(1S)-7endo-acetoxy-10exo-hydroxy-5endo-((1S,2S)-2-hydroxy-1-methyl-propyl)-2exo,6endo,8exo,10endo,12endo,17syn-hexamethyl-15-phenyl-4,14,16-trioxa-15-bora-bicyclo[11.3.1]heptadecane-3,9-dione | 51021-70-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 内酯类
• 英文名称: (1S)-7endo-acetoxy-10exo-hydroxy-5endo-((1S,2S)-2-hydroxy-1-methyl-propyl)-2exo,6endo,8exo,10endo,12endo,17syn-hexamethyl-15-phenyl-4,14,16-trioxa-15-bora-bicyclo[11.3.1]heptadecane-3,9-dione
• CAS: 51021-70-6
• 化学式: C₃₁H₄₇BO₉
• 分子量: 574.52
• InChiKey: VRIURPVBVSOKLV-UCPIXTOPSA-N

反应信息

• 作为产物：
  描述：

  (3R)-12t-acetoxy-4t,6t,9c-trihydroxy-14t-((1S,2S)-2-hydroxy-1-methyl-propyl)-3r,5c,7t,9t,11c,13t-hexamethyl-oxacyclotetradecane-2,10-dione 、 苯硼酸 以 苯 为溶剂， 生成 (1S)-7endo-acetoxy-10exo-hydroxy-5endo-((1S,2S)-2-hydroxy-1-methyl-propyl)-2exo,6endo,8exo,10endo,12endo,17syn-hexamethyl-15-phenyl-4,14,16-trioxa-15-bora-bicyclo[11.3.1]heptadecane-3,9-dione
  参考文献：
  名称：

  Cyclic phenylboronates as hydroxyl protecting groups in the synthesis of monoesters of macrolide aglycones

  摘要：

  DOI：

  10.1021/jo00924a008