3,3-Dimethyl-heptanal | 128850-08-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3,3-Dimethyl-heptanal
• 英文别名: 3,3-Dimethylheptanal
• CAS: 128850-08-8
• 化学式: C₉H₁₈O
• 分子量: 142.241
• InChiKey: SSHZZGWPPHHPGB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  10
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  苯磺酰胺 、 3,3-Dimethyl-heptanal 在 titanium (IV) ethoxide 作用下， 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Oxaziridine-Mediated Intramolecular Amination of sp³-Hybridized C−H Bonds

  摘要：

  We describe a new oxaziridine-mediated approach to the amination of sp(3)-hybridized C-H bonds. In the presence of a copper(II) catalyst, N-sulfonyl oxaziridines participate in efficient intramolecular cyclization reactions to afford a variety of piperidine and tetrahydroisoquinoline structures. The aminal intermediates provide a convenient functional handle for further elaboration of these structures, demonstrating the utility of this new methodology for the rapid construction of structurally complex nitrogen-containing heterocycles.

  DOI：

  10.1021/ja906183g
• 作为产物：
  描述：

  ethyl 3,3-dimethylheptanoate 在 lithium aluminium tetrahydride 、 pyridinium chlorochromate 作用下， 以 乙醚 、 二氯甲烷 为溶剂， 反应 7.0h， 生成 3,3-Dimethyl-heptanal
  参考文献：
  名称：

  PdII 催化的位点选择性 β- 和 γ-C(sp3)-H 伯醛的芳基化由瞬态定向基团控制

  摘要：

  Pd(II) 催化的位点选择性 β- 和 γ-C(sp 3 )–H 伯醛芳基化是通过 L,X 型瞬态导向基团 (TDG) 的合理设计开发的。外部 2-吡啶酮配体被确定为对观察到的反应性至关重要。通过最大限度地减少酸添加剂的负载，配体效应得到增强，以实现具有挑战性的伯醛底物的高反应性。通过改变 TDG 的咬角以匹配所需的 palladacycle 大小，可以将位点选择性从最近位置切换到相对较远的位置。实验和计算研究支持设计 TDG 以潜在实现远程位点选择性 C(sp 3 )–H 功能化的基本原理。

  DOI：

  10.1021/jacs.1c13586

文献信息

• Organomanganese (II) reagents XVIII: Copper-catalyzed 1,4- addition of organomanganese chloride compounds to conjugated ethylenic aldehydes
  作者：Gérard Cahiez、Mouad Alami

  DOI：10.1016/s0040-4039(00)70698-8

  日期：1989.1

  Organomanganese chlorides react with β-mono or β,β-bisubstituted α,β-ethylenic aldehydes in the presence of a catalytic amount of copper chloride to give good yields of 1,4-addition products in THF at −30°C.

  在催化量的氯化铜存在下，有机锰氯化物与β-单取代或β，β-双取代的α，β-乙烯醛反应，在-30°C下的THF中提供1,4-加成产物的良好收率。
• CELLULOSE DERIVATIVE AND PROCESS FOR PRODUCTION THEREOF, CELLULOSE RESIN COMPOSITION, MOLDED ARTICLE AND METHOD FOR PRODUCTION THEREOF, AND HOUSING FOR ELECTROCHEMICAL DEVICE
  申请人：FUJIFILM Corporation

  公开号：EP2295470A1

  公开（公告）日：2011-03-16

  A cellulose derivative having good thermal plasticity, strength, heat resistance and mold working suitability is provided. The cellulose derivative is a cellulose derivative obtained from cellulose by substitution of hydrocarbyl groups ranging in carbon number from 1 to 7 and aliphatic acyl groups ranging in carbon number from 4 to 11 for at least part of the hydrogen atoms of hydroxyl groups contained in the cellulose.

  提供了一种具有良好热可塑性、强度、耐热性和模具加工适应性的纤维素衍生物。 这种纤维素衍生物是从纤维素中通过用碳原子数为 1 至 7 的烃基和碳原子数为 4 至 11 的脂肪酰基取代纤维素中所含羟基的至少部分氢原子而得到的纤维素衍生物。
• CAHIEZ, GERARD;ALAMI, MOUAD, TETRAHEDRON LETT., 30,(1989) N2, C. 7365-7368
  作者：CAHIEZ, GERARD、ALAMI, MOUAD

  DOI：——

  日期：——
• Process for hydrogenation of conjugated diene polymer
  申请人：——

  公开号：US20040082727A1

  公开（公告）日：2004-04-29

  A process for hydrogenation of a conjugated diene polymer. The conjugated diene polymer in an inert organic solvent is brought into contact with hydrogen in the presence of a hydrogenation catalyst composition to selectively hydrogenate the unsaturated double bonds in the conjugated diene units of the conjugated diene polymer. The hydrogenation catalyst composition includes: (I) a titanium compound; (II) a compound represented by formula (II): 1 wherein L is a Group IVB element, R is C 1 -C 12 alkyl or C 1 -C 12 cycloalkyl, X can be the same or different and is C 1 -C 12 alkyl, C 1 -C 12 alkoxy, C 1 -C 12 cycloalkoxy, halogen, or carbonyl; and (III) a trialkylaluminum compound.
• Hydrogenation catalyst composition and process for hydrogenation of conjugated diene polymer
  申请人：Lin Fu

  公开号：US20060041079A1

  公开（公告）日：2006-02-23

  A process for hydrogenation of an unsaturated polymer. The conjugated diene polymer in an inert organic solvent is brought into contact with hydrogen in the presence of a hydrogenation catalyst composition to selectively hydrogenate the unsaturated double bonds in the conjugated diene units of the conjugated diene polymer. The hydrogenation catalyst composition includes: (a) a titanium compound; (b) a compound represented by formula (II) or formula (III): wherein L 1 is a Group IVA element, L 2 is a Group IVA element, R 3 is C 1 -C 12 alkyl or C 1 -C 12 cycloalkyl, R 4 is C 2 -C 12 alkyl or C 3 -C 12 cycloalkyl, and X 1 , X 2 , and X 3 can be the same or different and are C 1 -C 12 alkyl, C 1 -C 12 alkoxy, C 1 -C 12 cycloalkoxy, phenyl, or phenoxy; and (c) a trialkylaluminum compound.