10,10'-(biphenyl-4,4'-diyl)diacridin-9(10H)-one | 358972-75-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 10,10'-(biphenyl-4,4'-diyl)diacridin-9(10H)-one
• 英文别名: 10,10'-([1,1'-Biphenyl]-4,4'-diyl)bis(acridin-9(10H)-one)；10-[4-[4-(9-oxoacridin-10-yl)phenyl]phenyl]acridin-9-one
• CAS: 358972-75-5
• 化学式: C₃₈H₂₄N₂O₂
• 分子量: 540.621
• InChiKey: WGOYLLCKFNYGBO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9
• 重原子数：
  42
• 可旋转键数：
  3
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  40.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  4,4'-二溴联苯 、 吖啶酮 在 copper(l) iodide 、 丙二酸二叔丁酯 、 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 24.0h， 以85%的产率得到10,10'-(biphenyl-4,4'-diyl)diacridin-9(10H)-one
  参考文献：
  名称：

  Acridinone/Amine(carbazole)-Based Bipolar Molecules: Efficient Hosts for Fluorescent and Phosphorescent Emitters

  摘要：

  Three acridinone-based molecules ADBP, ACBP, and DABP were synthesized, and their application to the OLED devices was investigated. When used as the host for either the deep blue singlet or the green triplet emitter in OLED devices, the bipolar molecules ADBP and ACBP demonstrated superior performance compared to either DABP or commonly used host CBP, remarkably lowering the drive voltage and improving efficiencies.

  DOI：

  10.1021/ol901584g

文献信息

• Acridinone/Amine(carbazole)-Based Bipolar Molecules: Efficient Hosts for Fluorescent and Phosphorescent Emitters
  作者：Dileep A. K. Vezzu、Joseph C. Deaton、Mohammad Shayeghi、Yumin Li、Shouquan Huo

  DOI：10.1021/ol901584g

  日期：2009.10.1

  Three acridinone-based molecules ADBP, ACBP, and DABP were synthesized, and their application to the OLED devices was investigated. When used as the host for either the deep blue singlet or the green triplet emitter in OLED devices, the bipolar molecules ADBP and ACBP demonstrated superior performance compared to either DABP or commonly used host CBP, remarkably lowering the drive voltage and improving efficiencies.