methyl (E,E)-nona-4,6,8-trienyl ketone | 136429-55-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: methyl (E,E)-nona-4,6,8-trienyl ketone
• 英文别名: (6E,8E)-undeca-6,8,10-trien-2-one
• CAS: 136429-55-5
• 化学式: C₁₁H₁₆O
• 分子量: 164.247
• InChiKey: SKIHXIMTNWRUPM-YTXTXJHMSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  丁烯酮 、 丙烯醛 、 alkaline earth salt of/the/ methylsulfuric acid 生成 methyl (E,E)-nona-4,6,8-trienyl ketone
  参考文献：
  名称：

  Carbon–carbon bond formation mediated by molybdenum in an intermediate η⁴-s-trans-diene cation

  摘要：

  η3-烯丙基钼配合物[Mo(C5H5)(CO)2(syn-1-C3H4R)](R =乙烯基或丁-1,3-二烯基)与醛、酮和α,β-不饱和酮发生BF3催化下的碳-碳键形成；据报道，该化合物可用于合成官能化的1,3-二烯和1,3,5-三烯，并提供了形成s-反式-二烯作为中间体的证据。

  DOI：

  10.1039/c39910001004

文献信息

• JP2009084189A
  申请人：——

  公开号：JP2009084189A

  公开（公告）日：2009-04-23
• CARBONATE STIMULATION ENHANCER
  申请人：T. HASEGAWA CO., LTD.

  公开号：US20160213047A1

  公开（公告）日：2016-07-28

  [Problem] To provide a carbonate stimulation enhancer that allows maintenance of carbonate stimulation even for carbonated beverages that have reduced “carbonate stimulation sensation” because of decreased gas pressure during packing according to ingredients, decreased gas pressure due to gas permeability of containers or rapid degassing of gaseous carbonic acid after opening a container. [Solution] Provided is a carbonate stimulation enhancer for enhancing and maintaining preferable carbonate stimulation of gaseous carbonic acid, which is obtained by the addition of an undecatriene and/or an undecatetraene as an active component to a carbonated beverage.
• Carbon–carbon bond formation mediated by molybdenum in an intermediate η⁴-s-trans-diene cation
  作者：Shie-Hsiung Lin、Yuan-Jing Yang、Rai-Shung Liu

  DOI：10.1039/c39910001004

  日期：——

  The η3-allymolybdenum complexes [Mo(C5H5)(CO)2(syn-1-C3H4R)](R = vinyl or buta-1,3-dienyl) undergo BF3 catalysed carbon–carbon bond formation with aldehydes, ketones and α,β-unsaturated ketones; applications to the synthesis of functionalized 1,3-dienes and 1,3,5-trienes are reported, and evidence for formation of an s-trans-diene as an intermediate is presented.

  η3-烯丙基钼配合物[Mo(C5H5)(CO)2(syn-1-C3H4R)](R =乙烯基或丁-1,3-二烯基)与醛、酮和α,β-不饱和酮发生BF3催化下的碳-碳键形成；据报道，该化合物可用于合成官能化的1,3-二烯和1,3,5-三烯，并提供了形成s-反式-二烯作为中间体的证据。