[31-(2,5,8,11,14,19,22,25,28,31-Decaoxatricyclo[30.2.2.215,18]octatriaconta-1(35),15,17,32(36),33,37-hexaene-16-carbonyloxymethyl)-2,5,8,11,18,21,24,27-octaoxatricyclo[26.4.0.012,17]dotriaconta-1(28),12(17),13,15,29,31-hexaen-14-yl]methyl 2,5,8,11,14,19,22,25,28,31-decaoxatricyclo[30.2.2.215,18]octatriaconta-1(35),15,17,32(36),33,37-hexaene-16-carboxylate | 1186486-63-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [31-(2,5,8,11,14,19,22,25,28,31-Decaoxatricyclo[30.2.2.215,18]octatriaconta-1(35),15,17,32(36),33,37-hexaene-16-carbonyloxymethyl)-2,5,8,11,18,21,24,27-octaoxatricyclo[26.4.0.012,17]dotriaconta-1(28),12(17),13,15,29,31-hexaen-14-yl]methyl 2,5,8,11,14,19,22,25,28,31-decaoxatricyclo[30.2.2.215,18]octatriaconta-1(35),15,17,32(36),33,37-hexaene-16-carboxylate
• 英文别名: [31-(2,5,8,11,14,19,22,25,28,31-decaoxatricyclo[30.2.2.215,18]octatriaconta-1(35),15,17,32(36),33,37-hexaene-16-carbonyloxymethyl)-2,5,8,11,18,21,24,27-octaoxatricyclo[26.4.0.012,17]dotriaconta-1(28),12(17),13,15,29,31-hexaen-14-yl]methyl 2,5,8,11,14,19,22,25,28,31-decaoxatricyclo[30.2.2.215,18]octatriaconta-1(35),15,17,32(36),33,37-hexaene-16-carboxylate
• CAS: 1186486-63-4
• 化学式: C₈₄H₁₁₂O₃₂
• 分子量: 1633.79
• InChiKey: CZQCFVBIQXTFRO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  116
• 可旋转键数：
  8
• 环数：
  15.0
• sp3杂化的碳原子比例：
  0.55
• 拓扑面积：
  311
• 氢给体数：
  0
• 氢受体数：
  32

反应信息

• 作为产物：
  描述：

  trans-bis(hydroxymethylbenzo)-24-crown-8 、 bis(p-phenylene)-34-crown-10 monoacid 在 4-二甲氨基吡啶 、 盐酸-N-乙基-Nˊ-(3-二甲氨基丙基)碳二亚胺 作用下， 以 二氯甲烷 为溶剂， 反应 48.0h， 以51%的产率得到[31-(2,5,8,11,14,19,22,25,28,31-Decaoxatricyclo[30.2.2.215,18]octatriaconta-1(35),15,17,32(36),33,37-hexaene-16-carbonyloxymethyl)-2,5,8,11,18,21,24,27-octaoxatricyclo[26.4.0.012,17]dotriaconta-1(28),12(17),13,15,29,31-hexaen-14-yl]methyl 2,5,8,11,14,19,22,25,28,31-decaoxatricyclo[30.2.2.215,18]octatriaconta-1(35),15,17,32(36),33,37-hexaene-16-carboxylate
  参考文献：
  名称：

  Formation of linear main-chain polypseudorotaxanes with supramolecular polymer backbones via two self-sorting host–guest recognition motifs

  摘要：

  基于两种自我排序的主客体识别基元，采用三种组分在高浓度溶液中构建了具有超分子聚合物主链的新型线性多伞形旋转烯。

  DOI：

  10.1039/b905837k

文献信息

• Formation of linear main-chain polypseudorotaxanes with supramolecular polymer backbones via two self-sorting host–guest recognition motifs
  作者：Feng Wang、Bo Zheng、Kelong Zhu、Qizhong Zhou、Chunxi Zhai、Shijun Li、Ning Li、Feihe Huang

  DOI：10.1039/b905837k

  日期：——

  Based on two self-sorting host–guest recognition motifs, novel linear main-chain polypseudorotaxanes with supramolecular polymer backbones have been constructed from three components in solution at high concentrations.

  基于两种自我排序的主客体识别基元，采用三种组分在高浓度溶液中构建了具有超分子聚合物主链的新型线性多伞形旋转烯。