Z-2-chlorohept-2-en-1-ol | 138619-86-0

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代醇
• 英文名称: Z-2-chlorohept-2-en-1-ol
• CAS: 138619-86-0
• 化学式: C₇H₁₃ClO
• 分子量: 148.633
• InChiKey: OYPNXWZXYGSAIF-ALCCZGGFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.29
• 重原子数：
  9.0
• 可旋转键数：
  4.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  20.23
• 氢给体数：
  1.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  2-butyl-1,1-dichloro-cyclopropane 在 copper(II) sulfate 作用下， 以 水 、 二甲基亚砜 为溶剂， 反应 0.25h， 生成 2-chlorohept-1-en-3-ol 、 E-2-chlorohept-2-en-1-ol 、 Z-2-chlorohept-2-en-1-ol
  参考文献：
  名称：

  Preparation of allyl alcohols from monohalo- and gem-dihalobutylcyclopropanes in the presence of copper and its salt

  摘要：

  The reaction of gem-dibromo- or gem-dichlorobutylcyclopropanes with an equimolar amount of CuSO4 . 5H2O in a mixture of DMSO and water is accompanied by scission of the three-membered ring and formation of the corresponding 2-bromo- or 2-chloroallyl alcohols. The corresponding allyl alcohols were prepared analogously from monobromo- or monochlorocyclopropanes.

  DOI：

  10.1007/bf00961036

文献信息

• Preparation of allyl alcohols from monohalo- and gem-dihalobutylcyclopropanes in the presence of copper and its salt
  作者：O. S. Korneva、O. M. Nefedov

  DOI：10.1007/bf00961036

  日期：1991.11

  The reaction of gem-dibromo- or gem-dichlorobutylcyclopropanes with an equimolar amount of CuSO4 . 5H2O in a mixture of DMSO and water is accompanied by scission of the three-membered ring and formation of the corresponding 2-bromo- or 2-chloroallyl alcohols. The corresponding allyl alcohols were prepared analogously from monobromo- or monochlorocyclopropanes.