(E)-6-methyl-non-5-en-4-one | 22287-10-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (E)-6-methyl-non-5-en-4-one
• 英文别名: 5-Nonen-4-one, 6-methyl-；(E)-6-methylnon-5-en-4-one
• CAS: 22287-10-1
• 化学式: C₁₀H₁₈O
• 分子量: 154.252
• InChiKey: JCTGAYLAAYJGRN-CMDGGOBGSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  11
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2-戊酮 在 sodium methylate 作用下， 以 甲醇 为溶剂， 生成 (E)-6-methyl-non-5-en-4-one
  参考文献：
  名称：

  Spectral correlations for .alpha.,.beta.-unsaturated ketones

  摘要：

  DOI：

  10.1021/jo00827a017

文献信息

• Polyalkylhydroxychromene and process for preparing the same
  申请人：MITSUI PETROCHEMICAL INDUSTRIES, LTD.

  公开号：EP0021827A1

  公开（公告）日：1981-01-07

  A compound of the formula (1) wherein R1 and R5 each represents an alkyl group having 1 to3 3 carbon atoms; R2, R3 and R4 each represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms and wherein the bonding at the 2-3 position is a single bond and that at the 3-4 position is a double when the substitution of hydroxy group is at the 5-position or the bonding at the 2-3 position is a double bond and that at the 3-4 position is a single bond when the substitution of hydroxy group is at the 7-position:; with the proviso that R2 and R4 should not be a hydrogen atom or an alkyl group simultaneously. Such a compound can be prepared by reacting resorcinol with an aliphatic ketone or a tertiary alcohol or by thermally decomposing polyalkyl (2, 4 - dihydroxyphenyl) hydroxychroman. The compound is useful as a herbicide and fungicide and as an intermediate for preparing agricultural chemicals.

  式（1）的化合物 其中 R1 和 R5 各代表一个具有 1 至 3 个碳原子的烷基；R2、R3 和 R4 各代表一个氢原子或一个具有 1 至 3 个碳原子的烷基；当羟基的取代位于 5 位时，2-3 位的键合是单键，3-4 位的键合是双键；当羟基的取代位于 7 位时，2-3 位的键合是双键，3-4 位的键合是单键：但 R2 和 R4 不能同时为氢原子或烷基。这种化合物可以通过间苯二酚与脂肪族酮或叔醇反应，或通过热分解多烷基（2，4-二羟基苯基）羟基苯并吡喃来制备。该化合物可用作除草剂和杀真菌剂，以及制备农药的中间体。
• RUTHENIUM COMPLEX AND METHOD FOR PRODUCING SAME, AND METHOD FOR PRODUCING RUTHENIUM-CONTAINING THIN FILM
  申请人：Tosoh Corporation

  公开号：EP2930179B1

  公开（公告）日：2018-09-05
• RUTHENIUM COMPLEX, METHOD FOR PRODUCING SAME, AND METHOD FOR PRODUCING RUTHENIUM-CONTAINING THIN FILM
  申请人：TOSOH CORPORATION

  公开号：US20150303063A1

  公开（公告）日：2015-10-22

  The present invention is to provide a ruthenium complex represented by formula (1a), (2), (3), etc., which is useful for producing a ruthenium-containing thin film both under the conditions using an oxidizing gas as the reaction gas and under the conditions using a reducing gas as the reaction gas: wherein R 1a to R 7a , R 8 , R 9 and R 10 to R 18 represents an alkyl group having a carbon number of 1 to 6, etc., and n represents an integer of 0 to 2.
• US4002684A
  申请人：——

  公开号：US4002684A

  公开（公告）日：1977-01-11
• US4005145A
  申请人：——

  公开号：US4005145A

  公开（公告）日：1977-01-25