5-(1-dodecylpyridinium-4-yl)-10,15,20-triphenylporphyrin bromide | 95245-04-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: 5-(1-dodecylpyridinium-4-yl)-10,15,20-triphenylporphyrin bromide
• CAS: 95245-04-8
• 化学式: Br*C₅₅H₅₄N₅
• 分子量: 864.971
• InChiKey: YVZNYJNXAHBWSZ-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  copper(ll) bromide 、 5-(1-dodecylpyridinium-4-yl)-10,15,20-triphenylporphyrin bromide 以 乙醇 为溶剂， 生成 copper(II) 1-dodecyl-4-(10,15,20-triphenyl-5-porphinyl)pyridinium bromide complex
  参考文献：
  名称：

  Optical and ESR Studies on the Micellar Formation with Surfactant Cu(II)–Porphyrin

  摘要：

  A new surface-active porphyrin, 1-dodecyl-4-(10,15,20-triphenyl-5-porphinyl)pyridinium bromide, and its copper complex (Cu(II)DPyTPP) were synthesized. In toluene, chloroform and ethanol, a typical ESR hyperfine structure (hfs) ascribable to monomeric Cu(II) porphyrin was observed. In ethanol containing a buffer of pH=7.4, a reversible formation of the micellar colloid which is strongly dependent on the water/ethanol mixing ratio, was confirmed based on mearsurements of ESR line broadening and the splitting of the Soret band.

  DOI：

  10.1246/bcsj.57.3587
• 作为产物：
  描述：

  溴代十二烷 、 5-(4-pyridyl)-10,15,20-triphenylporphyrin 以 N,N-二甲基甲酰胺 为溶剂， 以70%的产率得到5-(1-dodecylpyridinium-4-yl)-10,15,20-triphenylporphyrin bromide
  参考文献：
  名称：

  Optical and ESR Studies on the Micellar Formation with Surfactant Cu(II)–Porphyrin

  摘要：

  A new surface-active porphyrin, 1-dodecyl-4-(10,15,20-triphenyl-5-porphinyl)pyridinium bromide, and its copper complex (Cu(II)DPyTPP) were synthesized. In toluene, chloroform and ethanol, a typical ESR hyperfine structure (hfs) ascribable to monomeric Cu(II) porphyrin was observed. In ethanol containing a buffer of pH=7.4, a reversible formation of the micellar colloid which is strongly dependent on the water/ethanol mixing ratio, was confirmed based on mearsurements of ESR line broadening and the splitting of the Soret band.

  DOI：

  10.1246/bcsj.57.3587

文献信息

• Location and photoionization studies of a series of alkylporphyrin derivatives solubilized in dioctadecyldimethylammonium chloride and dihexadecyl phosphate vesicles
  作者：Emmanuelle Chastenet de Castaing、Larry Kevan

  DOI：10.1021/j100177a100

  日期：1991.11