Acetic acid (3R,4S,6R)-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-diphenyl-silanyloxymethyl)-6-phenylsulfanyl-tetrahydro-pyran-3-yl ester | 90670-52-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Acetic acid (3R,4S,6R)-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-diphenyl-silanyloxymethyl)-6-phenylsulfanyl-tetrahydro-pyran-3-yl ester
• CAS: 90670-52-3
• 化学式: C₄₂H₆₄O₆SSi₃
• 分子量: 781.289
• InChiKey: GAFKIKHUEKTVQP-NNCOAAETSA-N

反应信息

• 作为反应物：
  描述：

  Acetic acid (3R,4S,6R)-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-diphenyl-silanyloxymethyl)-6-phenylsulfanyl-tetrahydro-pyran-3-yl ester 在 N-溴代丁二酰亚胺(NBS) 、 4,4'-二氨基二苯乙烯-2,2'-二磺酸 作用下， 生成 Acetic acid (3R,4S,6R)-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-diphenyl-silanyloxymethyl)-6-fluoro-tetrahydro-pyran-3-yl ester 、 Acetic acid (3R,4S,6S)-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-diphenyl-silanyloxymethyl)-6-fluoro-tetrahydro-pyran-3-yl ester
  参考文献：
  名称：

  Practical synthesis of oligosaccharides. Partial synthesis of avermectin B1a

  摘要：

  DOI：

  10.1021/ja00327a021