(trichlorogermyl)methanol | 21187-08-6

• 分子结构分类: 有机化合物 - 有机金属化合物 - 金属烷基卤化物
• 英文名称: (trichlorogermyl)methanol
• 英文别名: Trichlorgermylmethanol；trichlorogermylmethanol
• CAS: 21187-08-6
• 化学式: CH₃Cl₃GeO
• 分子量: 209.983
• InChiKey: IDIJICYXAGBLNI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.17
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (trichlorogermyl)methanol 在 氯乙烯 作用下， 以 neat (no solvent) 为溶剂， 以<50的产率得到trichlorovinylgermane
  参考文献：
  名称：

  Shcherbinin, V. V.; Shvedov, I. P.; Pavlov, K. V., Russian Journal of General Chemistry, 1993, vol. 63, p. 1336 - 1336

  摘要：

  DOI：

文献信息

• Synthesis and structure of (trichlorogermyl)methyl adamantane-1-carboxylate
  作者：A. A. Korlyukov、N. V. Alekseev、K. V. Pavlov、O. V. Krivolapova、V. G. Lakhtin、E. A. Chernyshev、M. Yu. Antipin

  DOI：10.1007/s11172-006-0013-9

  日期：2005.7

  The reaction of adamantane-1-carboxylic acid chloride with trichlorogermylmethanol afforded (trichlorogermyl)methyl adamantane-1-carboxylate, whose molecular structure was established by 1H NMR spectroscopy and X-ray diffraction analysis.

  金刚烷-1-羧酸氯化物与三氯肉豆蔻醇反应生成了金刚烷-1-羧酸（三氯肉豆蔻基）甲基酯，其分子结构通过 1H NMR 光谱和 X 射线衍射分析得以确定。
• Two germatranes with bulky substituents
  作者：Alexander A. Korlyukov、Eugene A. Komissarov、Nikolay V. Alekseev、Konstantin V. Pavlov、Olga V. Krivolapova、Valentin G. Lachtin

  DOI：10.1107/s0108270106019317

  日期：2006.7.15

  In 1-adamantyl-2,8,9-trioxa-5-aza-1-germabicyclo[3.3.3] undecane or 1-adamantylgermatrane, [Ge(C10H15)(C6H12NO3)], (I), and (2,8,9-trioxa-5-aza-1-germabicyclo[3.3.3]undecan-1yl) methyl N-cyclohexylcarbamate or [(germatran-1-yl) methyl]-cyclohexylcarbamate, [Ge(C6H12NO3)(C8H14NO2)], (II), the Ge atoms are characterized by trigonal-bypiramidal configurations. The Ge center dot center dot center dot N distances [2.266 (3) and 2.206 (3) angstrom in (I) and ( II), respectively] are among the longest observed in germatranes. The significant distortion of the apical N-Ge-C angle in (II) is caused by crystal packing effects.
• The structural peculiarities and chemical bonding in three organogermanes Cl3GeCH2OC(O)R with rigid coordination centre
  作者：Alexander A. Korlyukov、Eugen A. Komissarov、Mikhail Yu. Antipin、Nikolay V. Alekseev、Konstatntin V. Pavlov、Olga V. Krivolapova、Valerii G. Lahtin、Eugenii A. Chernyshev

  DOI：10.1016/j.molstruc.2007.04.019

  日期：2008.3

  The molecular and crystal structure of three organogermanes Cl3GeCH2OC(O)R (where R =-NHC6H11, -C10H15, and -NH2) has been determined by X-ray diffraction method in order to investigate geometrical regularities of these molecules. The nature of Ge-O bonding in these molecules was investigated by quantum chemistry method. It was shown that the influence of the nature of ligand, attached to carbon atom of the carbonyl group, on Ge center dot center dot center dot O interatomic distance is incidentally small in isolated molecule while in the crystal it is much more pronounced due to the crystal packing effect. The nature of Ge center dot center dot center dot O bonding corresponds to intermediate type of interatomic interaction in terms of "Atoms in molecules" theory. (C) 2007 Elsevier B.V. All rights reserved.
• GURKOVA, S. N.;GUSEV, A. I.;VIKTOROV, I. A.;MIRONOV, V. F., METALLOORGAN. XIMIYA, 4,(1991) N, S. 614-617
  作者：GURKOVA, S. N.、GUSEV, A. I.、VIKTOROV, I. A.、MIRONOV, V. F.

  DOI：——

  日期：——
• Pawlow K. W., Wiktorow N. A., Mironow W. F., Zh. obshh. khimii, 64 (1994) N 4, S 616-618
  作者：Pawlow K. W., Wiktorow N. A., Mironow W. F.

  DOI：——

  日期：——