((1S,4R,5S,6S)-4,5,6-Tris-benzyloxy-cyclohex-2-enyl)-((2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-ylmethyl)-thiocarbamic acid S-benzyl ester | 140933-98-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: ((1S,4R,5S,6S)-4,5,6-Tris-benzyloxy-cyclohex-2-enyl)-((2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-ylmethyl)-thiocarbamic acid S-benzyl ester
• CAS: 140933-98-8
• 化学式: C₆₃H₆₅NO₉S
• 分子量: 1012.28
• InChiKey: YEARZBOLEVWZKW-UOAYXXTLSA-N

反应信息

• 作为反应物：
  描述：

  ((1S,4R,5S,6S)-4,5,6-Tris-benzyloxy-cyclohex-2-enyl)-((2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-ylmethyl)-thiocarbamic acid S-benzyl ester 生成 (2S,3R,4S,5S,6R)-2-Methoxy-6-[((1S,4R,5S,6S)-4,5,6-trihydroxy-cyclohex-2-enylamino)-methyl]-tetrahydro-pyran-3,4,5-triol
  参考文献：
  名称：

  Intramolecular amino delivery reactions for the synthesis of valienamine and analogues

  摘要：

  Iodocyclization and [3,3] sigmatropic rearrangement reactions of N-substituted carbonimidothioates are used to prepare valienamine (1), 7-nor-valienamine (8), and the valienamine-based pseudo-disaccharide 12.

  DOI：

  10.1016/s0040-4039(00)91850-1
• 作为产物：
  描述：

  以 甲苯 为溶剂， 生成 ((1S,4R,5S,6S)-4,5,6-Tris-benzyloxy-cyclohex-2-enyl)-((2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-ylmethyl)-thiocarbamic acid S-benzyl ester
  参考文献：
  名称：

  Intramolecular amino delivery reactions for the synthesis of valienamine and analogues

  摘要：

  Iodocyclization and [3,3] sigmatropic rearrangement reactions of N-substituted carbonimidothioates are used to prepare valienamine (1), 7-nor-valienamine (8), and the valienamine-based pseudo-disaccharide 12.

  DOI：

  10.1016/s0040-4039(00)91850-1