Cyclohexanon-dipropylketal | 33781-76-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Cyclohexanon-dipropylketal
• 英文别名: 1,1-Dipropoxycyclohexane
• CAS: 33781-76-9
• 化学式: C₁₂H₂₄O₂
• 分子量: 200.321
• InChiKey: IEIYNUJMIWPRGL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  14
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  Cyclohexanon-dipropylketal 在 lithium aluminium tetrahydride 、 三氯化铝 作用下， 以 乙醚 为溶剂， 生成 环己基-丙基醚
  参考文献：
  名称：

  Reduction with Metal Hydrides. XII. Reduction of Acetals and Ketals with Lithium Aluminum Hydride-Aluminum Chloride

  摘要：

  DOI：

  10.1021/ja00871a020
• 作为产物：
  描述：

  丙醇 、 环己酮二甲缩酮 在 对甲苯磺酸 作用下， 以 苯 为溶剂， 生成 Cyclohexanon-dipropylketal
  参考文献：
  名称：

  Preparation of Ketals from 2,2-Dimethoxypropane¹

  摘要：

  DOI：

  10.1021/jo01074a010

文献信息

• A novel, mesoporous molybdenum doped titanium dioxide/reduced graphene oxide composite as a green, highly efficient solid acid catalyst for acetalization
  作者：Wimalika R. K. Thalgaspitiya、Tharindu Kankanam Kapuge、Junkai He、Peter Kerns、Andrew G. Meguerdichian、Steven L. Suib

  DOI：10.1039/c9dt03633d

  日期：——

  A novel, mesoporous molybdenum doped titanium dioxide-reduced graphene oxide composite is synthesized as a highly efficient heterogeneous solid acid catalyst.

  一种新型的介孔钼掺杂二氧化钛-还原石墨烯复合材料被合成为高效的异质固体酸催化剂。
• NOVEL AMINOGLYCOSIDE ANTIBIOTICS
  申请人：Kobayashi Yoshihiko

  公开号：US20120165283A1

  公开（公告）日：2012-06-28

  This invention relates to novel aminoglycoside antibiotics, which have potent antimicrobial activity against bacteria, which induce infectious diseases, particularly MRSA, and has no significant nephrotoxicity, and process for producing them. More particularly, the present invention relates to compounds represented by formula (Ia) or their pharmacologically acceptable salts or solvates, or their diastereomer mixtures, antimicrobial agents comprising them, and a process for producing them.

  这项发明涉及一种新型氨基糖苷类抗生素，对引起感染性疾病的细菌，特别是MRSA具有强效的抗菌活性，并且没有显著的肾毒性，并提供制备它们的方法。更具体地，本发明涉及由式（Ia）表示的化合物或其药理学上可接受的盐或溶剂合物，或其对映体混合物，包括它们的抗微生物剂以及制备它们的方法。
• Novel aminoglycoside antibiotics
  申请人：Kobayashi Yoshihiko

  公开号：US20090186841A1

  公开（公告）日：2009-07-23

  This invention relates to novel aminoglycoside antibiotics, which have potent antimicrobial activity against bacteria, which induce infectious diseases, particularly MRSA, and has no significant nephrotoxicity, and process for producing them. More particularly, the present invention relates to compounds represented by formula (Ia) or their pharmacologically acceptable salts or solvates, or their diastereomer mixtures, antimicrobial agents comprising them, and a process for producing them.

  本发明涉及一种新型氨基糖苷类抗生素，对引起传染病的细菌，特别是MRSA具有强效的抗微生物活性，并且没有显著的肾毒性，并提供了其生产方法。更具体地说，本发明涉及由式（Ia）表示的化合物或其药理学上可接受的盐或溶剂或其对映体混合物，包含它们的抗微生物剂以及生产它们的方法。
• Photocurable coating composition, laminate, and automotive headlamp covering sheet
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP2865720A1

  公开（公告）日：2015-04-29

  A photocurable coating composition is provided comprising (1) surface-treated titanium oxide comprising core/shell type microparticles each consisting of a titanium oxide core and a silicon oxide shell, which are treated with two surface treating components having formula (I): R1Si(OR2)3 wherein R1 is an organic group which may have a (meth)acrylic moiety, and R2 is alkyl, and formula (II): (R3R4 2Si)2NH wherein R3 is an organic group which may have a (meth)acrylic moiety, and R4 is alkyl, (2) a photopolymerizable monomer or oligomer, and (3) a photoinitiator. The composition has good transparency and mar resistance despite titanium oxide loading.

  本发明提供了一种光固化涂层组合物，包括(1)表面处理过的氧化钛，该氧化钛由核/壳型微粒组成，每个微粒都由氧化钛核和氧化硅壳组成，并用两种表面处理成分进行处理，这两种表面处理成分具有式(I)：R1Si(OR2)3 其中 R1 是有机基团，可以是(甲基)丙烯酸基团，R2 是烷基，和式 (II)：(R3R4 2Si)2NH 其中 R3 是有机基团，可以是(甲基)丙烯酸基团，R4 是烷基，(2) 可光聚合的单体或低聚物，和 (3) 光引发剂。尽管添加了氧化钛，该组合物仍具有良好的透明度和耐磨性。
• Titania-containing coating composition and coated article
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP2868717A1

  公开（公告）日：2015-05-06

  A coating composition is provided comprising (A) 1-50 parts by weight of surface-treated titanium oxide comprising core/shell type microparticles each consisting of a titanium oxide core and a silicon oxide shell, which are treated with two surface treating components having formula (I): R1Si(OR2)3 and formula (II): (R3R42Si)2NH, (B) 100 parts by weight of a vinyl copolymer obtained from copolymerization of (b-1) an alkoxysilyl-containing vinyl monomer, (b-2) a UV-absorbing vinyl monomer, and (b-3) another monomer, and (C) a solvent. A cured film of the composition has improved mar resistance and UV shielding while maintaining visible light transparency.

  提供了一种涂层组合物，它包括(A)1-50 份(重量)经表面处理的氧化钛，这些氧化钛由核/壳型微粒组成，每个微粒由氧化钛核和氧化硅壳组成，这些微粒经两种表面处理成分处理，这两种表面处理成分分别为式(I)：R1Si(OR2)3 和式 (II)：(R3R42Si)2NH，(B) 100 重量份的乙烯基共聚物，由(b-1)含烷氧基硅烷的乙烯基单体、(b-2)紫外线吸收乙烯基单体和(b-3)另一种单体共聚而成，以及(C)溶剂。该组合物固化后的薄膜具有更好的抗磨损性和紫外线屏蔽性，同时还能保持可见光的透明度。