4-methyl-2,3,6,7-tetrahydro-1H,5H-pyrido [3.2.1-ij] quinolinium | 80574-26-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 4-methyl-2,3,6,7-tetrahydro-1H,5H-pyrido [3.2.1-ij] quinolinium
• 英文别名: MTPQ；N-Methyl-julolidium；4-Methyl-2,3,4,5,6,7-hexahydro-1H-4lambda(5)-pyrido(3,2,1-ij)quinoline；1-methyl-1-azoniatricyclo[7.3.1.05,13]trideca-5(13),6,8-triene
• CAS: 80574-26-1
• 化学式: C₁₃H₁₈N
• 分子量: 188.293
• InChiKey: MDWZIHPBIGDFDH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  久洛尼定 、 碘甲烷 以 氯仿 为溶剂， 反应 72.0h， 生成 4-methyl-2,3,6,7-tetrahydro-1H,5H-pyrido [3.2.1-ij] quinolinium
  参考文献：
  名称：

  Synthesis of the Small Pore Silicoaluminophosphate STA-6 by Using Supramolecular Self-Assembled Organic Structure Directing Agents

  摘要：

  By means of organic structure directing agents (OSDA) formed by bulky paired quinolinium derived molecules, obtained by self-assembled monomers, it has been possible to synthesize for the first time the pure silicoaluminophosphate form of the small pore STA-6 zeotype. This synthesis method allows obtaining samples with very well dispersed framework silicon atoms, opening the possibility for its use in catalysis.

  DOI：

  10.1021/cm5005483

文献信息

• OPTICAL INFORMATION RECORDING MEDIUM AND AZO METAL COMPLEX DYE
  申请人：Watanabe Kousuke

  公开号：US20100074082A1

  公开（公告）日：2010-03-25

  A WORM-type recording layer in an optical information recording medium contains at least one azo-metal complex dye derived from a metal ion and a compound represented by the following general formula (1-1) or (1-2): wherein Q represents a carbocyclic group or a heterocyclic group, and R 6 to R 8 independently represent a hydrogen atom or a substituent. The compound represented by the general formula (1-1) or (1-2) has a dissociative hydrogen atom in Q, and the dissociative hydrogen atom in Q and the hydrogen atom in the —NH— group marked with asterisk * are eliminated from the compound, so that the residue is bonded to the metal ion to generate the azo-metal complex dye. The azo-metal complex dye may contain a component other than the metal ion and the compound represented by the general formula (1-1) or (1-2).
• US8394481B2
  申请人：——

  公开号：US8394481B2

  公开（公告）日：2013-03-12
• US9821297B2
  申请人：——

  公开号：US9821297B2

  公开（公告）日：2017-11-21
• Synthesis of the Small Pore Silicoaluminophosphate STA-6 by Using Supramolecular Self-Assembled Organic Structure Directing Agents
  作者：Raquel Martínez-Franco、Ángel Cantín、Manuel Moliner、Avelino Corma

  DOI：10.1021/cm5005483

  日期：2014.8.12

  By means of organic structure directing agents (OSDA) formed by bulky paired quinolinium derived molecules, obtained by self-assembled monomers, it has been possible to synthesize for the first time the pure silicoaluminophosphate form of the small pore STA-6 zeotype. This synthesis method allows obtaining samples with very well dispersed framework silicon atoms, opening the possibility for its use in catalysis.