10-(cyclohexylmethyl)-9(10H)-acridone | 1313736-99-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 10-(cyclohexylmethyl)-9(10H)-acridone
• 英文别名: 10-(Cyclohexylmethyl)acridin-9-one
• CAS: 1313736-99-0
• 化学式: C₂₀H₂₁NO
• 分子量: 291.393
• InChiKey: XTGRQLKYFUAVAT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  22
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.35
• 拓扑面积：
  20.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  10-(cyclohexylmethyl)-9(10H)-acridone 在 盐酸 、 锌 、 硝酸 作用下， 以 乙醇 、 水 为溶剂， 反应 20.0h， 以50%的产率得到N,N'-bis(cyclohexylmethyl)-9,9'-biacridinium dinitrate
  参考文献：
  名称：

  “Supramolecular Circuitry”: Three Chemiluminescent, Cucurbit[7]uril-Controlled On/Off Switches

  摘要：

  Three Cucurbit[7]uril-controlled chemiluminescent on/off switches based on the lucigenin motif have been synthesized. Light emission Is triggered upon addition of sodium peroxide, interrupted or dimmed in the presence of Cucurbit[7]uril, and restored upon injection of a competitive guest. The process, which can be mimicked by a simple resistor-capacitor circuit, is rationalized by examining the role of the macrocyclic host on the network of equilibria involved in the chemiluminescent process.

  DOI：

  10.1021/ol201403m
• 作为产物：
  描述：

  N,N'-bis(cyclohexylmethyl)-9,9'-biacridinium dinitrate 在 sodium peroxide 作用下， 以 水 为溶剂， 反应 2.0h， 生成 10-(cyclohexylmethyl)-9(10H)-acridone
  参考文献：
  名称：

  “Supramolecular Circuitry”: Three Chemiluminescent, Cucurbit[7]uril-Controlled On/Off Switches

  摘要：

  Three Cucurbit[7]uril-controlled chemiluminescent on/off switches based on the lucigenin motif have been synthesized. Light emission Is triggered upon addition of sodium peroxide, interrupted or dimmed in the presence of Cucurbit[7]uril, and restored upon injection of a competitive guest. The process, which can be mimicked by a simple resistor-capacitor circuit, is rationalized by examining the role of the macrocyclic host on the network of equilibria involved in the chemiluminescent process.

  DOI：

  10.1021/ol201403m

文献信息

• PIGMENT DISPERSION AND INK COMPOSITION USING THE SAME
  申请人：YASUDA Koji

  公开号：US20100081758A1

  公开（公告）日：2010-04-01

  Disclosed is a pigment dispersion containing a polymer compound having a partial structure represented by the following formula (1) at a terminal end of a main chain of the polymer compound, and a pigment. In formula (1), R 1 and R 2 each independently represent a hydrogen atom or a monovalent substituent; R 1 and R 2 may form a ring by bonding with each other; and * represents a position that is directly or indirectly bonded to the main chain structure of the compound.
• US8039542B2
  申请人：——

  公开号：US8039542B2

  公开（公告）日：2011-10-18
• “Supramolecular Circuitry”: Three Chemiluminescent, Cucurbit[7]uril-Controlled On/Off Switches
  作者：Eric Masson、Yasser M. Shaker、Jean-Pierre Masson、Martin E. Kordesch、Citra Yuwono

  DOI：10.1021/ol201403m

  日期：2011.8.5

  Three Cucurbit[7]uril-controlled chemiluminescent on/off switches based on the lucigenin motif have been synthesized. Light emission Is triggered upon addition of sodium peroxide, interrupted or dimmed in the presence of Cucurbit[7]uril, and restored upon injection of a competitive guest. The process, which can be mimicked by a simple resistor-capacitor circuit, is rationalized by examining the role of the macrocyclic host on the network of equilibria involved in the chemiluminescent process.