(E)-4,5-dimethyl-4-nonen-3-one | 104664-51-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (E)-4,5-dimethyl-4-nonen-3-one
• 英文别名: (E)-4,5-dimethylnon-4-en-3-one
• CAS: 104664-51-9
• 化学式: C₁₁H₂₀O
• 分子量: 168.279
• InChiKey: IYGDAKUOSHSEFL-MDZDMXLPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  12
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  正丁基锂 、 (E)-4-methyl-5-methylthiohex-4-en-3-one 在 copper(I) thiocyanate 作用下， 生成 (Z)-4,5-dimethyl-4-nonen-3-one 、 (E)-4,5-dimethyl-4-nonen-3-one
  参考文献：
  名称：

  A stereoselective synthesis of .alpha.,.beta.-unsaturated ketones involving the reactions of organocuprates with .beta.-alkylthio .alpha.,.beta.-enones

  摘要：

  DOI：

  10.1021/jo00374a034

文献信息

• DIETER R. K.; SILKS L. A., III, J. ORG. CHEM., 51,(1986) N 24, 4687-4701
  作者：DIETER R. K.、 SILKS L. A., III

  DOI：——

  日期：——
• POLYMERIZABLE LIQUID CRYSTAL COMPOUND, POLYMERIZABLE LIQUID CRYSTAL COMPOSITION, POLYMER AND FILM
  申请人：KATOH Shunya

  公开号：US20110233464A1

  公开（公告）日：2011-09-29

  A polymerizable liquid crystal compound represented by formula (I) is disclosed. R 0 and R 1 represent a hydrogen atom, or C 1-4 alkyl; L 0 and L 1 represent a hydrogen atom, or C 1-4 alkyl group; A 0 and A 1 represent a divalent linking group having a 5- to 12-membered cyclic structure; B 0 and B 1 represent a single bond or a divalent linking group having a 5- to 12-membered cyclic structure; D 0 and D 1 represent —O—, —S—, or —NR 2 —; X 0 and X 1 represent a hydrogen atom, acyl group or cyano; Y 0 and Y 1 represent a single bond or a divalent group; Q 0 and Q 1 represent a C 1-20 divalent aliphatic group; Z 0 and Z 1 represent a hydrogen atom, cyano, halogen atom or polymerizable group; and n and m each independently represent an integer of from 0 to 2.
• US8262931B2
  申请人：——

  公开号：US8262931B2

  公开（公告）日：2012-09-11
• A stereoselective synthesis of .alpha.,.beta.-unsaturated ketones involving the reactions of organocuprates with .beta.-alkylthio .alpha.,.beta.-enones
  作者：R. Karl Dieter、Louis A. Silks

  DOI：10.1021/jo00374a034

  日期：1986.11