6-chloro-2-naphthalen-2-yl-4-phenyl-quinoline | 21932-49-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 6-chloro-2-naphthalen-2-yl-4-phenyl-quinoline
• 英文别名: 6-Chloro-2-naphthalen-2-yl-4-phenylquinoline
• CAS: 21932-49-0
• 化学式: C₂₅H₁₆ClN
• 分子量: 365.862
• InChiKey: QIRKVZLPPWMYFX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.4
• 重原子数：
  27
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2'-acetonaphthone carbomethoxyhydrazone 、 2-氨基-5-氯二苯甲酮 生成 6-chloro-2-naphthalen-2-yl-4-phenyl-quinoline
  参考文献：
  名称：

  Mack, H. Michael; Davis, Everette A.; Kadkhodayan, Babak, Journal of Heterocyclic Chemistry, 1987, vol. 24, p. 1733 - 1740

  摘要：

  DOI：

文献信息

• Efficient and environmentally-benign three-component synthesis of quinolines and bis-quinolines catalyzed by recyclable potassium dodecatungstocobaltate trihydrate under microwave irradiation
  作者：Salma Anvar、Iraj Mohammadpoor-Baltork、Shahram Tangestaninejad、Majid Moghadam、Valiollah Mirkhani、Ahmad Reza Khosropour、Reza Kia

  DOI：10.1039/c2ra20639k

  日期：——

  Microwave-assisted one-pot three-component reaction between aromatic amines, aromatic aldehydes and phenylacetylene is accomplished efficiently in the presence of catalytic amounts of potassium dodecatungstocobaltate trihydrate (K5CoW12O40·3H2O) to afford the corresponding quinolines and bis-quinolines in excellent yields. Selective conversion of aromatic aldehyde and also arylacetylene to their corresponding

  微波辅助一锅三元反应的芳香胺，芳香醛和 苯乙炔在催化量的十二水合十二碳五烯酸钴钾三水合物（K 5 CoW 12 O 40 ·3H 2 O）的存在下有效地完成了上述反应，从而以优异的产率提供了相应的喹啉和双喹啉。在脂肪族醛和烷基乙炔的存在下，芳族醛以及芳基乙炔分别选择性地转化为它们相应的喹啉可以被认为是该方法的显着优点，并且使其成为合成喹啉衍生物的有用且有吸引力的方法。该催化剂可以重复使用数个循环而不会显着降低其催化活性。
• Blue-emitting materials and electroluminescent devices containing these materials
  申请人：Lucent Technologies Inc.

  公开号：EP0763965A2

  公开（公告）日：1997-03-19

  The present invention is directed to a class of blue emitting materials, that, when placed in EL devices with an emitter layer and a hole transporter layer, provide EL devices that emit white light. The blue-emitting material has a non-polymeric molecular structure that comprises a five or six-membered heterocyclic moiety selected from the groups consisting of oxazole, imidazole, quinoline and pyrazine with at least three organic substituents pendant thereto. The blue-emitting materials of the present invention have certain characteristics that allow them to be formed into films with advantageous properties. The films formed from these materials are amorphous (i.e they have a crystal size less than about 1000 Å). The thickness of the films of the blue-emitting material is less than 600 Å in the devices of the present invention.

  本发明涉及一类蓝色发光材料，当将其置于带有发射器层和空穴传输层的电致发光器件中时，可提供发射白光的电致发光器件。该蓝色发光材料具有非聚合物分子结构，包括一个五元或六元杂环分子，该杂环分子选自由噁唑、咪唑、喹啉和吡嗪组成的基团，其上至少有三个有机取代基。本发明的发蓝材料具有某些特性，可将其制成具有优势特性的薄膜。由这些材料形成的薄膜是无定形的（即晶体尺寸小于约 1000 Å）。在本发明的设备中，蓝色发光材料薄膜的厚度小于 600 Å。
• MACK, H. MICHAEL;DAVIS, EVERETTE A.;KADKHODAYAN, BABAK;TAYLOR, RICHARD A.+, J. HETEROCYCL. CHEM., 24,(1987) N 6, 1733-1739
  作者：MACK, H. MICHAEL、DAVIS, EVERETTE A.、KADKHODAYAN, BABAK、TAYLOR, RICHARD A.+

  DOI：——

  日期：——
• US5904994A
  申请人：——

  公开号：US5904994A

  公开（公告）日：1999-05-18
• Mack, H. Michael; Davis, Everette A.; Kadkhodayan, Babak, Journal of Heterocyclic Chemistry, 1987, vol. 24, p. 1733 - 1740
  作者：Mack, H. Michael、Davis, Everette A.、Kadkhodayan, Babak、Taylor, Richard A.、Duncan, Dean C.、Beam, Charles F.

  DOI：——

  日期：——