Acetic acid (3R,3aR,5S)-3-tert-butoxy-3a-methyl-6-oxo-2,3,3a,4,5,6-hexahydro-1H-inden-5-yl ester | 136671-70-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Acetic acid (3R,3aR,5S)-3-tert-butoxy-3a-methyl-6-oxo-2,3,3a,4,5,6-hexahydro-1H-inden-5-yl ester
• CAS: 136671-70-0
• 化学式: C₁₆H₂₄O₄
• 分子量: 280.364
• InChiKey: KCENOVIKWQAACA-SQWLQELKSA-N

反应信息

• 作为反应物：
  描述：

  Acetic acid (3R,3aR,5S)-3-tert-butoxy-3a-methyl-6-oxo-2,3,3a,4,5,6-hexahydro-1H-inden-5-yl ester 以 水 为溶剂， 生成 Acetic acid (1R,3R,3aR,5S)-3-tert-butoxy-1-hydroxy-3a-methyl-6-oxo-2,3,3a,4,5,6-hexahydro-1H-inden-5-yl ester 、 Acetic acid (1S,3R,3aR,5S)-3-tert-butoxy-1-hydroxy-3a-methyl-6-oxo-2,3,3a,4,5,6-hexahydro-1H-inden-5-yl ester
  参考文献：
  名称：

  Biohydroxylations of hydrindenone derivatives

  摘要：

  Antipodal hydrindenones are hydroxylated at the position gamma to the alpha,beta-unsaturated ketone as efficiently in both series.

  DOI：

  10.1016/0040-4039(91)80837-v