2-((3aR)-7c-methanesulfonyloxy-2,2-dimethyl-(3ar,7ac)-3a,6,7,7a-tetrahydro-benzo[1,3]dioxol-5-yl)-N-methyl-2-oxo-acetamide | 26681-52-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-((3aR)-7c-methanesulfonyloxy-2,2-dimethyl-(3ar,7ac)-3a,6,7,7a-tetrahydro-benzo[1,3]dioxol-5-yl)-N-methyl-2-oxo-acetamide
• CAS: 26681-52-7
• 化学式: C₁₃H₁₉NO₇S
• 分子量: 333.362
• InChiKey: UYIMYKIYQOZPMO-FXPVBKGRSA-N

反应信息

• 作为反应物：
  描述：

  重氮甲烷 、 2-((3aR)-7c-methanesulfonyloxy-2,2-dimethyl-(3ar,7ac)-3a,6,7,7a-tetrahydro-benzo[1,3]dioxol-5-yl)-N-methyl-2-oxo-acetamide 生成 (Ξ)-2-((3aR)-4c-methanesulfonyloxy-2,2-dimethyl-(3ar,8ac,8bc)-3a,4,56,8a,8b-hexahydro-[1,3]dioxolo[4,5-e]indazol-5ac-yl)-oxiranecarboxylic acid methylamide
  参考文献：
  名称：

  Synthetic intermediates potentially useful for the synthesis of tetrodotoxin and derivatives. III. Synthesis of a key lactone intermediate from shikimic acid

  摘要：

  DOI：

  10.1021/jo00800a025