10-(4'-(9H-carbazol-9-yl)biphenyl-4-yl)acridin-9(10H)-one | 1188546-11-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 10-(4'-(9H-carbazol-9-yl)biphenyl-4-yl)acridin-9(10H)-one
• 英文别名: 10-(4'-(9H-Carbazol-9-yl)-[1,1'-biphenyl]-4-yl)acridin-9(10H)-one；10-[4-(4-carbazol-9-ylphenyl)phenyl]acridin-9-one
• CAS: 1188546-11-3
• 化学式: C₃₇H₂₄N₂O
• 分子量: 512.61
• InChiKey: NUEUGIQIUCNWPS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.4
• 重原子数：
  40
• 可旋转键数：
  3
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  25.2
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  9-(4'-溴联苯-4-基)-9H-咔唑 、 吖啶酮 在 copper(l) iodide 、 丙二酸二叔丁酯 、 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 24.0h， 以82%的产率得到10-(4'-(9H-carbazol-9-yl)biphenyl-4-yl)acridin-9(10H)-one
  参考文献：
  名称：

  Acridinone/Amine(carbazole)-Based Bipolar Molecules: Efficient Hosts for Fluorescent and Phosphorescent Emitters

  摘要：

  Three acridinone-based molecules ADBP, ACBP, and DABP were synthesized, and their application to the OLED devices was investigated. When used as the host for either the deep blue singlet or the green triplet emitter in OLED devices, the bipolar molecules ADBP and ACBP demonstrated superior performance compared to either DABP or commonly used host CBP, remarkably lowering the drive voltage and improving efficiencies.

  DOI：

  10.1021/ol901584g

文献信息

• Spiro-condensed lactam compounds for organic electroluminescent devices
  申请人：Merck Patent GmbH

  公开号：US11121327B2

  公开（公告）日：2021-09-14

  The invention relates to polycondensed lactam compounds as materials for use in electronic devices, and electronic devices, in particular organic electroluminescent devices, containing said materials.

  本发明涉及作为电子设备材料的聚缩内酰胺化合物，以及含有上述材料的电子设备，特别是有机电致发光设备。
• SPIROKONDENSIERTE LACTAMVERBINDUNGEN FÜR ORGANISCHE ELEKTROLUMINESZENZVORRICHTUNGEN
  申请人：Merck Patent GmbH

  公开号：EP3016952B1

  公开（公告）日：2019-05-15
• SPIRO-CONDENSED LACTAM COMPOUNDS FOR ORGANIC ELECTROLUMINESCENT DEVICES
  申请人：MERCK PATENT GMBH

  公开号：US20160372681A1

  公开（公告）日：2016-12-22

  The invention relates to polycondensed lactam compounds as materials for use in electronic devices, and electronic devices, in particular organic electroluminescent devices, containing said materials.
• [DE] SPIROKONDENSIERTE LACT AMVERBI NDUNGEN FÜR ORGANISCHE ELEKTROLUMINESZENZVORRICHTUNGEN<br/>[EN] SPIRO-CONDENSED LACTAM COMPOUNDS FOR ORGANIC ELECTROLUMINESCENT DEVICES<br/>[FR] COMPOSÉS DE LACTAME SPIROCONDENSÉS POUR DES DISPOSITIFS ÉLECTROLUMINESCENTS ORGANIQUES
  申请人：MERCK PATENT GMBH

  公开号：WO2015000542A1

  公开（公告）日：2015-01-08

  Die vorliegende Erfindung betrifft polykondensierte Lactamverbindungen als Materialien für die Verwendung in elektronischen Vorrichtungen, sowie elektronische Vorrichtungen, insbesondere organische Elektrolumineszenzvorrichtungen, enthaltend diese Materialien.
• Acridinone/Amine(carbazole)-Based Bipolar Molecules: Efficient Hosts for Fluorescent and Phosphorescent Emitters
  作者：Dileep A. K. Vezzu、Joseph C. Deaton、Mohammad Shayeghi、Yumin Li、Shouquan Huo

  DOI：10.1021/ol901584g

  日期：2009.10.1

  Three acridinone-based molecules ADBP, ACBP, and DABP were synthesized, and their application to the OLED devices was investigated. When used as the host for either the deep blue singlet or the green triplet emitter in OLED devices, the bipolar molecules ADBP and ACBP demonstrated superior performance compared to either DABP or commonly used host CBP, remarkably lowering the drive voltage and improving efficiencies.