苯并[LMN]菲啶 | 194-03-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 中文名称: 苯并[LMN]菲啶
• 英文名称: benzo[lmn]phenanthridine
• 英文别名: benzophenanthridine；4-Azapyrene；Benzo[lmn]phenanthridin；Benzol[lmn]phenanthridin；Thebenidin；1-Aza-pyren；benzo[lmn]phenanthridine
• CAS: 194-03-6
• 化学式: C₁₅H₉N
• 分子量: 203.243
• InChiKey: YEELFSTYCPPLQY-UHFFFAOYSA-N

物化性质

• 保留指数：
  356.93;357.94;358.76;361.2;361.78;357.87;357.94;358.53

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  苯并[LMN]菲啶 、 碘甲烷 生成 N-methylthebenidinium iodide
  参考文献：
  名称：

  Vongerichten, Chemische Berichte, 1901, vol. 34, p. 768

  摘要：

  DOI：
• 作为产物：
  描述：

  5-甲酰基-4-菲羧酸 在 迭氮酸 、 氯仿 、 硫酸 、 锌 作用下， 生成 苯并[LMN]菲啶
  参考文献：
  名称：

  Medenwald, Chemische Berichte, 1953, vol. 86, p. 287,292

  摘要：

  DOI：

文献信息

• ORGANIC COMPOUND, THREE-DIMENSIONAL ORGANIC FRAMEWORK FORMED BY USING ORGANIC COMPOUND, SEPARATION SIEVE AND OPTICAL LAYER, WHICH COMPRISE ORGANIC FRAMEWORK, AND OPTICAL DEVICE COMPRISING OPTICAL LAYER AS OPTICAL AMPLIFICATION LAYER
  申请人：INDUSTRY-UNIVERSITY COOPERATION FOUNDATION HANYANG UNIVERSITY

  公开号：US20190031586A1

  公开（公告）日：2019-01-31

  An organic compound, a three-dimensional organic structure formed by using the organic compound, a separation sieve and an optical layer having the organic structure, and an optical device having the optical layer as an optical amplification layer are provided. The organic structure includes a plurality of organic molecules self-assembled by non-covalent bonding. Each of the unit organic molecules has an aromatic ring, a first pair of substituents being connected to immediately adjacent positions of substitutable positions of the aromatic ring, and a second pair of substituents being connected to immediately adjacent positions of remaining substitutable positions of the aromatic ring. The unit organic molecules are self-assembled by van der Waals interaction, London dispersion interaction or hydrogen bonding between the first and the second pairs of the substituents and by pi-pi interactions between the aromatic rings.

  提供一种有机化合物，通过使用该有机化合物形成的三维有机结构、分离筛和具有该有机结构的光学层，以及具有光学层作为光学放大层的光学器件。该有机结构包括通过非共价键自组装的多个有机分子。每个单元有机分子具有芳香环，第一对取代基连接到芳香环的可取代位置的相邻位置，第二对取代基连接到芳香环的剩余可取代位置的相邻位置。单元有机分子通过范德华力相互作用、伦敦分散相互作用或氢键作用于第一和第二对取代基之间的π-π相互作用而自组装。
• Thermal ring enlargement of aromatic cyclopentadienylidene iminyl radicals. Intramolecular radical addition to the N atom of nitriles results in high yields of aza-aromatics
  作者：Jörg Hofmann、Kathrin Schulz、Gerhard Zimmermann

  DOI：10.1016/0040-4039(96)00320-6

  日期：1996.4

  benz-anellated cyclopentadienones (fluorenone (9a), methanophenanthrenone (9b)), yield into phenanthridine (8a) and benzo[lmn]-phenanthridine (8b) in yields > 60%. The results point to a predominant addition of intermediately generated phenyl type radicals 5 to the N atom of the nitrile groups followed by bimolecular H-abstraction of the cyclic imidoyl radicals to 8 (scheme 3).

  业已证明，在高温（1000°C，0.3 s）下，无氧氮中的苯甲酰基基团由苯甲酰化的环戊二烯酮（芴酮（9a），美甲菲蒽酮（9b））的苯hydr生成，生成菲啶（8a）。和苯并[lmn]-菲啶（8b），产率＞ 60％。结果表明，主要将中间生成的苯基型自由基5加到腈基的N原子上，然后将环状亚氨基自由基的双分子H-抽象成8（方案3）。
• TRIPHENYLENE SILANE HOSTS
  申请人：Zeng Lichang

  公开号：US20130119353A1

  公开（公告）日：2013-05-16

  Novel aryl silicon and aryl germanium host materials, and in particular host materials containing triphenylene and pyrene fragments, are described. These compounds improve OLED device performance when used as hosts in the emissive layer of the OLED.

  本文描述了一些新型芳基硅和芳基锗宿主材料，尤其是含有三苯基和芘片段的宿主材料。当这些化合物被用作OLED发射层中的宿主时，可以提高OLED器件的性能。
• Organic compound, three-dimensional organic framework formed by using organic compound, separation sieve and optical layer, which comprise organic framework, and optical device comprising optical layer as optical amplification layer
  申请人：INDUSTRY-UNIVERSITY COOPERATION FOUNDATION HANYANG UNIVERSITY

  公开号：US11066351B2

  公开（公告）日：2021-07-20

  An organic compound, a three-dimensional organic structure formed by using the organic compound, a separation sieve and an optical layer having the organic structure, and an optical device having the optical layer as an optical amplification layer are provided. The organic structure includes a plurality of organic molecules self-assembled by non-covalent bonding. Each of the unit organic molecules has an aromatic ring, a first pair of substituents being connected to immediately adjacent positions of substitutable positions of the aromatic ring, and a second pair of substituents being connected to immediately adjacent positions of remaining substitutable positions of the aromatic ring. The unit organic molecules are self-assembled by van der Waals interaction, London dispersion interaction or hydrogen bonding between the first and the second pairs of the substituents and by pi-pi interactions between the aromatic rings.

  本文提供了一种有机化合物、利用该有机化合物形成的三维有机结构、具有该有机结构的分离筛和光学层，以及具有该光学层作为光放大层的光学设备。有机结构包括多个通过非共价键自组装的有机分子。每个单元有机分子都有一个芳香环，第一对取代基连接到芳香环可取代位置的紧邻位置，第二对取代基连接到芳香环其余可取代位置的紧邻位置。通过第一对和第二对取代基之间的范德华相互作用、伦敦色散相互作用或氢键作用，以及芳香环之间的π-π相互作用，单元有机分子得以自组装。
• Organic light-emitting diode devices with improved operational stability
  申请人：Eastman Kodak Company

  公开号：US20040076853A1

  公开（公告）日：2004-04-22

  An organic light-emitting device includes a substrate, an anode and a cathode disposed over the substrate, and a luminescent layer disposed between the anode and the cathode wherein the luminescent layer includes a host and at least one dopant. The host of the luminescent layer is selected to include a solid organic material comprising a mixture of at least two components, one of which is capable of forming both monomer state and an aggregate state.

  一种有机发光器件包括基板、设置在基板上的阳极和阴极，以及设置在阳极和阴极之间的发光层，其中发光层包括宿主和至少一种掺杂剂。发光层的宿主被选择为包括固体有机材料，该材料由至少两种成分的混合物组成，其中一种成分能够形成单体态和集合态。

表征谱图