(1S,3R,5R,6S,8R,10R,11S,13R,15R,16S,18R,20R,21S,23R,25R,26S,28R,30R,31R,32R,33R,34R,35R,36R,37R,38R,39R,40R,41R)-5,10,15,20,25,30-hexakis(hydroxymethyl)-2,4,7,9,12,14,17,19,22,24,27,29-dodecaoxaheptacyclo[26.2.2.23,6.28,11.213,16.218,21.223,26]dotetracontane-31,32,33,34,35,36,37,38,39,40,41-undecol | 98987-18-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (1S,3R,5R,6S,8R,10R,11S,13R,15R,16S,18R,20R,21S,23R,25R,26S,28R,30R,31R,32R,33R,34R,35R,36R,37R,38R,39R,40R,41R)-5,10,15,20,25,30-hexakis(hydroxymethyl)-2,4,7,9,12,14,17,19,22,24,27,29-dodecaoxaheptacyclo[26.2.2.23,6.28,11.213,16.218,21.223,26]dotetracontane-31,32,33,34,35,36,37,38,39,40,41-undecol
• CAS: 98987-18-9
• 化学式: C₃₆H₆₀O₂₉
• 分子量: 956.855
• InChiKey: DCMUCMVXDYRKOT-DYAMTPTFSA-N

反应信息

• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 生成 (1S,3R,5R,6S,8R,10R,11S,13R,15R,16S,18R,20R,21S,23R,25R,26S,28R,30R,31R,32R,33R,34R,35R,36R,37R,38R,39R,40R,41R)-5,10,15,20,25,30-hexakis(hydroxymethyl)-2,4,7,9,12,14,17,19,22,24,27,29-dodecaoxaheptacyclo[26.2.2.23,6.28,11.213,16.218,21.223,26]dotetracontane-31,32,33,34,35,36,37,38,39,40,41-undecol
  参考文献：
  名称：

  Cycloglycosidation of 1,2-unsaturated maltohexaose and maltoheptaose derivatives with iodonium addition. Conversion of α- and β-cyclodextrins into mono(2-deoxy) derivatives via acyclic intermediates

  摘要：

  Iodonium ion treatment of 1,2-unsaturated heptadeca-O-benzylmaltohexaose and icosa-O-benzylmaltoheptaose derivatives derived from α- and βcyclodextrins brought about their recyclization by intramolecular glycosidation, giving mono(2-deoxy-2-iodo)-α- and -β-cyclodextrin derivatives, which were converted into mono(2-deoxy)-α- and -β-cyclodextrins by radical reduction.

  DOI：

  10.1039/c39920000510