(2S,3S,4S,5R)-2,3,4-Trihydroxy-5-hydroxymethyl-tetrahydro-furan-2-carboxylic acid | 74006-99-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (2S,3S,4S,5R)-2,3,4-Trihydroxy-5-hydroxymethyl-tetrahydro-furan-2-carboxylic acid
• 英文别名: (2S,3S,4S,5R)-2,3,4-trihydroxy-5-(hydroxymethyl)oxolane-2-carboxylic acid
• CAS: 74006-99-8
• 化学式: C₆H₁₀O₇
• 分子量: 194.141
• InChiKey: XPFSDLKBUIGDJW-DFWBMZDPSA-N

物化性质

• 沸点：
  528.6±50.0 °C(Predicted)
• 密度：
  1.941±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -2
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  127
• 氢给体数：
  5
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  β-D-arabino-hex-2-ulopyranosonic acid 以 氘代二甲亚砜 为溶剂， 以35%的产率得到(2S,3S,4S,5R)-2,3,4-Trihydroxy-5-hydroxymethyl-tetrahydro-furan-2-carboxylic acid
  参考文献：
  名称：

  The structure of biologically important carbohydrates. A carbon-13 nuclear magnetic resonance study of tautomeric equilibriums in several hexulosonic acids and related compounds

  摘要：

  DOI：

  10.1021/ja00527a012

文献信息

• Processing biomass
  申请人：Xyleco, Inc.

  公开号：EP2647716A1

  公开（公告）日：2013-10-09

  The invention relates to a mixture comprising: a low molecular weight sugar, a functionalized biomass material having carboxylic acid groups, and a solvent. In one embodiment the material comprises a plurality of saccharide units arranged in a molecular chain, wherein from about 1 out of every 2 to about 1 out of every 250 saccharide units includes a carboxylic acid group or an ester or salt thereof.

  本发明涉及一种混合物，包括：低分子量糖、具有羧酸基团的功能化生物质材料和溶剂。在一个实施方案中，该材料包括排列在分子链中的多个糖单位，其中每 2 个糖单位中约有 1 个至每 250 个糖单位中约有 1 个包括羧酸基团或其酯或盐。
• PROCESSING BIOMASS
  申请人：MEDOFF Marshall

  公开号：US20090286295A1

  公开（公告）日：2009-11-19

  Biomass (e.g., plant biomass, animal biomass, and municipal waste biomass) is processed to produce useful products, such as fuels. For example, systems can use feedstock materials, such as cellulosic and/or lignocellulosic materials, to produce ethanol and/or butanol, e.g., by fermentation.
• PROCESSING BIOMASS AND PETROLEUM CONTAINING MATERIALS
  申请人：MEDOFF Marshall

  公开号：US20100108567A1

  公开（公告）日：2010-05-06

  Biomass (e.g., plant biomass, animal biomass, and municipal waste biomass) is processed to produce useful products, such as fuels. For example, systems can use feedstock materials, such as cellulosic and/or lignocellulosic materials and/or starchy materials, to produce ethanol and/or butanol, e.g., by fermentation.
• Processing Biomass
  申请人：Medoff Marshall

  公开号：US20120316376A1

  公开（公告）日：2012-12-13

  Biomass (e.g., plant biomass, animal biomass, microbial, and municipal waste biomass) is processed to produce useful products, such as food products and amino acids.
• Processing Biomass and Petroleum Containing Materials
  申请人：XYLECO, INC.

  公开号：US20130261340A1

  公开（公告）日：2013-10-03

  Biomass (e.g., plant biomass, animal biomass, and municipal waste biomass) is processed to produce useful products, such as fuels. For example, systems can use feedstock materials, such as cellulosic and/or lignocellulosic materials and/or starchy materials, to produce ethanol and/or butanol, e.g., by fermentation.