(E)-3-cyclododecen-1,2-dione | 130265-08-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (E)-3-cyclododecen-1,2-dione
• 英文别名: (3E)-cyclododec-3-ene-1,2-dione
• CAS: 130265-08-6
• 化学式: C₁₂H₁₈O₂
• 分子量: 194.274
• InChiKey: NGWGWAXHAZPQRR-VQHVLOKHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  cyclododecane-1,2-dione 在 palladium diacetate 、 三乙胺 、 对苯醌 作用下， 以 乙二醇二甲醚 、 乙腈 为溶剂， 反应 63.0h， 生成 (E)-3-cyclododecen-1,2-dione
  参考文献：
  名称：

  Kim, Moonsun; Applegate, Laura A.; Park, Oee-Sook, Synthetic Communications, 1990, vol. 20, # 7, p. 989 - 997

  摘要：

  DOI：

文献信息

• PROCESS FOR PREPARING PURE CYCLODODECANONE
  申请人：Teles Joaquim Henrique

  公开号：US20100191018A1

  公开（公告）日：2010-07-29

  The present invention relates to a process for preparing at least one cyclic compound with Z cycles and 7 to 16 carbon atoms with a keto group, at least comprising the stages: (a1) oxidation of a composition (A), at least comprising one cyclic olefin with Z cycles and 7 to 16 carbon atoms and at least two C—C double bonds, by means of dinitrogen monoxide to give a composition (A1), (a2) separating off the at least one cyclic olefin with Z cycles and 7 to 16 carbon atoms with at least two C—C double bonds from the composition (A1) in order to obtain a composition (A2), and (b) distillative treatment of the composition (A2) from step (a2) in order to obtain a composition (B), comprising the at least one cyclic compound with Z cycles and 7 to 16 carbon atoms with a keto group and less than 1.0% by weight of the at least one compound with Z−1 cycles and 7 to 16 carbon atoms with at least one aldehyde group, where Z can be 1, 2, 3 or 4.

  本发明涉及一种制备至少一种具有Z个环和7到16个碳原子的含酮基的环状化合物的方法，至少包括以下阶段：(a1)将含有至少一种具有Z个环和7到16个碳原子以及至少两个C—C双键的环状烯烃的组合物（A）氧化，通过二氧化二氮，得到组合物（A1）；(a2)从组合物（A1）中分离出至少一种具有Z个环和7到16个碳原子以及至少两个C—C双键的环状烯烃，以获得组合物（A2）；以及(b)对来自步骤（a2）的组合物（A2）进行蒸馏处理，以获得组合物（B），包括具有Z个环和7到16个碳原子的至少一种含酮基的环状化合物，以及少于1.0%的重量的至少一种含有Z−1个环和7到16个碳原子且至少一个醛基的化合物，其中Z可以为1、2、3或4。
• METHOD FOR THE PRODUCTION OF CYCLIC KETONES
  申请人：Teles Joaquim Henrique

  公开号：US20090281357A1

  公开（公告）日：2009-11-12

  The present invention relates to a process for preparing a cyclic ketone having from 7 to 16 carbon atoms, which comprises at least the steps (a) oxidation of a composition (I) comprising at least one cyclic olefin which has from 7 to 16 carbon atoms and at least one C—C double bond by means of dinitrogen monoxide to give a composition (A), (b) treatment of the composition (A) with at least one base to give a composition (B).

  本发明涉及一种制备具有7至16个碳原子的环酮的方法，该方法至少包括以下步骤：(a)氧化含有至少一种具有7至16个碳原子和至少一个C—C双键的环烯烃的组合物(I)，通过双氮氧化物的作用得到一个组合物(A)；(b)将组合物(A)与至少一种碱进行处理，得到一个组合物(B)。
• Method for producing a ketone
  申请人：Teles Henrique Joaquim

  公开号：US20060281952A1

  公开（公告）日：2006-12-14

  A process for preparing a ketone, in particular cyclododecanone, by reacting cyclododecatriene with dinitrogen monoxide to obtain cyclododecadienone and hydrogenating the resulting cyclododecadienone, in particular to give cyclododecanone.

  一种制备酮的方法，特别是环十二烯酮，通过将环十二烯三烯与一氧化二氮反应得到环十二烯二酮，然后对所得的环十二烯二酮进行氢化，特别是得到环十二烷酮。
• Method for Purifying and Concentrating Dinitrogen Monoxide
  申请人：Teles Joaquim Henrique

  公开号：US20080255393A1

  公开（公告）日：2008-10-16

  The present invention relates to a process for purifying a gas mixture comprising dinitrogen monoxide and to the use of a gas mixture purified in this way as an oxidant for olefins. In a further embodiment, the present invention also relates to a process for preparing ketones comprising the oxidation of an olefin with a gas mixture which has been purified in accordance with the invention and comprises dinitrogen monoxide.

  本发明涉及一种用于纯化含有二氧化氮的气体混合物的方法，并且涉及使用经过该方法纯化的气体混合物作为烯烃的氧化剂。在另一实施方案中，本发明还涉及一种制备酮的方法，该方法包括使用根据本发明纯化并含有二氧化氮的气体混合物氧化烯烃。
• KIM, MOONSUN;APPLEGATE, LAURA A.;PARK, OEE-SOOK;VASUDEVAN, SUNDAR;WATT, D+, SYNTH. COMMUN., 20,(1990) N, C. VAR. PAG.
  作者：KIM, MOONSUN、APPLEGATE, LAURA A.、PARK, OEE-SOOK、VASUDEVAN, SUNDAR、WATT, D+

  DOI：——

  日期：——