-03
• CERIUM DIOXIDE NANOPARTICLE-CONTAINING FUEL ADDITIVE
  申请人：Cerion Technology, Inc.

  公开号：EP2066767A1

  公开（公告）日：2009-06-10