N-[3-(8-甲基壬氧基)丙基]丙烷-1,3-二胺 | 72162-46-0

• 物质功能分类: 有机原料 - 氨基化合物
• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: N-[3-(8-甲基壬氧基)丙基]丙烷-1,3-二胺
• 中文别名: 异癸氧基丙基丙撑二胺；异十烷氧基丙基丙二胺；异十烷氧基丙基丙撑二胺
• 英文名称: N1-(3-((8-methylnonyl)oxy)propyl)propane-1,3-diamine
• 英文别名: 1,3-Propanediamine, N-[3-(isodecyloxy)propyl]-；N'-[3-(8-methylnonoxy)propyl]propane-1,3-diamine
• CAS: 72162-46-0
• 化学式: C₁₆H₃₆N₂O
• 分子量: 272.475
• InChiKey: LMVFSACRPDMFSQ-UHFFFAOYSA-N

物化性质

• 沸点：
  252-302℃ at 102.4kPa
• 密度：
  0.883-0.883g/cm3 at 20℃
• LogP：
  2.7 at 23℃ and pH7.9-8.3
• 表面张力：
  26-26.2mN/m at 1g/L and 20℃
• 解离常数：
  8.5-10.19 at 25℃

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  19
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  47.3
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  全氟酞菁锌 、 N-[3-(8-甲基壬氧基)丙基]丙烷-1,3-二胺 以 N,N-二甲基甲酰胺 为溶剂， 反应 16.0h， 以28%的产率得到
  参考文献：
  名称：

  通过点击化学扭曲酞菁：光声、光热和表面增强共振拉曼研究。

  摘要：

  名义上平面酞菁大环的畸变会影响激发态动力学，因为大部分激发态能量通过内部转换而衰减。全氟酞菁平台上的点击型成环反应将七元环附加到一个或多个异吲哚的 β 位上，从而扭曲大环并调节溶解度。扭曲的导数可以实现光声成像、光热效应和强表面增强共振拉曼信号。

  DOI：

  10.1002/chem.201903463

文献信息

• Improved multifunctional viscosity index modifier additives derived from polyamines containing one primary amino group and at least one secondary amino group
  申请人：EXXON CHEMICAL PATENTS INC.

  公开号：EP0400866A1

  公开（公告）日：1990-12-05

  An oil soluble composition useful as a multifunctional viscosity improver additive for oleaginous composition :omprising adduct of: (A) high molecular weight ethylene copolymer substituted carboxylic acid material comprising reaction product of (i) ethylene copolymer having a number average molecular weight of at least 15,000, and (ii) monounsaturated carboxylic acid material; and (B) at least one polyamine contining one primary amino group and at least one, preferably from 1 to 6, secondary amino group.

  一种可溶于油的组合物，可用作含油组合物的多功能粘度改进剂添加剂：包含以下成分的加合物：： (A) 高分子量乙烯共聚物取代羧酸材料，包括(i)平均分子量至少为 15,000 的乙烯共聚物和(ii)单不饱和羧酸材料的反应产物；以及 (B) 至少一种含有一个伯氨基和至少一个（最好是 1 至 6 个）仲氨基的多胺。
• Multifunctional viscosity index improver derived from polyamine containing one primary amino group and at least one secondary amino group exhibiting improved low temperature viscometric properties
  申请人：EXXON CHEMICAL PATENTS INC.

  公开号：EP0400870A1

  公开（公告）日：1990-12-05

  Composition of matter useful as a multifunctional viscosity index improver for lubricating oils comprising reaction product of: (i) (a) copolymer of ethylene and at least one other alpha-olefin monomer, said copolymer comprising intramolecularly heterogeneous copolymer chains containing at least one crystallizable segment of methylene units and at least one low crystallinity ethylene-alpha-olefin copolymer segment, wherein said at least one crystallizable segment comprises at least about 10 weight percent of said copolymer chain and contains at least about 57 weight percent of said copolymer chain and contains at least about 57 weight percent ethylene, wherein said low crystalliity segment contains not greater than about 53 weight percent ethylene, and wherein said copolymer has a molecular weight distribution characterized by at least one of a ratio of M W/ Mn of less than 2 and a ratio of M z/ M of less than 1.8 and wherein at least two portions of an individual intramolecularly heterogeneous chain, each portion comprisig at least 5 weight percent of said chain, differ incomposition form one antoher by at least 7 weight percent ethylene, said copolymer grafted with (b) ethylenically monounsaturated carboxylic acid material having 1 to 2 carboxylic acid groups or anhydride group to form grafted ethylene copolymer; and (ii) at least one polyamine containing one primary amino group and from 1 to about 6 secondary amino groups.

  可用作润滑油多功能粘度指数改进剂的物质组合物，包括下列物质的反应产物 (i) (a) 乙烯和至少另一种α-烯烃单体的共聚物，所述共聚物包括分子内异构共聚物链，其中至少含有一个亚甲基单元的可结晶段和至少一个低结晶度的乙烯-α-烯烃共聚物段、其中所述至少一个可结晶段包含至少约 10 重量百分比的所述共聚物链，并且包含至少约 57 重量百分比的所述共聚物链，并且包含至少约 57 重量百分比的乙烯，其中所述低结晶度段包含不大于约 53 重量百分比的乙烯，并且所述共聚物具有分子量分布，其特征在于 M W/ Mn 之比小于 2 和 M z/ M 之比小于 1 中的至少一个。(b) 具有 1 至 2 个羧酸基团或酸酐基团的乙烯基单不饱和羧酸材料，以形成接枝乙烯共聚物；和 (i) 至少一种多胺，其特征为 M W/ Mn 的比率小于 2 和 M z/ M 的比率小于 1。 (ii) 至少一种含有一个伯氨基和 1 至 6 个仲氨基的多胺。
• Multifunctional viscosity index improver
  申请人：EXXON CHEMICAL PATENTS INC.

  公开号：EP0422857A2

  公开（公告）日：1991-04-17

  Composition of matter useful as a multifunctional viscosity index improver for lubricating oils comprising reaction product of: (i) (a) degraded ethylene-alpha-olefin copolymer obtained by degrading undegraded copolymer of ethylene and at least one other alpha-olefin monomer, said undegraded copolymer comprising intramolecularly heterogeneous copolymer chains containing at least one crystallizable segment of methylene units and at least one low crystallinity ethylene-alpha- olefin copolymer segment, wherein said at least one crystallizable segment comprises at least about 10 weight percent of said copolymer chain and contains at least about 57 weight percent of said copolymer chain and contains at least about 57 weight percent ethylene, wherein said low crystallinity segment contains not greater than about 53 weight percent ethylene, and wherein said copolymer has a molecular weight distribution characterized by at least one of a ratio of M w/M n of less than 2 and a ratio of M z/M w of less than 1.8 and wherein at least two portions of an individual intramolecularly heterogeneous chain, each portion comrising at least 5 weight percent of said chain, differ in composition form one another by at least 7 weight percent ethylene; said degraded copolymer grafted with (b) ethylenically monounsaturated carboxylic acid material having 1 to 2 carboxylic acid groups or anhydride group to form grafted degraded ethylene copolymer; and (ii) at least one polyamine containing one primary amino group and from 1 to about 6 secondary amino groups.

  可用作润滑油多功能粘度指数改进剂的物质组合物，包括下列物质的反应产物 (i) (a) 降解乙烯-α-烯烃共聚物，该共聚物通过降解未降解的乙烯和至少另一种 α-烯烃单体共聚物而获得，所述未降解共聚物包含分子内异构共聚物链，其中 至少含有一个亚甲基单元可结晶段和至少一个低结晶度乙烯-α-烯烃共聚物段、其中所述至少一个可结晶段包含至少约 10 重量百分比的所述共聚物链，并且包含至少约 57 重量百分比的所述共聚物链，并且包含至少约 57 重量百分比的乙烯，其中所述低结晶度段包含不大于约 53 重量百分比的乙烯，并且所述共聚物具有分子量分布，其特征为 M w/M n 的比率小于 2 和 M z/M w 的比率小于 1 中的至少一个。(b) 具有 1 至 2 个羧酸基团或酸酐基团的乙烯基单不饱和羧酸材料接枝的降解共聚物，以形成接枝的降解乙烯共聚物；以及 (i) 具有 1 至 2 个羧酸基团或酸酐基团的乙烯基单不饱和羧酸材料接枝的降解共聚物。 (ii) 至少一种含有一个伯氨基和 1 至 6 个仲氨基的多胺。
• Water dispersed polyurethane polymer for improved coatings and adhesives
  申请人：H.B. FULLER LICENSING & FINANCING, INC.

  公开号：EP0552420A2

  公开（公告）日：1993-07-28

  Improved water dispersed polyurethanes are disclosed. Polyurethane-urea polymers in aqueous dispersion are obtained by chain extending an NCO-containing prepolymer in aqueous medium. The NCO-containing prepolymer is prepared by reacting a polyisocyanate with an active hydrogen-containing compound such as a polyol and an extended aliphatic diamine monomer, the reaction product of which is then dispersed in water and chain extended. The improved water dispersed polyurethane polymers of the invention are excellent coatings and adhesives.

  本发明公开了改进型水分散聚氨酯。水分散型聚氨酯-尿素聚合物是通过在水介质中对含 NCO 的预聚物进行链延伸而获得的。含 NCO 预聚物的制备方法是将多异氰酸酯与活性含氢化合物（如多元醇）和延伸脂肪族二胺单体反应，然后将反应产物分散在水中并进行链延伸。本发明的改进型水分散聚氨酯聚合物是优良的涂料和粘合剂。
• N-alkylsubstituted naphthalenesulfonic acid derivatives in fluids compositions
  申请人：KING INDUSTRIES, INC.

  公开号：EP1275707A1

  公开（公告）日：2003-01-15

  A functional fluid composition comprising a mixture of: (a) at least one functional fluid base stock; and (b) an additive package comprising at least one derivative of a mono-, di-, or poly-alkylated naphthalenesulfonic acid selected from the group consisting of: (i) neutral metal salts of said mono-, di-, and poly-alkylated naphthalenesulfonic acids; (ii) basic metal salts of said mono-, di-, and poly-alkylated naphthalenesulfonic acids; (iii) amine salts of said mono-, di-, and poly-alkylated naphthalenesulfonic acids; and (iv) esters of said mono-, di-, and poly-alkylated naphthalenesulfonic acids; wherein the mono-, di-, and poly-alkylated naphthalenesulfonic acids are represented by formula (I): wherein R1, R2, R3 and R4 are individually selected from the group consisting of hydrogen and essentially linear hydrocarbyl groups having about 10 to about 14 carbon atoms; and wherein l, m, n and p are integers from 0 to 4 and the sum of 1 + m + n + p is at least 1; and wherein R1, R2, R3, or R4 is a hydrogen where either l, m, n, or p is 0.

  一种功能性流体组合物，由以下物质的混合物组成： (a) 至少一种功能性流体基础油；和 (b) 一种复合添加剂，包含至少一种单、双或多烷基化萘磺酸的衍生物，该 衍生物选自由下列物质组成的组 (i) 上述单、双或多烷基化萘磺酸的中性金属盐； (ii) 单、双和多烷基化萘磺酸的碱金属盐； (iii) 所述单、双和多烷基化萘磺酸的胺盐；以及 (iv) 单烷基化、双烷基化和多烷基化萘磺酸的酯； 其中单烷基化、双烷基化和多烷基化萘磺酸由式 (I) 表示： 其中 R1、R2、R3 和 R4 单独选自由氢和具有约 10 至约 14 个碳原子的基本线性烃基组成的组；且 l、m、n 和 p 为 0 至 4 的整数，且 1 + m + n + p 的和至少为 1；以及其中 R1、R2、R3 或 R4 为氢，其中 l、m、n 或 p 均为 0。