copper(II) 1-dodecyl-4-(10,15,20-triphenyl-5-porphinyl)pyridinium bromide complex | 95179-18-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: copper(II) 1-dodecyl-4-(10,15,20-triphenyl-5-porphinyl)pyridinium bromide complex
• CAS: 95179-18-3
• 化学式: Br*C₅₅H₅₂CuN₅
• 分子量: 926.501
• InChiKey: UAWAKZMREAGHNG-OPCJBMRSSA-M

反应信息

• 作为产物：
  描述：

  copper(ll) bromide 、 5-(1-dodecylpyridinium-4-yl)-10,15,20-triphenylporphyrin bromide 以 乙醇 为溶剂， 生成 copper(II) 1-dodecyl-4-(10,15,20-triphenyl-5-porphinyl)pyridinium bromide complex
  参考文献：
  名称：

  Optical and ESR Studies on the Micellar Formation with Surfactant Cu(II)–Porphyrin

  摘要：

  A new surface-active porphyrin, 1-dodecyl-4-(10,15,20-triphenyl-5-porphinyl)pyridinium bromide, and its copper complex (Cu(II)DPyTPP) were synthesized. In toluene, chloroform and ethanol, a typical ESR hyperfine structure (hfs) ascribable to monomeric Cu(II) porphyrin was observed. In ethanol containing a buffer of pH=7.4, a reversible formation of the micellar colloid which is strongly dependent on the water/ethanol mixing ratio, was confirmed based on mearsurements of ESR line broadening and the splitting of the Soret band.

  DOI：

  10.1246/bcsj.57.3587