2-Methoxy-5-methylcyclohexan-1-one | 62471-50-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-Methoxy-5-methylcyclohexan-1-one
• 英文别名: 2-methoxy-5-methylcyclohexan-1-one
• CAS: 62471-50-5
• 化学式: C₈H₁₄O₂
• 分子量: 142.198
• InChiKey: GPXZEJQSASIXTQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-甲氧基-5-甲基苯酚 在 氢气 、 γ-戊内酯 作用下， 以 水 为溶剂， 反应 16.0h， 生成 2-Methoxy-5-methylcyclohexan-1-one
  参考文献：
  名称：

  牢固支撑的铑纳米簇：木质素衍生的酚类化合物的选择性合成和合成及其应用†

  摘要：

  据报道，在聚合物衍生的碳氮化硅（SiCN）基质中，小的铑纳米簇（NC）的稳定化产生了用于酚类化合物选择性加氢的高度坚固和活性的固体催化剂。氨基吡啶吡啶Rh配合物用于修饰预陶瓷聚合物（HTT 1800），然后在1100°C进行热解，得到小的Rh NCs很好地分散在致密SiCN陶瓷上。为了合成含Rh NCs的多孔催化剂，使用了HTT 1800的二嵌段共聚物与羟基聚乙烯（PE-OH）的微相分离（通过热解法）。两种催化剂在室温和低氢气压下在取代酚的氢化中均表现出高活性。催化剂保持高活性，并连续六次运行具有选择性。

  DOI：

  10.1039/c6nj01974a

文献信息

• Electrochemical Radical Reactions of Enol Acetates and Free Alcohols Directly Access to α-Alkoxylated Carbonyl Compounds
  作者：Fan Wu、Yu Guo、Zihao Ren、Zixuan Chen、Xiaoqin Liu、Chang Wang、Liangce Rong

  DOI：10.1021/acs.joc.3c00635

  日期：2023.7.7

  The efficient intermolecular alkoxylation reactions of various enol acetates and different alcohols are developed in the electrochemical process for the first time. Enol acetates derived from either aromatic, alkyl, or alicyclic ketones, and abundant free alcohols directly used in this synthetic strategy, make this transformation very valuable in synthesis and application in the future.

  首次在电化学过程中开发了各种烯醇乙酸酯和不同醇的高效分子间烷氧基化反应。衍生自芳香族、烷基或脂环族酮的烯醇乙酸酯，以及直接用于该合成策略的丰富的游离醇，使得这种转化在未来的合成和应用中非常有价值。
• [EN] POLYSILOXANE COMPOSITION AND METHOD FOR PRODUCING THE SAME<br/>[FR] COMPOSITION DE POLYSILOXANE ET PROCÉDÉ DE FABRICATION DE CELLE-CI
  申请人：DOW CORNING TORAY CO LTD

  公开号：WO2009057817A1

  公开（公告）日：2009-05-07

  The present invention relates to a polysiloxane composition containing microparticles of a metal or metal oxide having a silicon-containing organic group with reactivity on the surface thereof, and a method for producing the same. The polysiloxane composition contains a polysiloxane represented by average structural formula (A) and microparticles of a metal or metal oxide on the surface of which a silicon-containing organic group represented by specified general formula (B) is fixed by means of chemical bonding. In the method for producing the aforementioned polysiloxane composition, a silicon-containing compound and an aqueous solution or aqueous dispersion of a metal salt are reacted under the conditions at a temperature of 300°C or greater under pressure of 10 MPa or greater, and thereby, the polysiloxane and the microparticles of the metal or metal oxide are produced at the same time.
• [EN] MICROPARTICLE OF METAL OR METAL OXIDE HAVING SILICON-CONTAINING ORGANIC GROUP, AND METHOD FOR PRODUCING THE SAME<br/>[FR] MICROPARTICULE DE MÉTAL OU D'OXYDE MÉTALLIQUE AYANT UN GROUPE ORGANIQUE CONTENANT DU SILICIUM ET SON PROCÉDÉ DE FABRICATION
  申请人：DOW CORNING TORAY CO LTD

  公开号：WO2009057821A1

  公开（公告）日：2009-05-07

  The present invention relates to microparticles of a metal or metal oxide having a silicon-containing organic group with reactivity on the surface thereof, and a method for producing the same. The microparticles of a metal or metal oxide has a silicon-containing organic group represented by general formula (A) fixed on the surface thereof by means of chemical bonding. In the method for producing the microparticles, a silicon-containing compound and an aqueous solution or aqueous dispersion of a metal salt are reacted under the conditions at a temperature of 300°C or greater under pressure of 10 MPa or greater.
• [EN] POLYSILOXANE COMPOSITION AND METHOD FOR PRODUCING THE SAME<br/>[FR] COMPOSITION À BASE DE POLYSILOXANE ET PROCÉDÉ DE PRODUCTION DE CETTE DERNIÈRE
  申请人：DOW CORNING TORAY CO LTD

  公开号：WO2010073969A2

  公开（公告）日：2010-07-01

  A polysiloxane composition containing fine particles of a metal or metal oxide on the surface of which an organosilicon group is present and a method for producing the same are provided. The polysiloxane composition contains a polysiloxane represented by average structural formula (A) and fine particles of a metal or metal oxide on the surface of which an organosilicon group represented by general formula (B) is fixed by means of chemical binding. The method for producing the aforementioned polysiloxane composition includes reacting the fine particles of a metal or metal oxide with the organosilicon compound having a monovalent organic group having an organic functional group, and a silicon atom-binding hydrolyzable group or a silanol group in the presence of water under conditions at a temperature of not less than 2000C, to simultaneously form a polysiloxane and fine particles of the metal or metal oxide on the surface of which the organosilicon group is fixed by means of chemical binding.
• Robustly supported rhodium nanoclusters: synthesis and application in selective hydrogenation of lignin derived phenolic compounds
  作者：Sonja Fehn、Muhammad Zaheer、Christine E. Denner、Martin Friedrich、Rhett Kempe

  DOI：10.1039/c6nj01974a

  日期：——

  The stabilization of small rhodium nanoclusters (NCs) in a polymer derived silicon carbonitride (SiCN) matrix has been reported to generate highly robust and active solid catalysts for the selective hydrogenation of phenolic compounds. An aminopyridinato Rh complex was used to modify a preceramic polymer (HTT 1800) followed by its pyrolysis at 1100 °C to afford small Rh NCs nicely dispersed over dense

  据报道，在聚合物衍生的碳氮化硅（SiCN）基质中，小的铑纳米簇（NC）的稳定化产生了用于酚类化合物选择性加氢的高度坚固和活性的固体催化剂。氨基吡啶吡啶Rh配合物用于修饰预陶瓷聚合物（HTT 1800），然后在1100°C进行热解，得到小的Rh NCs很好地分散在致密SiCN陶瓷上。为了合成含Rh NCs的多孔催化剂，使用了HTT 1800的二嵌段共聚物与羟基聚乙烯（PE-OH）的微相分离（通过热解法）。两种催化剂在室温和低氢气压下在取代酚的氢化中均表现出高活性。催化剂保持高活性，并连续六次运行具有选择性。