4,8,12-trioxapentadecane-1,14-diene-6,10-diol | 64310-15-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 甘油脂
• 英文名称: 4,8,12-trioxapentadecane-1,14-diene-6,10-diol
• 英文别名: 1,1a(2)-Oxybis[3-(2-propen-1-yloxy)-2-propanol]；1-(2-hydroxy-3-prop-2-enoxypropoxy)-3-prop-2-enoxypropan-2-ol
• CAS: 64310-15-2
• 化学式: C₁₂H₂₂O₅
• 分子量: 246.304
• InChiKey: OONCTYTYTNELHV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.2
• 重原子数：
  17
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  68.2
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  4,8,12-trioxapentadecane-1,14-diene-6,10-diol 在 palladium on activated charcoal 2,6-二甲基吡啶 、 四丁基溴化铵 、 sodium hydride 、 APTS 作用下， 以 四氢呋喃 、 甲醇 、 二氯甲烷 、 水 为溶剂， 反应 77.25h， 生成 3,7,11,15-tetra-O-benzyl-1,5,9,13-tetraoxacyclohexadecane-3,7,11,15-tetraol
  参考文献：
  名称：

  Original Synthesis of Linear, Branched and Cyclic Oligoglycerol Standards

  摘要：

  DOI：

  10.1002/1099-0690(200103)2001:5<875::aid-ejoc875>3.0.co;2-r
• 作为产物：
  描述：

  烯丙基缩水甘油醚 在 sodium hydride 、 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 反应 29.0h， 生成 4,8,12-trioxapentadecane-1,14-diene-6,10-diol
  参考文献：
  名称：

  Original Synthesis of Linear, Branched and Cyclic Oligoglycerol Standards

  摘要：

  DOI：

  10.1002/1099-0690(200103)2001:5<875::aid-ejoc875>3.0.co;2-r

文献信息

• Polysaccharide graft polymers containing acetal groups and their conversion to aldehyde groups
  申请人：National Starch and Chemical Investment Holding Corporation

  公开号：EP0283824A2

  公开（公告）日：1988-09-28

  Polysaccharide graft polymers which comprise an acetal-containing or aldehyde-containing homopolymer or copolymer grafted to a polysaccharide base, represented as Sacch-g-(M')x or Sacch-g-(M)y (M')z and Sacch-g-(M")x or Sacch-g-(M)y-(M")z, have been prepared. M' and M" respectively represent repeating units derived from one or more ethylenically or allylically unsaturated monomers containing an acetal group or aldehyde group; M represents a repeating unit derived from one or more ethylenically or allylically unsaturated monomers other than the acetal-containing or aldehyde-containing monomer; x is at least 2 and y and z are at least 1; A and A' are independently a lower alkyl or A and A' together form at least a 5-membered cyclic acetal; with the proviso that the graft polymer contain no -groups when the aldehyde groups are present. The aldehyde-containing graft polymers are useful for imparting wet strength to paper. Various novel acetal-and aldehyde-containing monomers have also been prepared they can be graft polymerized to polysaccharide substrates or polymerized by conventional emulsion polymerization techniques with vinyl polymerizable monomers.

  多糖接枝聚合物由接枝到多糖基上的含缩醛或含醛均聚物或共聚物组成，已制备出 Sacch-g-(M')x 或 Sacch-g-(M)y (M')z 和 Sacch-g-(M")x 或 Sacch-g-(M)y-(M")z。M' 和 M "分别代表由一种或多种含缩醛基团或醛基团的乙烯基或烯丙基不饱和单体衍生的重复单元；M 代表由一种或多种含缩醛基团或醛基团单体以外的乙烯基或烯丙基不饱和单体衍生的重复单元；x 至少为 2，y 和 z 至少为 1； A 和 A'独立地为低级烷基，或 A 和 A'共同形成至少 5 元环状缩醛；但接枝聚合物在含醛单体时不含有-基团。 当存在醛基时，接枝聚合物不包含-基团。含醛接枝聚合物可用于提高纸张的湿强度。此外，还制备出了各种新型的含缩醛和醛单体，它们可以接枝聚合到多糖基材上，或通过传统的乳液聚合技术与乙烯基可聚合单体聚合。
• 3-Allyloxy-2-hydroxypropyl-ether der Cellulose
  申请人：Wolff Walsrode Aktiengesellschaft

  公开号：EP0541939A1

  公开（公告）日：1993-05-19

  Die Erfindung betrifft wasserlösliche polymerisierbare 3-Allyloxy-2-hydroxypropylether der Cellulose sowie ein Verfahren zu deren Herstellung.

  本发明涉及可水溶性聚合的 3-烯丙氧基-2-羟丙基纤维素醚及其制备工艺。
• ANIONIC CELLULOSE ETHERS HAVING TEMPERATURE-DEPENDENT ASSOCIATIVE PROPERTIES
  申请人：Akzo Nobel N.V.

  公开号：EP1151014A1

  公开（公告）日：2001-11-07
• HYDRAULIC BINDER COMPOSITION
  申请人：Lamberti SpA

  公开号：EP2658821A1

  公开（公告）日：2013-11-06
• SILICONE-MODIFIED WAX, COMPOSITION AND COSMETIC PREPARATION CONTAINING THE SAME, AND PRODUCTION METHOD OF SILICONE-MODIFIED WAX
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US20130150458A1

  公开（公告）日：2013-06-13

  The present invention provides a silicone-modified wax obtained by subjecting an esterification reaction product obtained from a polyhydric alcohol having one or two alkenyl groups in one molecule and a higher fatty acid, and an organohydrogenpolysiloxane containing at least one methyl group, to a hydrosilylation reaction; wherein the silicone-modified wax is solid or in a grease state exhibiting a thixotropy, at 25° C. There can be a silicone-modified wax, a production method thereof, and a composition and a cosmetic preparation each containing the silicone-modified wax, which silicone-modified wax is solid or in a grease state exhibiting a thixotropy, at 25° C., and is high in compatibility with oil-based agents such as volatile and nonvolatile silicone oils, hydrocarbon oils, ester oils, natural animal oils and plant oils, and the like.